基本信息
胡金波  男  博导  中国科学院上海有机化学研究所
电子邮件: jinbohu@mail.sioc.ac.cn
通信地址: 上海市徐汇区零陵路345号
邮政编码: 200032

研究领域

有机氟化学研究,包括:(1)有机氟化学新试剂、新反应;(2)含氟分子制备和相互转化过程中的科学本质研究;(3)含氟功能材料的合成。

招生信息

每年招收硕博连读研究生2名,或招收硕士考博士研究生1名。
招生专业
070303-有机化学
招生方向
有机氟化学

教育背景

   
学历
-- 研究生
学位
-- 博士

出版信息

   
发表论文
[1] Guo, Junkai, Wang, Xiu, Ni, Chuanfa, Wan, Xiaolong, Hu, Jinbo. SulfoxFluor-enabled deoxyazidation of alcohols with NaN3. NATURE COMMUNICATIONS[J]. 2022, 13(1): http://dx.doi.org/10.1038/s41467-022-30132-x.
[2] Wang, Xiu, Pan, Shitao, Luo, Qinyu, Wang, Qian, Ni, Chuanfa, Hu, Jinbo. Controllable Single and Double Difluoromethylene Insertions into C-Cu Bonds: Copper-Mediated Tetrafluoroethylation and Hexafluoropropylation of Aryl Iodides with TMSCF2H and TMSCF2Br. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY[J]. 2022, 144(27): 12202-12211, http://dx.doi.org/10.1021/jacs.2c0310412202J.
[3] Wei, Zhiqiang, Lou, Zhengzhao, Ni, Chuanfa, Zhang, Wei, Hu, Jinbo. Visible-light-promoted S-trifluoromethylation of thiophenols with trifluoromethyl phenyl sulfone. CHEMICAL COMMUNICATIONS. 2022, [4] Kuang, Cuiwen, Ni, Chuanfa, Gu, Yucheng, Hu, Jinbo. Photoredox-Catalyzed Ring-Opening Addition Reaction between Benzyl Bromides and Cyclic Ethers. SYNTHESIS-STUTTGART[J]. 2022, 54(5): 1272-1286, http://dx.doi.org/10.1055/a-1671-6856.
[5] 胡金波. Dynamic Kinetic Resolution-Enabled Highly Stereoselective Nucleophilic Fluoroalkylation to Access Chiral β-Fluoro Amines. Org. Lett.[J]. 2022, 24(32): 5982-5987, [6] Qinghe Liu, Taige Kong, Chuanfa Ni, Jinbo Hu. Reagent-Controlled Highly Stereoselective Difluoromethylation: Efficient Access to Chiral α-Difluoromethylamines from Ketimines. Molecules[J]. 2022, 27: https://doaj.org/article/59e3f1ead10e470497c423dfaaa27dce.
[7] Liu, Renxiang, Zhou, XiaoCong, He, XinYi, Li, YuanQiang, Zheng, Weiqin, Wang, Xiu, Guo, Junkai, Ni, Chuanfa, Hu, Jinbo. Modified and Scalable Synthesis of N-Tosyl-4-Chlorobenzenesulfonimidoyl Fluoride (SulfoxFluor): Direct Imidation of Sulfinyl Chlorides with Chloramine-T Trihydrate. ORGANIC PROCESS RESEARCH & DEVELOPMENT[J]. 2022, 26(2): 380-386, http://dx.doi.org/10.1021/acs.oprd.1c00431.
[8] Pan, Shitao, Xie, Qiqiang, Wang, Xiu, Wang, Qian, Ni, Chuanfa, Hu, Jinbo. Copper-mediated pentafluoroethylation of organoboronates and terminal alkynes with TMSCF3. CHEMICAL COMMUNICATIONS[J]. 2022, 58(33): 5156-5159, http://dx.doi.org/10.1039/d2cc00975g.
[9] Luo, Qinyu, Wang, Xiu, Hu, Jinbo. Synthesis of fluoroalkenes via Julia and Julia-Kocienski olefination reactions. TETRAHEDRON[J]. 2022, 113: http://dx.doi.org/10.1016/j.tet.2022.132694.
[10] 胡金波. Palladium-Catalyzed Defluorinative Coupling of Difluoroalkenes and Aryl Boronic Acids for Ketone Synthesis. Angew. Chem.Int. Ed.[J]. 2022, e202213646: [11] 胡金波. Difluoromethyl 2-Pyridyl Sulfoximine: A Stereoselective Nucleophilic Reagent for Difluoro(aminosulfinyl)methylation and Difluoro(aminosulfonyl)methylation. CCS Chem.[J]. 2022, 4: 3648-3659, [12] 胡金波. Synthesis of Aryl Perfluorocyclopropyl Ethers via [2 + 1] Cyclopropanation Using TMSCF2Br Reagent. Org. Lett.[J]. 2022, 24: 3589-3593, [13] Meng, Depei, Lyu, Yichong, Ni, Chuanfa, Zhou, Min, Li, Yang, Hu, Jinbo. S-(Trifluoromethyl)Benzothioate (TFBT): A KF-Based Reagent for Nucleophilic Trifluoromethylthiolation. CHEMISTRY-A EUROPEAN JOURNAL[J]. 2022, 28(13): http://dx.doi.org/10.1002/chem.202104395.
[14] 胡金波. Photoredox Catalyzed Ring-Opening Addition Reaction Between Benzyl Bromides and Cyclic Ethers. Synthesis. 2021, [15] Wang, Xiu, Ye, Wenchao, Kong, Taige, Wang, Chenlu, Ni, Chuanfa, Hu, Jinbo. Divergent S- and C-Difluoromethylation of 2-Substituted Benzothiazoles. ORGANIC LETTERS[J]. 2021, 23(21): 8554-8558, http://dx.doi.org/10.1021/acs.orglett.1c03267.
[16] Ji Meishan, Zhu Chen. Iron-Catalyzed Fluoroalkylation of Arylborates with Sulfone Reagents: Beyond the Limitation of Reduction Potential. CHINESE JOURNAL OF ORGANIC CHEMISTRY. 2021, 41(7): 2914-2915, http://dx.doi.org/10.6023/cjoc202100049.
[17] 胡金波. Nucleophilic Trifluoromethylation of Azinium Salts with Zn(CF3)2•bpy. Tetrahedron. 2021, [18] Jia, Rulong, Wang, Xiu, Hu, Jinbo. Recent advance in synthetic applications of difluoromethyl phenyl sulfone and its derivatives. TETRAHEDRON LETTERSnull. 2021, 75: http://dx.doi.org/10.1016/j.tetlet.2021.153182.
[19] Wang, Xiu, Zhou, Min, Liu, Qinghe, Ni, Chuanfa, Fei, Zhongbo, Li, Wei, Hu, Jinbo. Deoxyfluorination of alcohols with aryl fluorosulfonates. CHEMICAL COMMUNICATIONS[J]. 2021, 57(66): 8170-8173, http://dx.doi.org/10.1039/d1cc02617h.
[20] Rong, Jian, Ni, Chuanfa, Gu, Yucheng, Hu, Jinbo. Synthesis of Enantiopure Benzo Fused Cyclic Sulfoximines Through Stereoselective 3+2 Cycloaddition between N-tert-Butanesulfinyl (2-Pyridyl)sulfonyl-difluoromethyl Ketimines and Arynes. HELVETICA CHIMICA ACTA[J]. 2021, 104(4): http://dx.doi.org/10.1002/hlca.202100019.
[21] Zhang, Rongyi, Li, Qigang, Xie, Qiqiang, Ni, Chuanfa, Hu, Jinbo. Difluorocarbene-Induced Ring-Opening Difluoromethylation-Halogenation of Cyclic (Thio)Ethers with TMSCF2X (X=Br, Cl)**. CHEMISTRY-A EUROPEAN JOURNAL[J]. 2021, 27(71): 17773-17779, http://dx.doi.org/10.1002/chem.202103428.
[22] 胡金波. A Radical Chlorodifluoromethylation Protocol for Late Stage Difluoromethylation and Its Application to An Oncology Candidate. Cell Reports Physical Science. 2021, [23] Chen, Dingben, Fan, Zili, Huang, Ling, Gao, Kaili, Xiao, Pan, Ni, Chuanfa, Hu, Jinbo. TMSCFX2 (X = Cl, Br) as halofluorocarbene sources for the synthesis of halofluorocyclopropanes. CHEMICAL COMMUNICATIONS[J]. 2021, 57(3): 319-322, https://www.webofscience.com/wos/woscc/full-record/WOS:000607739000025.
[24] Wang, Qian, Liu, An, Wang, Yan, Ni, Chuanfa, Hu, Jinbo. Copper-Mediated Cross-Coupling of Diazo Compounds with Sulfinates. ORGANIC LETTERS[J]. 2021, 23(17): 6919-6924, http://dx.doi.org/10.1021/acs.orglett.1c02481.
[25] Supranovich, Vyacheslav, I, Volodin, Alexander D, Korlyukov, Alexander A, Hu, Jinbo, Dilman, Alexander D. Reaction of (bromodifluoromethyl)trimethylsilane with HMPA: Structural studies. JOURNAL OF FLUORINE CHEMISTRY[J]. 2021, 250: http://dx.doi.org/10.1016/j.jfluchem.2021.109881.
[26] Zhou, Xin, Ni, Chuanfa, Deng, Ling, Hu, Jinbo. Electrochemical reduction of fluoroalkyl sulfones for radical fluoroalkylation of alkenes. CHEMICAL COMMUNICATIONS[J]. 2021, 57(70): 8750-8753, http://dx.doi.org/10.1039/d1cc03258e.
[27] Miao, Wenjun, Ni, Chuanfa, Xiao, Pan, Jia, Rulong, Zhang, Wei, Hu, Jinbo. Nickel-Catalyzed Reductive 2-Pyridination of Aryl Iodides with Difluoromethyl 2-Pyridyl Sulfone. ORGANIC LETTERS[J]. 2021, 23(3): 711-715, http://dx.doi.org/10.1021/acs.orglett.0c03939.
[28] 肖吉昌. Contemporary synthetic strategies in organofluorine chemistry. Nature Reviews, Methods Primers. 2021, [29] Wang, Xiu, Wang, Fei, Huang, Fengfeng, Ni, Chuanfa, Hu, Jinbo. Deoxyfluorination of Carboxylic Acids with CpFluor: Access to Acyl Fluorides and Amides. ORGANIC LETTERS[J]. 2021, 23(5): 1764-1768, http://dx.doi.org/10.1021/acs.orglett.1c00190.
[30] Wang, Qian, Tao, Quan, Dong, Hui, Ni, Chuanfa, Xie, Xiaoming, Hu, Jinbo. Fluorination Triggers Fluoroalkylation: Nucleophilic Perfluoro-tert-butylation with 1,1-Dibromo-2,2-bis(trifluoromethyl)ethylene (DBBF) and CsF. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2021, 60(52): 27318-27323, http://dx.doi.org/10.1002/anie.202113727.
[31] 倪传法, 胡金波. 涉及碳-氟键断裂与重组的氟化重排反应:由炔丙基氟制备官能团化偕二氟烯丙基化合物. 有机化学[J]. 2020, 40(9): 2997-2998, https://kns.cnki.net/KCMS/detail/detail.aspx?dbcode=CJFQ&dbname=CJFDAUTO&filename=YJHU202009042&v=MDgyNTBoMVQzcVRyV00xRnJDVVI3cWVadWR1Rnl2blVyelBQQ2ZEZTdHNEhOSE1wbzlCWm9SOGVYMUx1eFlTN0Q=.
[32] Liang, Huamin, Liu, Ran, Zhou, Min, Fu, Yue, Ni, Chuanfa, Hu, Jinbo. Difluorocarbene-Triggered Cyclization: Synthesis of (Hetero)arene-Fused 2,2-Difluoro-2,3-dihydrothiophenes. ORGANIC LETTERS[J]. 2020, 22(17): 7047-7051, https://www.webofscience.com/wos/woscc/full-record/WOS:000569377600068.
[33] Zhang, Rongyi, Ni, Chuanfa, Xie, Qiqiang, Hu, Jinbo. Difluoromethylation of alcohols with TMSCF2Br in water: A new insight into the generation and reactions of difluorocarbene in a two-phase system. TETRAHEDRON[J]. 2020, 76(50): http://dx.doi.org/10.1016/j.tet.2020.131676.
[34] 胡金波. From C1 to C3 : Copper-Catalyzed gem-Bis(trifluoromethyl)olefination of a-Diazo Esters with TMSCF3. Angew. Chem. Int. Ed. 2020, 59, 8507 –8511. 2020, [35] Wei, Jun, Bao, Kun, Wang, Yuan, Sheng, Rong, Hu, Jinbo. Novel usage of 2-BTSO2CF2H for metal-free electrophilic difluoroalkanethiolation of indoles. ORGANIC & BIOMOLECULAR CHEMISTRY[J]. 2020, 18(24): 4556-4559, https://www.webofscience.com/wos/woscc/full-record/WOS:000544927100006.
[36] 胡金波. Highly diastereoselective and thermodynamically controlled nucleophilic addition of a-fluoro-a-phenylthio-aphenylsulfonylmethane (FTSM) to aldehydes. Tetrahedron 76 (2020) 130877. 2020, [37] Qiqiang Xie, Jinbo Hu. Chen's Reagent: A Versatile Reagent for Trifluoromethylation,Difluoromethylenation, and Difluoroalkylation in Organic Synthesis. 中国化学:英文版[J]. 2020, 38(2): 202-212, http://lib.cqvip.com/Qikan/Article/Detail?id=7101700406.
[38] Wenchao Ye, Chuanfa Ni, Jinbo Hu. Stereoselective nucleophilic monofluoromethylation of tert-butanesulfinimines: Dynamic thermodynamic Resolution of racemic α-fluoro carbanions. Journal of Fluorine Chemistry. 2020, 231: http://dx.doi.org/10.1016/j.jfluchem.2020.109451.
[39] Tang, Yong, Hu, Jinbo. In deep memory of Professor Rolf Huisgen, a great chemist, who passed away on March 26, 2020. CHINESE JOURNAL OF CHEMISTRY. 2020, 38(5): 529-529, http://lib.cqvip.com/Qikan/Article/Detail?id=7102221656.
[40] Zubkov, Mikhail O, Kosobokov, Mikhail D, Levin, Vitalij V, Kokorekin, Vladimir A, Korlyukov, Alexander A, Hu, Jinbo, Dilman, Alexander D. A novel photoredox-active group for the generation of fluorinated radicals from difluorostyrenes. CHEMICAL SCIENCE[J]. 2020, 11(3): 737-741, http://dx.doi.org/10.1039/c9sc04643g.
[41] Ni, Chuanfa, Hu, Jinbo. Fluorinative Rearrangement Involving Cleavage and Recombination of Carbon-Fluorine Bond: Synthesis of Functionalized Allylic gem-Difluorides from Propargylic Fluorides. CHINESE JOURNAL OF ORGANIC CHEMISTRY. 2020, 40(9): 2997-2998, http://dx.doi.org/10.6023/cjoc202000056.
[42] Kuang, Cuiwen, Zhou, Xin, Xie, Qiqiang, Ni, Chuanfa, Gu, Yucheng, Hu, Jinbo. Generation of Carbocations under Photoredox Catalysis: Electrophilic Aromatic Substitution with 1-Fluoroalkylbenzyl Bromides. ORGANIC LETTERS[J]. 2020, 22(21): 8670-8675, http://dx.doi.org/10.1021/acs.orglett.0c03258.
[43] Wei, Jun, Bao, Kun, Qi, Chengcheng, Liu, Yao, Ni, Chuanfa, Sheng, Rong, Hu, Jinbo. Transition-Metal-Free Electrophilic Fluoroalkanesulfinylation of Electron-Rich (Het)Arenes with Fluoroalkyl Heteroaryl Sulfones via C(Het)-S and S=O Bond Cleavage. ADVANCED SYNTHESIS & CATALYSIS[J]. 2019, 361(24): 5528-5533, https://www.webofscience.com/wos/woscc/full-record/WOS:000494414200001.
[44] Xiao Pan, Ni Chuanfa, Miao Wenjun, Zhou Min, Hu Jingyu, Chen Dingben, Hu Jinbo. Fluoroalkylation of Various Nucleophiles with Fluoroalkyl Sulfones through a Single Electron Transfer Process.. The Journal of organic chemistry. 2019, [45] Guo, Junkai, Kuang, Cuiwen, Rong, Jian, Li, Lingchun, Ni, Chuanfa, Hu, Jinbo. Rapid Deoxyfluorination of Alcohols with N-Tosyl-4-chlorobenzenesulfonimidoyl Fluoride (SulfoxFluor) at Room Temperature. CHEMISTRY-A EUROPEAN JOURNAL[J]. 2019, 25(30): 7259-7264, https://www.webofscience.com/wos/woscc/full-record/WOS:000469274700003.
[46] Xing, Bo, Li, Lingchun, Ni, Chuanfa, Hu, Jinbo. Pentafluoroethylation of Arenediazonium Tetrafluoroborates Using On-Site Generated Tetrafluoroethylene. CHINESE JOURNAL OF CHEMISTRY[J]. 2019, 37(11): 1131-1136, http://lib.cqvip.com/Qikan/Article/Detail?id=7101064977.
[47] 胡金波. Controllable double CF2-insertion into sp2 C–Cu bond using TMSCF3: a facile access to tetrafluoroethylene-bridged structures†. chem. Sci.. 2019, [48] Tsui, Gavin Chit, Hu, Jinbo. Organofluorine Chemistry. ASIAN JOURNAL OF ORGANIC CHEMISTRYnull. 2019, 8(5): 566-567, https://www.webofscience.com/wos/woscc/full-record/WOS:000472711500001.
[49] Wei, Jun, Liang, Huamin, Ni, Chuanfa, Sheng, Rong, Hu, Jinbo. Transition-Metal-Free Desulfinative Cross-Coupling of Heteroaryl Sulfinates with Grignard Reagents. ORGANIC LETTERS[J]. 2019, 21(4): 937-940, [50] Xie, Qiqiang, Zhu, Ziyue, Li, Lingchun, Ni, Chuanfa, Hu, Jinbo. A General Protocol for C-H Difluoromethylation of Carbon Acids with TMSCF2Br. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2019, 58(19): 6405-6410, [51] Hu, Jinbo. From C1 to C2: Pentafluoroethylation with Ruppert-Prakash reagent. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETYnull. 2019, 257: [52] 刘俊, 胡金波. 神奇的氟元素. 化学教育(中英文)[J]. 2019, 40(21): 1-3, http://lib.cqvip.com/Qikan/Article/Detail?id=7100347291.
[53] Xie, Qiqiang, Zhu, Ziyue, Ni, Chuanfa, Hu, Jinbo. Nucleophilic (Phenylsulfonyl/arylthio)difluoromethylation of Aldehydes with TMSCF2Br: A Three-Component Strategy. ORGANIC LETTERS[J]. 2019, 21(22): 9138-9141, https://www.webofscience.com/wos/woscc/full-record/WOS:000497259500058.
[54] Miao, Wenjun, Zhao, Yanchuan, Ni, Chuanfa, Gao, Bing, Zhang, Wei, Hu, Jinbo. Iron-Catalyzed Difluoromethylation of Arylzincs with Difluoromethyl 2-Pyridyl Sulfone. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY[J]. 2018, 140(3): 880-883, https://www.webofscience.com/wos/woscc/full-record/WOS:000423496700007.
[55] 胡金波, 丁奎岭. 有机氟化学:独特和有用的化学研究前沿. 化学学报[J]. 2018, 76(12): 905-906, http://lib.cqvip.com/Qikan/Article/Detail?id=6100115484.
[56] 胡金波. Access to 2,2-diaryl-1,1-difluoroethenes via palladium-Catalyzed dehydrosulfonylative cross-coupling of α-[difluoro(phenylsulfonyl)methyl]benzyl tosylates: PhSO2CF2H as a difluoromethylidene equivalent for connecting aromatic aldehydes. Tetrahedron. 2018, [57] Hu Jinbo, Ding Kuiling. Organofluorine Chemistry: A Unique and Useful Research Frontier of Chemistry. ACTA CHIMICA SINICA. 2018, 76(12): 905-906, https://www.webofscience.com/wos/woscc/full-record/WOS:000456161700001.
[58] 胡金波. Trifluoromethyl Benzoate (TFBz): A Versatile Trifluoromethoxylation Reagent. Journal of American Chemical Society. 2018, [59] Hu Jingyu, Yang Yide, Lou Zhengzhao, Ni Chuanfa, Hu Jinbo. Fluoro-Hydroxylation of gem-Difluoroalkenes:Synthesis of 18O-labeled α-CF3 Alcohols. 中国化学:英文版[J]. 2018, 36(12): 1202-1208, http://lib.cqvip.com/Qikan/Article/Detail?id=6100154729.
[60] Jingyu Hu, Yide Yang, Zhengzhao Lou, Chuanfa Ni, Jinbo Hu. Fluoro-Hydroxylation of gem-Difluoroalkenes:Synthesis of 18O-labeled α-CF3 Alcohols. 中国化学:英文版[J]. 2018, 36(12): 1202-1208, http://lib.cqvip.com/Qikan/Article/Detail?id=6100154729.
[61] Wei, Jun, Gu, Dongyan, Wang, Shengdan, Hu, Jinbo, Dong, Xiaowu, Sheng, Rong. Visible-light-mediated radical arylthiodifluoromethylation of isocyanides with fluorinated 2-pyridyl sulfones. ORGANIC CHEMISTRY FRONTIERS[J]. 2018, 5(17): 2568-2572, https://www.webofscience.com/wos/woscc/full-record/WOS:000443281400008.
[62] Xing, Bo, Ni, Chuanfa, Hu, Jinbo. Copper-Mediated Di- and Monofluoromethanesulfonylation of Arenediazonium Tetrafluoroborates: Probing the Fluorine Effect. CHINESE JOURNAL OF CHEMISTRY[J]. 2018, 36(3): 206-212, http://lib.cqvip.com/Qikan/Article/Detail?id=675013613.
[63] Xie, Qiqiang, Li, Lingchun, Zhu, Ziyue, Zhang, Rongyi, Ni, Chuanfa, Hu, Jinbo. From C-1 to C-2: TMSCF3 as a Precursor for Pentafluoroethylation. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2018, 57(40): 13211-13215, https://www.webofscience.com/wos/woscc/full-record/WOS:000445445700038.
[64] Supranovich, Vyacheslav, I, Levin, Vitalij V, Struchkova, Marina, I, Hu, Jinbo, Dilman, Alexander D. Visible light-mediated difluoroalkylation of electron-deficient alkenes. BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY[J]. 2018, 14(1): 1637-1641, https://doaj.org/article/7f006b9e176d4935a47a7736255f8230.
[65] Rui Zhang, Chuanfa Ni, Zhengbiao He, Jinbo Hu. Organocatalyzed Decarboxylative Trifluoromethylation of β -Ketoacids. Topics in Catalysis,. 2018, 61: [66] Xing, Bo, Ni, Chuanfa, Hu, Jinbo. Hypervalent Iodine(III)-Catalyzed Balz-Schiemann Fluorination under Mild Conditions. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2018, 57(31): 9896-9900, http://dx.doi.org/10.1002/anie.201802466.
[67] Wang, Lingfei, Wei, Jun, Wu, Ranran, Cheng, Gang, Li, Xinjin, Hu, Jinbo, Hu, Yongzhou, Sheng, Rong. The stability and reactivity of tri-, di-, and monofluoromethyl/methoxy/methylthio groups on arenes under acidic and basic conditions. ORGANIC CHEMISTRY FRONTIERS[J]. 2017, 4(2): 214-223, [68] Rong, Jian, Ni, Chuanfa, Hu, Jinbo. Metal-Catalyzed Direct Difluoromethylation Reactions. ASIAN JOURNAL OF ORGANIC CHEMISTRYnull. 2017, 6(2): 139-152, http://dx.doi.org/10.1002/ajoc.201600509.
[69] Qinghe Liu, Chuanfa Ni, Jinbo Hu. China's flourishing synthetic organofluorine chemistry:innovations in the new millennium. 国家科学评论:英文版[J]. 2017, 4(3): 303-325, http://lib.cqvip.com/Qikan/Article/Detail?id=673005844.
[70] Zhao, Yanchuan, Liu, Qinghe, Jiang, Fanzhou, Hu, Jinbo. Stereoselective carbonyl fluoroolefinations with fluorinated sulfone and sulfoximine reagents. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETYnull. 2017, 253: https://www.webofscience.com/wos/woscc/full-record/WOS:000430569101637.
[71] 荣健, 倪传法, 王云泽, 匡翠文, 顾玉诚, 胡金波. 可见光促进下氟烷基砜对芳基烯烃的自由基氟烷基化反应. 化学学报. 2017, [72] Jiang, Fanzhou, Ni, Chuanfa, Hu, Jinbo. Efficient nucleophilic difluoromethylation of aldehydes with (phenylsulfonyl)difluoromethylzinc and (phenylsulfonyl) difluoromethylcadmium reagents. JOURNAL OF FLUORINE CHEMISTRY[J]. 2017, 198: 67-75, http://dx.doi.org/10.1016/j.jfluchem.2016.12.005.
[73] Rong Jian, Ni Chuanfa, Wang Yunze, Kuang Cuiwen, Gu Yucheng, Hu Jinbo. Radical Fluoroalkylation of Aryl Alkenes with Fluorinated Sulfones by Visible- Light Photoredox Catalysis. ACTA CHIMICA SINICA[J]. 2017, 75(1): 105-109, https://www.webofscience.com/wos/woscc/full-record/WOS:000395965800015.
[74] Xie, Qiqiang, Ni, Chuanfa, Zhang, Rongyi, Li, Lingchun, Rong, Jian, Hu, Jinbo. Efficient Difluoromethylation of Alcohols Using TMSCF2Br as a Unique and Practical Difluorocarbene Reagent under Mild Conditions. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2017, 56(12): 3206-3210, https://www.webofscience.com/wos/woscc/full-record/WOS:000397329300012.
[75] Li, Lingchun, Ni, Chuanfa, Xie, Qiqiang, Hu, Mingyou, Wang, Fei, Hu, Jinbo. TMSCF3 as a Convenient Source of CF2=CF2 for Pentafluoroethylation, (Aryloxy)tetrafluoroethylation, and Tetrafluoroethylation. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2017, 56(33): 9971-9975, https://www.webofscience.com/wos/woscc/full-record/WOS:000406798700062.
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[78] Liu, Qinghe, Ni, Chuanfa, Hu, Jinbo. China's flourishing synthetic organofluorine chemistry: innovations in the new millennium. NATIONAL SCIENCE REVIEW[J]. 2017, 4(3): 303-325, http://lib.cqvip.com/Qikan/Article/Detail?id=673005844.
[79] Li Xinjin, Zhao Jingwei, Hu Mingyou, Chen Dingben, Ni Chuanfa, Wang Limin, Hu Jinbo. Copper-mediated aerobic (phenylsulfonyl)difluoromethylation of arylboronic acids with difluoromethyl phenyl sulfone.. Chemical communications (Cambridge, England). 2016, http://kns.cnki.net/KCMS/detail/detail.aspx?QueryID=0&CurRec=1&recid=&FileName=SJPD13D33F5270A9342A807BE2B22F49690D&DbName=SJPD_05&DbCode=SJPD&yx=&pr=&URLID=&bsm=.
[80] Zhou Min, Ni Chuanfa, He Zhengbiao, Hu Jinbo. O-Trifluoromethylation of Phenols: Access to Aryl Trifluoromethyl Ethers by O-Carboxydifluoromethylation and Decarboxylative Fluorination.. Organic letters. 2016, https://www.webofscience.com/wos/woscc/full-record/WOS:000381236300062.
[81] Zeng, Yuwen, Hu, Jinbo. Bridging Fluorine and Aryne Chemistry: Vicinal Difunctionalization of Arynes Involving Nucleophilic Fluorination, Trifluoromethylation, or Trifluoromethylthiolation. SYNTHESIS-STUTTGARTnull. 2016, 48(14): 2137-2150, https://www.webofscience.com/wos/woscc/full-record/WOS:000380251800004.
[82] He, Zhengbiao, Tan, Ping, Hu, Jinbo. Copper-Catalyzed Trifluoromethylation of Polysubstituted Alkenes Assisted by Decarboxylation. ORGANIC LETTERS[J]. 2016, 18(1): 72-75, https://www.webofscience.com/wos/woscc/full-record/WOS:000367702400019.
[83] Xie Qiqiang, Li Xinjin, Ni Chuanfa, Hu Jinbo, Hu Mingyou. Copper-Mediated Deuterotrifluoromethylation of α-Diazo Esters. 中国化学:英文版[J]. 2016, 469-472, http://lib.cqvip.com/Qikan/Article/Detail?id=669128212.
[84] 胡金波. The Unique Fluorine Effects in Organic Chemistry: Recent Facts and Insights into Fluoroalkylations. Chem. Soc. Rev.. 2016, [85] Dr. Dingben Chen, Dr. Chuanfa Ni, Dr. Yanchuan Zhao, Xian Cai, Xinjin Li, Pan Xiao, Prof. Dr. Jinbo Hu. Bis(difluoromethyl)trimethylsilicate Anion: A Key Intermediate in Nucleophilic Difluoromethylation of Enolizable Ketones with Me3SiCF2H. Angewandte Chemie. 2016, [86] Jian Rong, Ling Deng, Ping Tan, Dr. Chuanfa Ni, Dr. Yucheng Gu, Prof. Dr. Jinbo Hu. Radical Fluoroalkylation of Isocyanides with Fluorinated Sulfones by Visible‐Light Photoredox Catalysis. Angewandte Chemie. 2016, [87] 胡金波. Copper-Catalyzed Trifluoromethylation of Polysubstituted Alkenes Assisted by Decarboxylation. Org. Lett.. 2016, [88] Yuwen Zeng, Jinbo Hu. Bridging Fluorine and Aryne Chemistry: Vicinal Difunctionalization of Arynes Involving Nucleophilic Fluorination, Trifluoromethylation, or Trifluoromethylthiolation. Synthesis (Stuttg). 2016, 48(14): http://kns.cnki.net/KCMS/detail/detail.aspx?QueryID=0&CurRec=2&recid=&FileName=SJGT672759A12A2AE1D079B2802E31A2227D&DbName=WWMERGEJ03&DbCode=WWME&yx=&pr=&URLID=&bsm=.
[89] Rong, Jian, Deng, Ling, Tan, Ping, Ni, Chuanfa, Gu, Yucheng, Hu, Jinbo. Radical Fluoroalkylation of Isocyanides with Fluorinated Sulfones by Visible-Light Photoredox Catalysis. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2016, 55(8): 2743-2747, https://www.webofscience.com/wos/woscc/full-record/WOS:000370655700018.
[90] Lingchun Li, Chuanfa Ni, Fei Wang, Jinbo Hu. Deoxyfluorination of alcohols with 3,3-difluoro-1,2-diarylcyclopropenes. NATURE COMMUNICATIONS[J]. 2016, 7: https://doaj.org/article/a543bfff6b39429489f2280db98b4d64.
[91] Miao, Wenjun, Ni, Chuanfa, Zhao, Yanchuan, Hu, Jinbo. Nucleophilic Iododifluoromethylation of Carbonyl Compounds Using Difluoromethyl 2-Pyridyl Sulfone. ORGANIC LETTERS[J]. 2016, 18(11): 2766-2769, https://www.webofscience.com/wos/woscc/full-record/WOS:000377319000063.
[92] Mingyou Hu, Qiqiang Xie, Xinjin Li, Chuanfa Ni, Jinbo Hu. Copper-Mediated Deuterotrifluoromethylation of α-Diazo Esters. 中国化学:英文版[J]. 2016, 469-472, http://lib.cqvip.com/Qikan/Article/Detail?id=669128212.
[93] Chen, Dingben, Ni, Chuanfa, Zhao, Yanchuan, Cai, Xian, Li, Xinjin, Xiao, Pan, Hu, Jinbo. Bis(difluoromethyl)trimethylsilicate Anion: A Key Intermediate in Nucleophilic Difluoromethylation of Enolizable Ketones with Me3SiCF2H. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2016, 55(41): 12632-12636, [94] Ni, Chuanfa, Hu, Jinbo. The unique fluorine effects in organic reactions: recent facts and insights into fluoroalkylations. CHEMICAL SOCIETY REVIEWSnull. 2016, 45(20): 5441-5454, https://www.webofscience.com/wos/woscc/full-record/WOS:000385181300001.
[95] 胡金波. Silver-Mediated Trifluoromethylthiolation−Iodination of Arynes. Org. Lett.. 2016, [96] Hu, Mingyou, Xie, Qiqiang, Li, Xinjin, Ni, Chuanfa, Hu, Jinbo. Copper-Mediated Deuterotrifluoromethylation of alpha-Diazo Esters. CHINESE JOURNAL OF CHEMISTRY[J]. 2016, 34(5): 469-472, https://www.webofscience.com/wos/woscc/full-record/WOS:000379678600006.
[97] Zeng, Yuwen, Hu, Jinbo. Bridging Fluorine and Aryne Chemistry: Vicinal Difunctionalization of Arynes Involving Nucleophilic Fluorination, Trifluoromethylation, or Trifluoromethylthiolation. SYNTHESIS-STUTTGARTnull. 2016, 48(14): 2137-2150, https://www.webofscience.com/wos/woscc/full-record/WOS:000380251800004.
[98] Li, Xinjin, Zhao, Jingwei, Wang, Yunze, Rong, Jian, Hu, Mingyou, Chen, Dingben, Xiao, Pan, Ni, Chuanfa, Wang, Limin, Hu, Jinbo. Copper-Mediated Aromatic 1,1-Difluoroethylation with (1,1-Difluoroethyl)trimethylsilane (TMSCF2CH3). CHEMISTRY-AN ASIAN JOURNAL[J]. 2016, 11(12): 1789-1792, https://www.webofscience.com/wos/woscc/full-record/WOS:000379519400007.
[99] Shen, Xiao, Liu, Qinghe, Zhang, Wei, Hu, Jinbo. Stereoselective Synthesis of (Sulfonimidoyl)cyclopropanes with (R)-PhSO(NTs)CH2Cl and ,-Unsaturated Weinreb Amides: Tuning the of Selectivity between C-Cl and C-S Bond Cleavage. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY[J]. 2016, 2016(5): 906-909, http://dx.doi.org/10.1002/ejoc.201501611.
[100] Zeng, Yuwen, Ni, Chuanfa, Hu, Jinbo. Recent Advances in the One-Step Synthesis of Distally Fluorinated Ketones. CHEMISTRY-A EUROPEAN JOURNALnull. 2016, 22(10): 3210-3223, https://www.webofscience.com/wos/woscc/full-record/WOS:000371419200004.
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[103] Zhou, Min, Ni, Chuanfa, He, Zhengbiao, Hu, Jinbo. O-Trifluoromethylation of Phenols: Access to Aryl Trifluoromethyl Ethers by O-Carboxydifluoromethylation and Decarboxylative Fluorination. ORGANIC LETTERS[J]. 2016, 18(15): 3754-3757, https://www.webofscience.com/wos/woscc/full-record/WOS:000381236300062.
[104] Xiao, Pan, Rong, Jian, Ni, Chuanfa, Guo, Junkai, Li, Xinjin, Chen, Dingben, Hu, Jinbo. Radical (Phenylsulfonyl)difluoromethylation of Isocyanides with PhSO2CF2H under Transition-Metal-Free Conditions. ORGANIC LETTERS[J]. 2016, 18(22): 5912-5915, https://www.webofscience.com/wos/woscc/full-record/WOS:000388428600036.
[105] Zeng, Yuwen, Hu, Jinbo. Silver-Mediated Trifluoromethylthiolation-Iodination of Arynes. ORGANIC LETTERS[J]. 2016, 18(4): 856-859, https://www.webofscience.com/wos/woscc/full-record/WOS:000370768200058.
[106] Lingchun Li, Chuanfa Ni, Fei Wang, Junkai Guo, Jinbo Hu. Deoxyfluorination of alcohols with 3,3-difluoro-1,2-diarylcyclopropenes(CpFluors). 2016, http://kns.cnki.net/KCMS/detail/detail.aspx?QueryID=0&CurRec=6&recid=&FileName=ZGHY201611003122&DbName=CPFDLAST2018&DbCode=CPFD&yx=&pr=&URLID=&bsm=.
[107] Gao, Bing, Zhao, Yanchuan, Hu, Jinbo. AgF-Mediated Fluorinative Cross-Coupling of Two Olefins: Facile Access to alpha-CF3 Alkenes and beta-CF3 Ketones. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2015, 54(2): 638-642, https://www.webofscience.com/wos/woscc/full-record/WOS:000347238800046.
[108] He, Zhengbiao, Tan, Ping, Ni, Chuanfa, Hu, Jinbo. Fluoroalkylative Aryl Migration of Conjugated N-Arylsulfonylated Amides Using Easily Accessible Sodium Di- and Monofluoroalkanesulfinates. ORGANIC LETTERS[J]. 2015, 17(8): 1838-1841, https://www.webofscience.com/wos/woscc/full-record/WOS:000353314800006.
[109] Zeng, Yuwen, Li, Guangyu, Hu, Jinbo. Diphenyliodonium-Catalyzed Fluorination of Arynes: Synthesis of ortho-Fluoroiodoarenes. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2015, 54(37): 10773-10777, [110] 胡金波. 过渡金属促进的二氟烷基化和一氟烷基化反应研究进展. Acta Chim. Sinica. 2015, [111] 胡金波. Recent advances in green fluorine chemistry. Reports in Organic Chemistry. 2015, [112] Ni, Chuanfa, Jiang, Fanzhou, Zeng, Yuwen, Hu, Jinbo. Chemically oxidative fluorination with fluoride ions. JOURNAL OF FLUORINE CHEMISTRYnull. 2015, 179: 3-13, http://dx.doi.org/10.1016/j.jfluchem.2015.06.026.
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[114] Zhao, Yanchuan, Jiang, Fanzhou, Hu, Jinbo. Spontaneous Resolution of Julia-Kocienski Intermediates Facilitates Phase Separation to Produce Z- and E-Monofluoroalkenes. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY[J]. 2015, 137(15): 5199-5203, https://www.webofscience.com/wos/woscc/full-record/WOS:000353606700054.
[115] Luo, Tao, Zhang, Rui, Shen, Xiao, Zhang, Wei, Ni, Chuanfa, Hu, Jinbo. Bronsted acid-catalyzed 1,2-fluorine migration with fluoroepoxides. DALTON TRANSACTIONS[J]. 2015, 44(45): 19636-19641, https://www.webofscience.com/wos/woscc/full-record/WOS:000364912100027.
[116] 胡金波. Spontaneous Resolution of Julia-Kocienski Intermediates Facilitates Phase Separation to Produce Z- and E‑Monofluoroalkenes. J. Am. Chem. Soc.. 2015, [117] Zhu, Jieming, Ni, Chuanfa, Gao, Bing, Hu, Jinbo. Copper(0)-mediated fluoroalkylation of iodobenzene with 2-bromo-1,1,2,2-tetrafluoroethyl compounds: Investigation on the influence of R substituent on the reactivity of RCF2Cu species. JOURNAL OF FLUORINE CHEMISTRY[J]. 2015, 171: 139-147, http://dx.doi.org/10.1016/j.jfluchem.2014.08.011.
[118] Gao, Bing, Zhao, Yanchuan, Hu, Jinbo. AgF-mediated fluorinative cross-coupling of two olefins. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETYnull. 2015, 249: https://www.webofscience.com/wos/woscc/full-record/WOS:000411186500495.
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[120] Ni, Chuanfa, Hu, Mingyou, Hu, Jinbo. Good Partnership between Sulfur and Fluorine: Sulfur-Based Fluorination and Fluoroalkylation Reagents for Organic Synthesis. CHEMICAL REVIEWSnull. 2015, 115(2): 765-825, https://www.webofscience.com/wos/woscc/full-record/WOS:000348689400008.
[121] 胡金波. AgF-Mediated Fluorinative Cross-Coupling of Two Olefins: FacileAccess to a-CF3 Alkenes and b-CF3 Ketones**. Angew. Chem. Int. Ed. 2015, [122] Gao, Bing, Zhao, Yanchuan, Hu, Jingyu, Hu, Jinbo. Difluoromethyl 2-pyridyl sulfone: a versatile carbonyl gem-difluoroolefination reagent. ORGANIC CHEMISTRY FRONTIERS[J]. 2015, 2(2): 163-168, https://www.webofscience.com/wos/woscc/full-record/WOS:000364443200013.
[123] Li, Xinjin, Zhao, Jingwei, Zhang, Liang, Hu, Mingyou, Wang, Limin, Hu, Jinbo. Copper-Mediated Trifluoromethylation Using Phenyl Trifluoromethyl Sulfoxide. ORGANIC LETTERS[J]. 2015, 17(2): 298-301, https://www.webofscience.com/wos/woscc/full-record/WOS:000348331800033.
[124] 胡金波. Chemically oxidative fluorination with fluoride ions. Journal of Fluorine Chemistry. 2015, [125] Hu, Mingyou, Ni, Chuanfa, Li, Lingchun, Han, Yongxin, Hu, Jinbo. gem-Difluoroolefination of Diazo Compounds with TMSCF3 or TMSCF2Br: Transition-Metal-Free Cross-Coupling of Two Carbene Precursors. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY[J]. 2015, 137(45): 14496-14501, https://www.webofscience.com/wos/woscc/full-record/WOS:000365148500037.
[126] Li, Shan, Peng, Peng, Wei, Jun, Hu, Yongzhou, Hu, Jinbo, Sheng, Rong. Nucleophilic Difluoroalkylation of Isocyanates with Difluoromethyl 2-Pyridyl Sulfone. ADVANCED SYNTHESIS & CATALYSIS[J]. 2015, 357(16-17): 3429-3434, https://www.webofscience.com/wos/woscc/full-record/WOS:000368342400004.
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[128] Hu, Jingyu, Gao, Bing, Li, Lingchun, Ni, Chuanfa, Hu, Jinbo. Palladium-Catalyzed Monofluoromethylation of Arylboronic Esters with Fluoromethyl Iodide. ORGANIC LETTERS[J]. 2015, 17(12): 3086-3089, https://www.webofscience.com/wos/woscc/full-record/WOS:000356845000057.
[129] Yang, Congrong, Wang, Suli, Jiang, Luhua, Hu, Jinbo, Ma, Wenjia, Sun, Gongquan. 1,2-Dimethylimidazolium-functionalized cross-linked alkaline anion exchange membranes for alkaline direct methanol fuel cells. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY[J]. 2015, 40(5): 2363-2370, http://dx.doi.org/10.1016/j.ijhydene.2014.12.050.
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[143] 高兵, 赵延川, 胡明友, 倪传法, 胡金波. Gem-Difluoroolefination of Diaryl Ketones and Enolizable Aldehydes with Difluoromethyl 2-Pyridyl Sulfone: New Insights into the Julia-Kocienski Reaction. Chem.-Eur. J.[J]. 2014, 20(25): 7803-7810, http://ir.sioc.ac.cn/handle/331003/38821.
[144] 叶文超, 张来俊, 倪传法, 荣健, 胡金波. Stereoselective 3+2 cycloaddition of N-tert-butanesulfinyl imines to arynes facilitated by a removable PhSO2CF2 group: synthesis and transformation of cyclic sulfoximines. Chem. Commun.[J]. 2014, 50(73): 10596-10599, http://ir.sioc.ac.cn/handle/331003/38825.
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[149] Ye, Wenchao, Zhang, Laijun, Ni, Chuanfa, Rong, Jian, Hu, Jinbo. Stereoselective 3+2 cycloaddition of N-tert-butanesulfinyl imines to arynes facilitated by a removable PhSO2CF2 group: synthesis and transformation of cyclic sulfoximines. CHEMICAL COMMUNICATIONS[J]. 2014, 50(73): 10596-10599, https://www.webofscience.com/wos/woscc/full-record/WOS:000340899500009.
[150] 曾裕文, 胡金波. Silver-Catalyzed Formal Insertion of Arynes into RfI Bonds. Chem.-Eur. J.[J]. 2014, 20(23): 6866-6870, http://ir.sioc.ac.cn/handle/331003/38822.
[151] Gao, Bing, Zhao, Yanchuan, Hu, Mingyou, Ni, Chuanfa, Hu, Jinbo. gem-Difluoroolefination of Diaryl Ketones and Enolizable Aldehydes with Difluoromethyl 2-Pyridyl Sulfone: New Insights into the Julia-Kocienski Reaction. CHEMISTRY-A EUROPEAN JOURNAL[J]. 2014, 20(25): 7803-7810, https://www.webofscience.com/wos/woscc/full-record/WOS:000337637400035.
[152] Shen, Xiao, Liu, Qinghe, Luo, Tao, Hu, Jinbo. Nucleophilic Difluoromethylation of Epoxides with PhSO(NTBS)CF2H by a Preorganization Strategy. CHEMISTRY-A EUROPEAN JOURNAL[J]. 2014, 20(22): 6795-6800, http://dx.doi.org/10.1002/chem.201402506.
[153] 沈晓, 周敏, 倪传法, 张伟, 胡金波. Direct monofluoromethylation of O-, S-, N-, and P-nucleophiles with PhSO(NTs) CH2F: the accelerating effect of alpha-fluorine substitution. Chem. Sci.[J]. 2014, 5(1): 117-122, http://ir.sioc.ac.cn/handle/331003/38812.
[154] Shen, Xiao, Hu, Jinbo. Fluorinated Sulfoximines: Preparation, Reactions and Applications. EUROPEAN JOURNAL OF ORGANIC CHEMISTRYnull. 2014, 2014(21): 4437-4451, https://www.webofscience.com/wos/woscc/full-record/WOS:000339493400001.
[155] 沈晓, 胡金波. Fluorinated Sulfoximines: Preparation, Reactions and Applications. Eur. J. Org. Chem.[J]. 2014, 4437-4451, http://ir.sioc.ac.cn/handle/331003/38824.
[156] Wang, Fei, Li, Lingchun, Ni, Chuanfa, Hu, Jinbo. Deoxygenative gem-difluoroolefination of carbonyl compounds with (chlorodifluoromethyl)trimethylsilane and triphenylphosphine. BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY[J]. 2014, 10(1): 344-351, https://doaj.org/article/6634ba7affb24527a054ed8e3049772d.
[157] 沈晓, 刘庆贺, 罗涛, 胡金波. Nucleophilic Difluoromethylation of Epoxides with PhSO(NTBS)CF2H by a Preorganization Strategy. Chem.-Eur. J.[J]. 2014, 20(22): 6795-6800, http://ir.sioc.ac.cn/handle/331003/38819.
[158] 胡明友, 荣健, 缪文俊, 倪传法, 韩永新, 胡金波. Copper-Mediated Trifluoromethylthiolation of alpha-Diazoesters. Org. Lett.[J]. 2014, 16(7): 2030-2033, http://ir.sioc.ac.cn/handle/331003/38818.
[159] Yuan, Zhizhang, Li, Xianfeng, Hu, Jinbo, Xu, Wanxing, Cao, Jingyu, Zhang, Huamin. Degradation mechanism of sulfonated poly(ether ether ketone) (SPEEK) ion exchange membranes under vanadium flow battery medium. PHYSICAL CHEMISTRY CHEMICAL PHYSICS[J]. 2014, 16(37): 19841-19847, http://cas-ir.dicp.ac.cn/handle/321008/143935.
[160] Shen, Xiao, Liu, Qinghe, Ni, Chuanfa, Hu, Jinbo. Nucleophilic Difluoro(phenylsulfonimidoyl)methylation of Unactivated Alkyl Bromides with PhSO(NTBS)CF2H: Facile Entry into gem-Difluoroalkenes. CHINESE JOURNAL OF CHEMISTRY[J]. 2014, 32(8): 703-708, https://www.webofscience.com/wos/woscc/full-record/WOS:000341236900010.
[161] 缪文俊, 倪传法, 赵延川, 胡金波. Radical (2-pyridylsulfonyl)difluoromethylation of terminal alkenes with iododifluoromethyl 2-pyridyl sulfone. J. Fluor. Chem.[J]. 2014, 167: 231-236, http://ir.sioc.ac.cn/handle/331003/38827.
[162] 罗涛, 张锐, 张伟, 沈晓, UMEMOTO TERUO, 胡金波. Divergent Rearrangements of Cyclopropyl-Substituted Fluoroepoxides Involving C-F Bond Cleavage and Formation. Org. Lett.[J]. 2014, 16(3): 888-891, http://ir.sioc.ac.cn/handle/331003/38817.
[163] Gao, Bing, Zhao, Yanchuan, Ni, Chuanfa, Hu, Jinbo. AgF-Mediated Fluorinative Homocoupling of gem-Difluoroalkenes. ORGANIC LETTERS[J]. 2014, 16(1): 102-105, https://www.webofscience.com/wos/woscc/full-record/WOS:000329472800027.
[164] 姜範洲, 赵延川, 胡金波. Selective mono?uorination of active methylene compounds: the important role of ZnCl2 in inhibiting over?uorination. Org. Chem. Front.[J]. 2014, 1: 625-629, http://ir.sioc.ac.cn/handle/331003/38815.
[165] 高兵, 赵延川, 倪传法, 胡金波. AgF-Mediated Fluorinative Homocoupling of gem-Difluoroalkenes. Org. Lett.[J]. 2014, 16(1): 102-105, http://ir.sioc.ac.cn/handle/331003/38814.
[166] Zeng, Yuwen, Zhang, Laijun, Zhao, Yanchuan, Ni, Chuanfa, Zhao, Jingwei, Hu, Jinbo. Silver-Mediated Trifluoromethylation-Iodination of Arynes. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY[J]. 2013, 135(8): 2955-2958, http://www.irgrid.ac.cn/handle/1471x/869982.
[167] Hu, Mingyou, He, Zhengbiao, Gao, Bing, Li, Lingchun, Ni, Chuanfa, Hu, Jinbo. Copper-Catalyzed gem-Difluoroolefination of Diazo Compounds with TMSCF3 via C-F Bond Cleavage. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY[J]. 2013, 135(46): 17302-17305, http://www.irgrid.ac.cn/handle/1471x/869978.
[168] 胡明友, 何正标, 高兵, 李铃春, 倪传法, 胡金波. Copper-Catalyzed gem-Difluoroolefination of Diazo Compounds with TMSCF3 via C-F Bond Cleavage. J. Am. Chem. Soc.[J]. 2013, 135(46): 17302-17305, http://www.irgrid.ac.cn/handle/1471x/869978.
[169] 何正标, 张锐, 胡明友, 李铃春, 倪传法, 胡金波. Copper-mediated trifluoromethylation of propiolic acids: facile synthesis of alpha-trifluoromethyl ketones. Chem. Sci.[J]. 2013, 4(9): 3478-3483, http://www.irgrid.ac.cn/handle/1471x/869976.
[170] Huang, Weizhou, Ni, Chuanfa, Zhao, Yanchuan, Hu, Jinbo. DIAD-mediated metal-free cross dehydrogenative coupling between tertiary amines and alpha-fluorinated sulfones. NEW JOURNAL OF CHEMISTRY[J]. 2013, 37(6): 1684-1687, http://www.irgrid.ac.cn/handle/1471x/869979.
[171] Shen, Xiao, Zhang, Wei, Ni, Chuanfa, Hu, Jinbo. Chiral fluorinated sulfoximines as new fluoroalkylating agents. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETYnull. 2013, 245: https://www.webofscience.com/wos/woscc/full-record/WOS:000324303600342.
[172] 曾裕文, 张来俊, 赵延川, 倪传法, 赵经纬, 胡金波. Silver-Mediated Trifluoromethylation-Iodination of Arynes. J. Am. Chem. Soc.[J]. 2013, 135(8): 2955-2958, http://www.irgrid.ac.cn/handle/1471x/869982.
[173] Li, Lingchun, Wang, Fei, Ni, Chuanfa, Hu, Jinbo. Synthesis of gem-Difluorocyclopropa(e)nes and O-, S-, N-, and P-Difluoromethylated Compounds with TMSCF2Br. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2013, 52(47): 12390-12394, http://www.irgrid.ac.cn/handle/1471x/869980.
[174] Hu, Mingyou, Gao, Bing, Ni, Chuanfa, Zhang, Laijun, Hu, Jinbo. Nucleophilic difluoro(phenylsulfonyl)methylation of carbonyls with PhSO2CF2H reagent in the presence of in situ generated substoichiometric amount of base. JOURNAL OF FLUORINE CHEMISTRY[J]. 2013, 155: 52-58, http://dx.doi.org/10.1016/j.jfluchem.2013.05.015.
[175] Zhao, Yanchuan, Ni, Chuanfa, Jiang, Fanzhou, Gao, Bing, Shen, Xiao, Hu, Jinbo. Copper-Catalyzed Debenzoylative Monofluoromethylation of Aryl Iodides Assisted by the Removable (2-Pyridyl)sulfonyl Group. ACS CATALYSIS[J]. 2013, 3(4): 631-634, https://www.webofscience.com/wos/woscc/full-record/WOS:000317328000023.
[176] 胡金波. Special Issue of "Organofluorine Chemistry". Chin. J. Chem.[J]. 2013, 31(7): 867-867, http://www.irgrid.ac.cn/handle/1471x/870021.
[177] Hu, Jinbo. Special Issue of "Organofluorine Chemistry". CHINESE JOURNAL OF CHEMISTRY. 2013, 31(7): 867-867, http://www.irgrid.ac.cn/handle/1471x/870021.
[178] 李铃春, 王飞, 倪传法, 胡金波. Synthesis of gem-Difluorocyclopropa(e)nes and O-, S-, N-, and P-Difluoromethylated Compounds with TMSCF2Br. Angew. Chem.-Int. Edit.[J]. 2013, 52(47): 12390-12394, http://www.irgrid.ac.cn/handle/1471x/869980.
[179] 胡明友, 高兵, 倪传法, 张来俊, 胡金波. Nucleophilic difluoro(phenylsulfonyl)methylation of carbonyls with PhSO2CF2H reagent in the presence of in situ generated substoichiometric amount of base. J. Fluor. Chem.[J]. 2013, 155: 52-58, http://dx.doi.org/10.1016/j.jfluchem.2013.05.015.
[180] He, Zhengbiao, Zhang, Rui, Hu, Mingyou, Li, Lingchun, Ni, Chuanfa, Hu, Jinbo. Copper-mediated trifluoromethylation of propiolic acids: facile synthesis of alpha-trifluoromethyl ketones. CHEMICAL SCIENCE[J]. 2013, 4(9): 3478-3483, http://www.irgrid.ac.cn/handle/1471x/869976.
[181] 沈晓, 倪传法, 胡金波. Highly Stereoselective and One-Pot Synthesis of Tetra-substituted Monofluoroalkenes with Aldehydes and Fluorobis(phenylsulfonyl)methane. Chin. J. Chem.[J]. 2013, 31(7): 878-884, http://www.irgrid.ac.cn/handle/1471x/869981.
[182] 黄维洲, 倪传法, 赵延川, 胡金波. DIAD-mediated metal-free cross dehydrogenative coupling between tertiary amines and alpha-fluorinated sulfones. New J. Chem.[J]. 2013, 37(6): 1684-1687, http://www.irgrid.ac.cn/handle/1471x/869979.
[183] Shen, Xiao, Ni, Chuanfa, Hu, Jinbo. Highly Stereoselective and One-Pot Synthesis of Tetra-substituted Monofluoroalkenes with Aldehydes and Fluorobis(phenylsulfonyl)methane. CHINESE JOURNAL OF CHEMISTRY[J]. 2013, 31(7): 878-884, http://www.irgrid.ac.cn/handle/1471x/869981.
[184] 何正标, 胡明友, 罗涛, 李玲春, 胡金波. Copper-Catalyzed Difluoromethylation of beta,gama-Unsaturated Carboxylic Acids: An Efficient Allylic Difluoromethylation. Angew. Chem.-Int. Edit.[J]. 2012, 51(46): 11545-11547, http://ir.sioc.ac.cn/handle/331003/28361.
[185] Zhao, Yanchuan, Gao, Bing, Hu, Jinbo. From Olefination to Alkylation: In-Situ Halogenation of Julia-Kocienski Intermediates Leading to Formal Nucleophilic Iodo- and Bromodifluoromethylation of Carbonyl Compounds. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY[J]. 2012, 134(13): 5790-5793, http://www.irgrid.ac.cn/handle/1471x/681803.
[186] Hu, Mingyou, Wang, Fei, Zhao, Yanchuan, He, Zhengbiao, Zhang, Wei, Hu, Jinbo. Difluoro(phenylchalcogen)methylation of aldehydes, ketones, and imines with S-, Se-, and Te-containing reagents PhXCF2H (X = S, Se, Te). JOURNAL OF FLUORINE CHEMISTRY[J]. 2012, 135: 45-58, http://dx.doi.org/10.1016/j.jfluchem.2011.08.007.
[187] Shen, Xiao, Zhang, Wei, Ni, Chuanfa, Gu, Yucheng, Hu, Jinbo. Tuning the Reactivity of Difluoromethyl Sulfoximines from Electrophilic to Nucleophilic: Stereoselective Nucleophilic Difluoromethylation of Aryl Ketones. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY[J]. 2012, 134(41): 16999-17002, http://www.irgrid.ac.cn/handle/1471x/681841.
[188] Zhao, Yanchuan, Hu, Jinbo. Palladium-Catalyzed 2,2,2-Trifluoroethylation of Organoboronic Acids and Esters. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2012, 51(4): 1033-1036, http://www.irgrid.ac.cn/handle/1471x/681830.
[189] Zhang, Wei, Zhao, Yanchuan, Ni, Chuanfa, Mathew, Thomas, Hu, Jinbo. Palladium-catalyzed allylation of 2,2,2-thfluoroethyl phenyl sulfone, a potential 2,2,2-trifluoroethyl pronucleophile. TETRAHEDRON LETTERS[J]. 2012, 53(48): 6565-6568, http://www.irgrid.ac.cn/handle/1471x/681848.
[190] Zhang, Wei, Ni, Chuanfa, Hu, Jinbo, Horvath, IT. Selective Fluoroalkylation of Organic Compounds by Tackling the "Negative Fluorine Effect". FLUOROUS CHEMISTRYnull. 2012, 308: 25-44, https://www.webofscience.com/wos/woscc/full-record/WOS:000300911800003.
[191] Zhao, Yanchuan, Gao, Bing, Ni, Chuanfa, Hu, Jinbo. Copper-Mediated Fluoroalkylation of Aryl Iodides Enables Facile Access to Diverse Fluorinated Compounds: The Important Role of the (2-Pyridyl)sulfonyl Group. ORGANIC LETTERS[J]. 2012, 14(23): 6080-6083, http://www.irgrid.ac.cn/handle/1471x/681855.
[192] Huang, Weizhou, Ni, Chuanfa, Zhao, Yanchuan, Zhang, Wei, Dilman, Alexander D, Hu, Jinbo. Nucleophilic difluoromethylation of C=N bonds in heterocycles with difluoromethyl silane reagents. TETRAHEDRON[J]. 2012, 68(26): 5137-5144, http://www.irgrid.ac.cn/handle/1471x/681789.
[193] Kosobokov, Mikhail D, Dilman, Alexander D, Struchkova, Marina I, Belyakov, Pavel A, Hu, Jinbo. Reactions of Sulfur- and Phosphorus-Substituted Fluoroalkylating Silicon Reagents with Imines and Enamines under Acidic Conditions. JOURNAL OF ORGANIC CHEMISTRY[J]. 2012, 77(4): 2080-2086, http://dx.doi.org/10.1021/jo202669w.
[194] He, Zhengbiao, Luo, Tao, Hu, Mingyou, Cao, Yanjing, Hu, Jinbo. Copper-Catalyzed Di- and Trifluoromethylation of alpha,beta-Unsaturated Carboxylic Acids: A Protocol for Vinylic Fluoroalkylations. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2012, 51(16): 3944-3947, http://www.irgrid.ac.cn/handle/1471x/681821.
[195] Huang, Weizhou, Ni, Chuanfa, Zhao, Yanchuan, Gao, Bing, Hu, Jinbo. Nucleophilic difluoromethylation of N,N-acetals with TMSCF2SO2Ph reagent promoted by trifluoroacetic acid: A facile access to alpha-difluoromethylated tertiary amines. JOURNAL OF FLUORINE CHEMISTRY[J]. 2012, 143: 161-166, http://www.irgrid.ac.cn/handle/1471x/681851.
[196] He, Zhengbiao, Hu, Mingyou, Luo, Tao, Li, Lingchun, Hu, Jinbo. Copper-Catalyzed Difluoromethylation of ss,?-Unsaturated Carboxylic Acids: An Efficient Allylic Difluoromethylation. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2012, 51(46): 11545-11547, https://www.webofscience.com/wos/woscc/full-record/WOS:000310875700024.
[197] Shen, Xiao, Zhang, Wei, Zhang, Lei, Luo, Tao, Wan, Xiaolong, Gu, Yucheng, Hu, Jinbo. Enantioselective Synthesis of Cyclopropanes That Contain Fluorinated Tertiary Stereogenic Carbon Centers: A Chiral a-Fluoro Carbanion Strategy. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2012, 51(28): 6966-6970, http://dx.doi.org/10.1002/anie.201202451.
[198] Hu, Mingyou, Ni, Chuanfa, Hu, Jinbo. Copper-Mediated Trifluoromethylation of alpha-Diazo Esters with TMSCF3: The Important Role of Water as a Promoter. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY[J]. 2012, 134(37): 15257-15260, http://www.irgrid.ac.cn/handle/1471x/681839.
[199] Shen, Xiao, Ni, Chuanfa, Hu, Jinbo. Nucleophilic Fluoroalkylation of alpha,beta-Unsaturated Carbonyl Compounds with alpha-Fluorinated Sulfones: Investigation of the Reversibility of 1,2-Additions and the Formation of 1,4-Adducts. HELVETICA CHIMICA ACTA[J]. 2012, 95(10): 2043-2051, http://dx.doi.org/10.1002/hlca.201200445.
[200] 赵延川, 黄维洲, 郑吉, 胡金波. Efficient and Direct Nucleophilic Difluoromethylation of Carbonyl Compounds and Imines with Me(3)SiCF(2)H at Ambient or Low Temperature. Org. Lett.[J]. 2011, 13(19): 5342-5345, http://ir.sioc.ac.cn/handle/331003/24099.
[201] 王飞, 黄维洲, 胡金波. Difluoromethylation of O-, S-, N-, C-Nucleophiles Using Difluoromethyltri(n-butyl)ammonium Chloride as a New Difluorocarbene Source. 中国化学:英文版[J]. 2011, 29(12): 2717-2721, http://lib.cqvip.com/Qikan/Article/Detail?id=40185183.
[202] 赵延川, 张丽君, 许国峰, 郑吉, 胡金波. 以二氟烷基磺酸修饰的聚降冰片烯为基础的聚合物电解质薄膜的制备. 中国科学:化学[J]. 2011, 41(12): 1833-1839, http://lib.cqvip.com/Qikan/Article/Detail?id=40208280.
[203] Zhu JieMing, Wang Fei, Hu JinBo. Free radical fluoroalkylation of terminal alkenes and alkynes with iododifluoromethanesulfonamides. SCIENCE CHINA-CHEMISTRY[J]. 2011, 54(1): 95-102, http://www.irgrid.ac.cn/handle/1471x/594221.
[204] Zhu, Jieming, Wang, Fei, Huang, Weizhou, Zhao, Yanchuan, Ye, Wenchao, Hu, Jinbo. Copper-Mediated Fluoroalkylation Reactions with (Phenylsulfonyl)-difluoromethyltrimethylsilane: Synthesis of PhSO2CF2-Containing Allenes and Alkynes. SYNLETT[J]. 2011, 899-902, http://ir.sioc.ac.cn/handle/331003/24091.
[205] Wang, Fei, Zhang, Laijun, Zheng, Ji, Hu, Jinbo. Chlorodifluoromethyl aryl ketones and sulfones as difluorocarbene reagents: The substituent effect. JOURNAL OF FLUORINE CHEMISTRY[J]. 2011, 132(8): 521-528, http://dx.doi.org/10.1016/j.jfluchem.2011.05.009.
[206] Wang, Fei, Zhang, Wei, Zhu, Jieming, Li, Huaifeng, Huang, KuoWei, Hu, Jinbo. Chloride ion-catalyzed generation of difluorocarbene for efficient preparation of gem-difluorinated cyclopropenes and cyclopropanes. CHEMICAL COMMUNICATIONS[J]. 2011, 47(8): 2411-2413, http://www.irgrid.ac.cn/handle/1471x/594220.
[207] 赵延川, 张丽君, 许国峰, 郑吉, 胡金波. 以二氟烷基磺酸修饰的聚降冰片烯为基础的聚合物电解质薄膜的制备. 中国科学: 化学[J]. 2011, 41(12): 1833-1839, http://ir.sioc.ac.cn/handle/331003/24081.
[208] Wang Fei, Huang Weizhou, Hu Jinbo. Difluoromethylation of O-, S-, N-, C-Nucleophiles Using Difluoromethyltri(n-butyl)ammonium Chloride as a New Difluorocarbene Source. CHINESE JOURNAL OF CHEMISTRY[J]. 2011, 29(12): 2717-2721, http://lib.cqvip.com/Qikan/Article/Detail?id=40185183.
[209] Ni, Chuanfa, Hu, Jinbo. Selective Nucleophilic Fluoroalkylations Facilitated by Removable Activation Groups. SYNLETT[J]. 2011, 770-782, http://www.irgrid.ac.cn/handle/1471x/594223.
[210] Zhao, Yanchuan, Huang, Weizhou, Zheng, Ji, Hu, Jinbo. Efficient and Direct Nucleophilic Difluoromethylation of Carbonyl Compounds and Imines with Me3SiCF2H at Ambient or Low Temperature. ORGANIC LETTERS[J]. 2011, 13(19): 5342-5345, http://ir.sioc.ac.cn/handle/331003/24099.
[211] Shen, Xiao, Zhang, Laijun, Zhao, Yanchuan, Zhu, Lingui, Li, Guangyu, Hu, Jinbo. Nucleophilic Fluoromethylation of Aldehydes with Fluorobis(phenylsulfonyl) methane: The Importance of Strong Li-O Coordination and Fluorine Substitution for C-C Bond Formation. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2011, 50(11): 2588-2592, http://www.irgrid.ac.cn/handle/1471x/594219.
[212] Hu, Jinbo. Development of new fluoroalkylation and fluoroolefination methods. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETYnull. 2011, 242: https://www.webofscience.com/wos/woscc/full-record/WOS:000299378302868.
[213] Zhu, Jieming, Wang, Fei, Huang, Weizhou, Zhao, Yanchuan, Ye, Wenchao, Hu, Jinbo. Copper-Mediated Fluoroalkylation Reactions with (Phenylsulfonyl)-difluoromethyltrimethylsilane: Synthesis of PhSO2CF2-Containing Allenes and Alkynes. SYNLETT[J]. 2011, 899-902, http://ir.sioc.ac.cn/handle/331003/24091.
[214] Prakash, G K Surya, Ni, Chuanfa, Wang, Fang, Hu, Jinbo, Olah, George A. From Difluoromethyl 2-Pyridyl Sulfone to Difluorinated Sulfonates: A Protocol for Nucleophilic Difluoro(sulfonato)methylation. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2011, 50(11): 2559-2563, http://www.irgrid.ac.cn/handle/1471x/594218.
[215] Wang, Fei, Luo, Tao, Hu, Jinbo, Wang, Ying, Krishnan, Hema S, Jog, Parag V, Ganesh, Somesh K, Prakash, G K Surya, Olah, George A. Synthesis of gem-Difluorinated Cyclopropanes and Cyclopropenes: Trifluoromethyltrimethylsilane as a Difluorocarbene Source. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2011, 50(31): 7153-7157, http://www.irgrid.ac.cn/handle/1471x/594225.
[216] Zhu, Lingui, Ni, Chuanfa, Zhao, Yanchuan, Hu, Jinbo. 1-tert-Butyl-1H-tetrazol-5-yl fluoromethyl sulfone (TBTSO2CH2F): a versatile fluoromethylidene synthon and its use in the synthesis of monofluorinated alkenes via Julia-Kocienski olefination. TETRAHEDRON[J]. 2010, 66(27-28): 5089-5100, http://dx.doi.org/10.1016/j.tet.2010.04.113.
[217] Zhu, Jieming, Zhang, Wei, Zhang, Laijun, Liu, Jun, Zheng, Ji, Hu, Jinbo. Copper-Mediated Fluoroalkylation Reactions with Iododifluoroacetamides: Controlling the Selectivity among Cross-Coupling, Intramolecular Cyclization, and Homocoupling Reactions. JOURNAL OF ORGANIC CHEMISTRY[J]. 2010, 75(16): 5505-5512, http://www.irgrid.ac.cn/handle/1471x/594211.
[218] Liu, Jun, Hu, Jinbo. Highly Diastereoselective Synthesis of alpha-Difluoromethyl Amines from N-tert-Butylsulfinyl Ketimines and Difluoromethyl Phenyl Sulfone. CHEMISTRY-A EUROPEAN JOURNAL[J]. 2010, 16(37): 11443-11454, http://www.irgrid.ac.cn/handle/1471x/594210.
[219] Zhao, Yanchuan, Zhu, Jieming, Ni, Chuanfa, Hu, Jinbo. Magnesium Metal-Mediated Reductive Trifluoromethylation of Aldehydes with Phenyl Trifluoromethyl Sulfone. SYNTHESIS-STUTTGART[J]. 2010, 1899-1904, http://www.irgrid.ac.cn/handle/1471x/594213.
[220] Zemtsov, Artem A, Levin, Vitalij V, Dilman, Alexander D, Struchkova, Marina I, Belyakov, Pavel A, Tartakovsky, Vladimir A, Hu, Jinbo. Reaction of Baylis-Hillman Adducts with Fluorinated Silanes. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY[J]. 2010, 2010(35): 6779-6785, http://www.irgrid.ac.cn/handle/1471x/594216.
[221] Zhang, Wei, Hu, Jinbo. Efficient Synthesis and Ring-Opening Reactions of Monofluorinated Epoxides Derived from alpha-Fluorosulfoximines. ADVANCED SYNTHESIS & CATALYSIS[J]. 2010, 352(16): 2799-2804, http://www.irgrid.ac.cn/handle/1471x/594209.
[222] Zhu, Lingui, Li, Ya, Zhao, Yanchuan, Hu, Jinbo. Nucleophilic (phenylsulfonyl)difluoromethylation of alkyl halides using PhSO2CF2SiMe3: preparation of gem-difluoroalkenes and trifluoromethyl compounds. TETRAHEDRON LETTERS[J]. 2010, 51(47): 6150-6152, http://dx.doi.org/10.1016/j.tetlet.2010.09.068.
[223] Zhao, Yanchuan, Huang, Weizhou, Zhu, Lingui, Hu, Jinbo. Difluoromethyl 2-Pyridyl Sulfone: A New gem-Difluoroolefination Reagent for Aldehydes and Ketones. ORGANIC LETTERS[J]. 2010, 12(7): 1444-1447, http://www.irgrid.ac.cn/handle/1471x/594214.
[224] Ni, Chuanfa, Zhang, Laijun, Hu, Jinbo. Synthesis of Fluorinated beta-Ketosulfones and gem-Disulfones by Nucleophilic Fluoroalkylation of Esters and Sulfinates with Di- and Monofluoromethyl Sulfones. JOURNAL OF ORGANIC CHEMISTRY[J]. 2009, 74(10): 3767-3771, http://www.irgrid.ac.cn/handle/1471x/594200.
[225] Hu, Jinbo, Zhang, Wei, Wang, Fei. Selective difluoromethylation and monofluoromethylation reactions. CHEMICAL COMMUNICATIONS[J]. 2009, Unassigned(48): 7465-7478, http://www.irgrid.ac.cn/handle/1471x/594205.
[226] Zhang, Wei, Huang, Weizhou, Hu, Jinbo. Highly Stereoselective Synthesis of Monofluoroalkenes from alpha-Fluorosulfoximines and Nitrones. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2009, 48(52): 9858-9861, https://www.webofscience.com/wos/woscc/full-record/WOS:000273452200015.
[227] Li, Ya, Li, Huaifeng, Hu, Jinbo. Free radical (phenylsulfonyl)difluoromethylation of alkynes with PhSO2CF2I reagent: stereoselective preparation of PhSO2CF2- and CF2H-substituted alkenes. TETRAHEDRON[J]. 2009, 65(2): 478-483, http://dx.doi.org/10.1016/j.tet.2008.11.011.
[228] Wang Fei, Hu Jinbo. Bronsted Acid Mediated (sp(3))Carbon-Fluorine Bond Activation: Inter- and Intramolecular Arylation of Trifluoromethylated Arenes. CHINESE JOURNAL OF CHEMISTRY[J]. 2009, 27(1): 93-98, http://www.irgrid.ac.cn/handle/1471x/594202.
[229] Zhang, Wei, Wang, Fei, Hu, Jinbo. N-Tosyl-S-difluoromethyl-S-phenylsulfoximine: A New Difluoromethylation Reagent for S-, N-, and C-Nucleophiles. ORGANIC LETTERS[J]. 2009, 11(10): 2109-2112, http://www.irgrid.ac.cn/handle/1471x/594199.
[230] Hu, Jinbo. Nucleophilic, radical, and electrophilic (phenylsulfonyl)difluoromethylations. JOURNAL OF FLUORINE CHEMISTRY[J]. 2009, 130(12): 1130-1139, http://dx.doi.org/10.1016/j.jfluchem.2009.05.016.
[231] Liu, Jun, Hu, Jinbo. Synthesis of fluorinated chiral amines using N-tert-butylsulfinyl imines. FUTURE MEDICINAL CHEMISTRY[J]. 2009, 1(5): 875-888, http://www.irgrid.ac.cn/handle/1471x/594206.
[232] Zhang, Laijun, Zhang, Wei, Liu, Jun, Hu, Jinbo. C-F Bond Cleavage by Intramolecular S(N)2 Reaction of Alkyl Fluorides with O- and N-Nucleophiles. JOURNAL OF ORGANIC CHEMISTRY[J]. 2009, 74(7): 2850-2853, http://www.irgrid.ac.cn/handle/1471x/594201.
[233] Ni, Chuanfa, Hu, Jinbo. Palladium/acetic acid-catalyzed fluoroalkylation of alkynes with monofluorinated sulfones as pronucleophiles. TETRAHEDRON LETTERS[J]. 2009, 50(52): 7252-7255, http://dx.doi.org/10.1016/j.tetlet.2009.09.126.
[234] 张伟, 黄维洲, 胡金波. Highly Stereoselective Synthesis of Monofluoroalkenes from α-Fluorosulfoximines and Nitrones. Angew. Chem.-Int. Edit.[J]. 2009, 48(52): 9858-9861, http://ir.sioc.ac.cn/handle/331003/24063.
[235] Liu, Jun, Ni, Chuanfa, Wang, Fang, Hu, Jinbo. Stereoselective synthesis of alpha-difluoromethyl-beta-amino alcohols via nucleophilic difluoromethylation with Me3SiCF2SO2Ph. TETRAHEDRON LETTERS[J]. 2008, 49(10): 1605-1608, http://ir.sioc.ac.cn/handle/331003/24041.
[236] Li, Ya, Hu, Jinbo. Fluoride ion-mediated nucleophilic fluoroalkylation of alkyl halides with Me(3)SiCF(2)SPh: Synthesis of PhSCF(2)- and CF(2)H-containing compounds. JOURNAL OF FLUORINE CHEMISTRY[J]. 2008, 129(5): 382-385, http://dx.doi.org/10.1016/j.jfluchem.2008.01.010.
[237] 刘俊, 倪传法, 王方, 胡金波. Stereoselective synthesis of alpha-difluoromethyl-beta-amino alcohols via nucleophilic difluoromethylation with Me3SiCF2SO2Ph. Tetrahedron Lett.[J]. 2008, 49(10): 1605-1608, http://ir.sioc.ac.cn/handle/331003/24041.
[238] Hu, Jinbo. FLUO 30-Stereoselective synthesis of partially fluorinated amines with fluorinated organosulfur reagents. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETYnull. 2008, 236: https://www.webofscience.com/wos/woscc/full-record/WOS:000270256304579.
[239] Zhang, Wei, Zhu, Jieming, Hu, Jinbo. Electrophilic (phenylsulfonyl)difluoromethylation of thiols with a hypervalent iodine(III)-CF2SO2Ph reagent. TETRAHEDRON LETTERS[J]. 2008, 49(34): 5006-5008, http://dx.doi.org/10.1016/j.tetlet.2008.06.064.
[240] Ni, Chuanfa, Zhang, Laijun, Hu, Jinbo. Nucleophilic fluoroalkylation of alpha,beta-enones, arynes, and activated alkynes with fluorinated sulfones: Probing the hard/soft nature of fluorinated carbanions. JOURNAL OF ORGANIC CHEMISTRY[J]. 2008, 73(15): 5699-5713, http://www.irgrid.ac.cn/handle/1471x/594194.
[241] 李亚, 胡金波. Fluoride ion-mediated nucleophilic fluoroalkylation of alkyl halides with Me3SiCF2SPh: Synthesis of PhSCF2- and CF2H-containing compounds. J. Fluor. Chem.[J]. 2008, 129(5): 382-385, http://dx.doi.org/10.1016/j.jfluchem.2008.01.010.
[242] Liu, Jun, Zhang, Laijun, Hu, Jinbo. Stereoselective Monofluoromethylation of N-tert-Butylsulfinyl Ketimines Using Pregenerated Fluoro(phenylsulfonyl)methyl Anion. ORGANIC LETTERS[J]. 2008, 10(23): 5377-5380, http://www.irgrid.ac.cn/handle/1471x/594198.
[243] Ni, Chuanfa, Wang, Fang, Hu, Jinbo. Enantioselective nucleophilic difluoromethylation of aromatic aldehydes with Me3SiCF2SO2Ph and PhSO2CF2H reagents catalyzed by chiral quaternary ammonium salts. BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY[J]. 2008, 4(1): http://www.irgrid.ac.cn/handle/1471x/594195.
[244] Mogi, Ryo, Morisaki, Kazuo, Hu, Jinbo, Prakash, G K Surya, Olah, George A. Synthesis of 1,1-difluoroethylsilanes and their application for the introduction of the 1,1-difluoroethyl group. JOURNAL OF FLUORINE CHEMISTRY[J]. 2007, 128(10): 1098-1103, http://dx.doi.org/10.1016/j.jfluchem.2007.03.013.
[245] Li, Ya, Liu, Jun, Zhang, Laijun, Zhu, Lingui, Hu, Jinbo. Radical (phenylsulfonyl)difluoromethylation with iododifluoromethyl phenyl sulfone. JOURNAL OF ORGANIC CHEMISTRY[J]. 2007, 72(15): 5824-5827, http://www.irgrid.ac.cn/handle/1471x/594185.
[246] Zhang, Wei, Zhu, Lingui, Hu, Jinbo. Electrophilic monofluoromethylation of O-nucleophiles, S-nucleophiles, and N-nucleophiles with chlorofluoromethane. TETRAHEDRON[J]. 2007, 63(43): 10569-10575, https://www.webofscience.com/wos/woscc/full-record/WOS:000252092400001.
[247] Li, Ya, Hu, Jinbo. Stereoselective difluoromethylenation using Me3SiCF2SPh: Synthesis of chiral 2,4-disubstituted 3,3-difluoropyrrolidines. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2007, 46(14): 2489-2492, http://www.irgrid.ac.cn/handle/1471x/594187.
[248] Ni, Chuanfa, Liu, Jun, Zhang, Laijun, Hu, Jinbo. A remarkably efficient fluoroalkylation of cyclic sulfates and sulfamidates with PhSO2CF2H: Facile entry into beta-difluoromethylated or beta-difluoromethylenated alcohols and amines. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2007, 46(5): 786-789, http://www.irgrid.ac.cn/handle/1471x/594188.
[249] Zhang, Laijun, Li, Ya, Hu, Jinbo. Preparation of 1-aryl-2,2-difluoro enol esters via dehydrosulfonylation of alpha-(phenylsulfonyl)difluoromethylated benzoates. JOURNAL OF FLUORINE CHEMISTRY[J]. 2007, 128(7): 755-761, http://www.irgrid.ac.cn/handle/1471x/594184.
[250] 张伟, 朱林桂, 胡金波. Electrophilic Monofluoromethylation of O-, S-, N-Nucleophiles with Chlorofluoromethane. Tetrahedron[J]. 2007, 63(43): 10569-10575, http://ir.sioc.ac.cn/handle/331003/24027.
[251] Zhu, Lingui, Li, Ya, Ni, Chuanfa, Hu, Jinbo, Beier, Petr, Wang, Ying, Prakash, G K Surya, Olah, George A. Nucleophilic (phenylsulfinyl)difluoromethylation of carbonyl compounds with difluoromethyl phenyl sulfoxide. JOURNAL OF FLUORINE CHEMISTRY[J]. 2007, 128(10): 1241-1247, http://dx.doi.org/10.1016/j.jfluchem.2007.05.003.
[252] 郑吉, 李亚, 张来俊, 胡金波, Meuzalaar, Federsel. Chlorodifluoromethyl Phenyl Sulfone: A Novel Non-ODS-Based Difluorocarbene Reagent for O- and N-Difluoromethylations. Chem. Commun.[J]. 2007, 5149-5151, http://ir.sioc.ac.cn/handle/331003/24025.
[253] Liu, Jun, Li, Ya, Hu, Jinbo. Stereoselective synthesis of di- and monofluoromethylated vicinal ethylenediamines with di- and monofluoromethyl sulfones. JOURNAL OF ORGANIC CHEMISTRY[J]. 2007, 72(8): 3119-3121, http://www.irgrid.ac.cn/handle/1471x/594186.
[254] Zhang, Laijun, Zheng, Ji, Hu, Jinbo. 2-chloro-2,2-difluoroacetophenone: A non-ODS-based difluorocarbene precursor and its use in the difluoromethylation of phenol derivatives. JOURNAL OF ORGANIC CHEMISTRY[J]. 2006, 71(26): 9845-9848, http://www.irgrid.ac.cn/handle/1471x/594182.
[255] Ni, Chuanfa, Li, Ya, Hu, Jinbo. Nucleophilic fluoroalkylation of epoxides with fluorinated sulfones. JOURNAL OF ORGANIC CHEMISTRY[J]. 2006, 71(18): 6829-6833, http://www.irgrid.ac.cn/handle/1471x/594180.
[256] Liu, Jun, Ni, Chuanfa, Li, Ya, Zhang, Laijun, Wang, Guanyu, Hu, Jinbo. Facile preparation of difluoromethyl- and monofluoromethyl-containing amides via Ritter reaction. TETRAHEDRON LETTERS[J]. 2006, 47(38): 6753-6756, http://dx.doi.org/10.1016/j.tetlet.2006.07.079.
[257] 倪传法, 胡金波. Nucleophilic Difluoromethylation of Carbonyl Compounds Using TMSCF2SO2Ph and Mg0-Mediated Desulfonylation. Tetrahedron Lett.[J]. 2005, 46(48): 8273-8277, http://ir.sioc.ac.cn/handle/331003/24001.
[258] Prakash, GKS, WANG YING, 胡金波, Olah, GA. Nucleophilic Difluoromethylation and Difluoromethylenation Using Bromodifluoromethyl Phenyl Sulfon. J. Fluor. Chem.[J]. 2005, 126(9-10): 1361-1367, http://ir.sioc.ac.cn/handle/331003/24003.
[259] Prakash, GKS, 胡金波, WANG YING, Olah, GA. Convenient synthesis of difluoromethyl alcohols from both enolizable and non-enolizable carbonyl compounds with difluoromethyl phenyl sulfone difluoromethylation; fluorine; reductive desulfonylation. Eur. J. Org. Chem.[J]. 2005, 2218-2223, http://ir.sioc.ac.cn/handle/331003/23999.

指导学生

已指导学生

李亚  博士研究生  070303-有机化学  

倪传法  博士研究生  070303-有机化学  

朱林桂  博士研究生  070303-有机化学  

张来俊  博士研究生  070303-有机化学  

刘俊  博士研究生  070303-有机化学  

朱杰明  博士研究生  070303-有机化学  

张伟  博士研究生  070303-有机化学  

王飞  博士研究生  070303-有机化学  

现指导学生

黄维洲  博士研究生  070303-有机化学  

高兵  硕士研究生  070303-有机化学  

罗涛  硕士研究生  070303-有机化学  

赵延川  博士研究生  070303-有机化学  

何正标  博士研究生  070303-有机化学  

叶文超  博士研究生  070303-有机化学  

胡明友  博士研究生  070303-有机化学  

沈晓  博士研究生  070303-有机化学