081705-工业催化

天然气转化和利用，二氧化碳转化和利用
工业催化
高温材料

2007-06--2010-06   山西煤化所   博士

   

2014-01~2019-11,中国科学院上海高等研究院, 副研究员
2010-07~2013-12,中科院上海高等研究院, 助理研究员

   

[1] 张军, 孙予罕, 李树青, 刘曙光, 陆娜. 氮化铝基催化剂及其制备方法和用途. CN113663714A, 2021-11-19.
[2] 张军, 黄金成, 付彧, 孙予罕. 一种自调节铁氧体材料及其制备方法和应用. CN: CN108163898B, 2020-12-04.
[3] 孔文波, 孙予罕, 张军. 甲烷干重整催化剂及其制备方法和用途. CN: CN107790170B, 2020-11-27.
[4] 黄金成, 孙予罕, 张军, 付彧. 铁酸盐类储氧材料及其前体和用途. CN: CN107649133B, 2020-11-20.
[5] 张军, 孙予罕, 孔文波, 刘曙光, 陆娜. 具有双合金复合微介孔结构的催化剂、制备方法及应用. CN: CN111001408A, 2020-04-14.
[6] 孔文波, 孙予罕, 张军. 镓铟锡金属催化剂、制备方法及应用. CN: CN110975925A, 2020-04-10.
[7] 张军, 蔡夫锋, 孙予罕. 一种铜基催化剂、制备方法及应用. CN: CN110787809A, 2020-02-14.
[8] 孙予罕, 张军, 李树青, 刘曙光, 陆娜. 一种以纳米氢氧化铝为粘结剂的氮化铝基催化剂及其制备方法. CN: CN110756214A, 2020-02-07.
[9] 张军, 孙予罕, 李树青, 刘曙光, 陆娜. 一种氮化铝基催化剂、制备方法及应用. CN: CN110756213A, 2020-02-07.
[10] 孙予罕, 付彧, 张军. 一种用于甲烷三重整反应的高负载量催化剂及其制备方法和用途. CN: CN107008328B, 2019-10-22.
[11] 张军, 蔡夫锋, 孙予罕. 一种甲醇重整制氢催化剂及其制备方法. CN: CN110075889A, 2019-08-02.
[12] 孙予罕, 袁昌坤, 张军. 一种用于甲烷三重整反应的高强度多级孔催化剂及其制备方法. CN: CN106799263B, 2019-03-22.
[13] 孙予罕, 袁昌坤, 张军, 李晋平, 肖亚宁, 黄巍, 孙志强, 王东飞, 孔文波, 潘秉荣. 一种高分散高负载高活性低温甲烷重整镍基催化剂及其应用. 中国: CN105688916B, 2018-10-26.
[14] 张军, 黄金成, 付彧, 孙予罕. 一种双层钙钛矿型储氧材料及其制备方法和应用. 中国: CN108313978A, 2018-07-24.
[15] 孙予罕, 张军, 黄金成, 付彧. 一种两步甲烷‑二氧化碳重整制备醋酸原料气的方法. 中国: CN105502288B, 2017.10.03.
[16] 孙予罕, 祝艳, 陈陆飞, 张军. 二维多孔NiCo 2 O 4 及其制备方法及应用. 中国: CN106966440A, 2017-07-21.
[17] 孙予罕, 付彧, 张军. 一种动态铁酸盐储氧材料及其应用. 中国: CN105126852A, 2015-12-09.
[18] 孙予罕, 李晋平, 肖亚宁, 张军, 孔文波, 潘秉荣, 赵铁均, 黄巍, 孙志强, 王东飞. 镍基催化剂及其成型方法与应用. 中国: CN104399471A, 2015-03-11.
[19] 孙予罕, 李晋平, 肖亚宁, 张军, 陈庆军, 孔文波, 潘秉荣, 赵铁均, 黄巍, 孙志强, 王东飞. 纳米复合物催化剂及其制备方法与应用. 中国: CN104258864A, 2015-01-07.
[20] 孙予罕, 李晋平, 肖亚宁, 张军, 孔文波, 潘秉荣, 赵铁均, 黄巍, 孙志强, 王东飞. 多相镍基催化剂及其制备方法与应用. 中国: CN104190427A, 2014-12-10.
[21] 孙予罕, 李晋平, 肖亚宁, 张军, 孔文波, 潘秉荣, 赵铁均, 黄巍, 孙志强, 王东飞. 用于制合成气或者制氢的催化剂及其制法和应用. 中国: CN104084211A, 2014-10-08.
[22] 孙予罕, 陈庆军, 张军, 赵铁均, 黄巍, 孙志强, 王东飞. 高度分散的纳米复合物催化剂及其制备方法和应用. 中国: CN103143364A, 2013-06-12.
[23] 孙予罕, 魏伟, 王慧, 张军. 一种甲烷-二氧化碳重整反应催化剂及其制备方法. 中国: CN102151570A, 2011-08-17.

   

[1] 王济阳, 张军, 付彧. Investigation of Atom-Level Reaction Kinetics of Carbon-Resistant Bimetallic NiCo-Reforming Catalysts: Combining Microkinetic Modeling and Density Functional Theory. Acs Catalysis[J]. 2022, [2] 白洁茹, 张军. The Design of Ni‐substituted La2(CeZrNi)2O7 Pyrochlore Catalysts for Methane Dry Reforming. ChemNanoMat[J]. 2022, [3] Cai, Fufeng, Guo, Yanjiao, Ibrahim, Jessica Juweriah, Zhang, Jun, Sun, Yuhan. A highly active and stable Pd/MoC catalyst for hydrogen production from methanol decomposition. APPLIED CATALYSIS B-ENVIRONMENTAL[J]. 2021, 299: http://dx.doi.org/10.1016/j.apcatb.2021.120648.
[4] Kong, Wenbo, Fu, Yu, Shi, Lei, Li, Shenggang, Vovk, Evgeny, Zhou, Xiaohong, Si, Rui, Pan, Bingrong, Yuan, Changkun, Li, Shuqing, Cai, Fufeng, Zhu, He, Zhang, Jun, Yang, Yong, Sun, Yuhan. Nickel nanoparticles with interfacial confinement mimic noble metal catalyst in methane dry reforming. APPLIED CATALYSIS B-ENVIRONMENTAL[J]. 2021, 285: http://dx.doi.org/10.1016/j.apcatb.2020.119837.
[5] Wang, Jiyang, Fu, Yu, Kong, Wenbo, Jin, Feikai, Bai, Jieru, Zhang, Jun, Sun, Yuhan. Design of a carbon-resistant Ni@S-2 reforming catalyst: Controllable Ni nanoparticles sandwiched in a peasecod-like structure. APPLIED CATALYSIS B-ENVIRONMENTAL[J]. 2021, 282: http://dx.doi.org/10.1016/j.apcatb.2020.119546.
[6] Guan, Cairu, Yang, Yong, Pang, Yaoqi, Liu, Zebang, Li, Shenggang, Vovk, Evgeny I, Zhou, Xiaohong, Li, Jerry Pui Ho, Zhang, Jun, Yu, Na, Long, Liuliu, Hao, Jie, van Bavel, Alexander P. How CO2 poisons La2O3 in an OCM catalytic reaction: A study by in situ XRD-MS and DFT. JOURNAL OF CATALYSIS[J]. 2021, 396: 202-214, http://dx.doi.org/10.1016/j.jcat.2021.02.017.
[7] Huang, Jincheng, Fu, Yu, Zhao, Yonghui, Zhang, Jun, Li, Shuqing, Li, Shenggang, Li, Guijun, Chen, Zhenpan, Sun, Yuhan. Anti-sintering non-stoichiometric nickel ferrite for highly efficient and thermal-stable thermochemical CO2 splitting. CHEMICAL ENGINEERING JOURNAL[J]. 2021, 404: http://dx.doi.org/10.1016/j.cej.2020.127067.
[8] Fu, Yu, Kong, Wenbo, Pan, Bingrong, Yuan, Changkun, Li, Shuqing, Zhu, He, Zhang, Jun. In situ redispersion of rhodium nanocatalyst for CO2 reforming of CH4. JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING[J]. 2021, 9(4): http://dx.doi.org/10.1016/j.jece.2021.105790.
[9] Hao, Jie, Cai, Fufeng, Wang, Jiyang, Fu, Yu, Zhang, Jun, Sun, Yuhan. The effect of oxygen vacancy of alkaline-earth metal Sr doped Sm2Zr2O7 catalysts in the oxidative coupling of methane. CHEMICAL PHYSICS LETTERS[J]. 2021, 771: http://dx.doi.org/10.1016/j.cplett.2021.138562.
[10] Li, Shuqing, Fu, Yu, Kong, Wenbo, Pan, Bingrong, Yuan, Changkun, Cai, Fufeng, Zhu, He, Zhang, Jun, Sun, Yuhan. Dually confined Ni nanoparticles by room-temperature degradation of AlN for dry reforming of methane. APPLIED CATALYSIS B-ENVIRONMENTAL[J]. 2020, 277: http://dx.doi.org/10.1016/j.apcatb.2020.118921.
[11] Kong, Wenbo, Fu, Yu, Zhang, Jun, Sun, Yuhan. Stabilized Ni nanoparticles derived from silicate via hydrothermal method for carbon dioxide reforming of methane. CHEMICAL PHYSICS LETTERS[J]. 2020, 739: http://dx.doi.org/10.1016/j.cplett.2019.137027.
[12] Cai, Fufeng, Ibrahim, Jessica Juweriah, Fu, Yu, Kong, Wenbo, Zhang, Jun, Sun, Yuhan. Low-temperature hydrogen production from methanol steam reforming on Zn-modified Pt/MoC catalysts. APPLIED CATALYSIS B-ENVIRONMENTAL[J]. 2020, 264: http://dx.doi.org/10.1016/j.apcatb.2019.118500.
[13] Cai, Fufeng, Lu, Peijing, Ibrahim, Jessica Juweriah, Fu, Yu, Zhang, Jun, Sun, Yuhan. Investigation of the role of Nb on Pd-Zr-Zn catalyst in methanol steam reforming for hydrogen. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY[J]. 2019, 44(23): 11717-11733, https://www.webofscience.com/wos/woscc/full-record/WOS:000468710100033.
[14] Kong, Wenbo, Fu, Yu, Guan, Cairu, Pan, Bingrong, Yuan, Changkun, Li, Shuqing, Cai, Fufeng, Zhang, Jun, Sun, Yuhan. Facile Synthesis of Highly Coking-Resistant and Active Nickel-Based Catalyst for Low-Temperature CO2 Reforming of Methane. ENERGY TECHNOLOGY[J]. 2019, 7(9): http://dx.doi.org/10.1002/ente.201900521.
[15] Huang, Jincheng, Fu, Yu, Li, Shuqing, Kong, Wenbo, Zhang, Jun, Sun, Yuhan. Cobalt-based ferrites as efficient redox materials for thermochemical two-step CO2-splitting: enhanced performance due to cation diffusion. SUSTAINABLE ENERGY & FUELS[J]. 2019, 3(4): 975-984, http://dx.doi.org/10.1039/c8se00611c.
[16] 卢培静, 蔡夫锋, 张军, 刘予宇, 孙予罕. Hydrogen production from methanol steam reforming over B-modified CuZnAlOx catalysts. Journal of Fuel Chemistry and Technology[J]. 2019, 47(7): 791-798, http://dx.doi.org/10.1016/S1872-5813(19)30035-0.
[17] 刘俊义, 祝贺, 张军. 甲烷二氧化碳自热重整工艺分析. 天然气化工. C1化学与化工[J]. 2019, 44(3): 56-60, [18] Huang, Jincheng, Fu, Yu, Kong, Wenbo, Zhang, Jun, Sun, Yuhan. Differences in the Nature of Reaction Process for Thermochemical CO2 Splitting over NiFe2O4-Based Materials. ENERGY TECHNOLOGY[J]. 2019, 7(5): http://dx.doi.org/10.1002/ente.201800523.
[19] Zhang, Jun, Zeng, Gaofeng, Li, Xiaopeng, Sun, Yuhan. Methane conversion and utilization via catalysis. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETYnull. 2019, 257: [20] Jincheng Huang, Yu Fu, Shenggang Li, Wenbo Kong, Jun Zhang, Yuhan Sun. Enhanced activity of MgsbndFesbndO ferrites for two-step thermochemical CO2 splitting. Journal of CO2 Utilization. 2018, 27: 450-458, http://dx.doi.org/10.1016/j.jcou.2018.08.007.
[21] Huang, Jincheng, Fu, Yu, Li, Shenggang, Kong, Wenbo, Zhang, Jun, Sun, Yuhan. Enhanced activity of Mg-Fe-O ferrites for two-step thermochemical CO2 splitting (vol 26, pg 544, 2018). JOURNAL OF CO2 UTILIZATIONnull. 2018, 27: 414-414, https://www.webofscience.com/wos/woscc/full-record/WOS:000445035500042.
[22] Cai, Fufeng, Pan, Donghui, Ibrahim, Jessica Juweriah, Zhang, Jun, Xiao, Guomin. Hydrogenolysis of glycerol over supported bimetallic Ni/Cu catalysts with and without external hydrogen addition in a fixed-bed flow reactor. APPLIED CATALYSIS A-GENERAL[J]. 2018, 564: 172-182, http://dx.doi.org/10.1016/j.apcata.2018.07.029.
[23] Huang, Jincheng, Fu, Yu, Li, Shenggang, Kong, Wenbo, Zhang, Jun, Sun, Yuhan. Enhanced activity of Mg-Fe-O ferrites for two-step thermochemical CO2 splitting. JOURNAL OF CO2 UTILIZATION[J]. 2018, 27: 450-458, http://dx.doi.org/10.1016/j.jcou.2018.06.014.
[24] 柴应洁, 冯鹤, 崔艳斌, 刘俊义, 张军. 镍基钙钛矿型催化剂的结构调控及其在甲烷干重整反应中的应用. 分子催化[J]. 2018, 228-239, http://lib.cqvip.com/Qikan/Article/Detail?id=70906772504849564851484855.
[25] 张军. Differences in the nature of reaction process for thermochemical CO2 splitting over NiFe2O4 based materials. Energy Technology. 2018, [26] Chen, Qingjun, Zhang, Jun, Pan, Bingrong, Kong, Wenbo, Chen, Yuyun, Zhang, Weili, Sun, Yuhan. Temperature-dependent anti-coking behaviors of highly stable Ni-CaO-ZrO2 nanocomposite catalysts for CO2 reforming of methane. CHEMICAL ENGINEERING JOURNAL[J]. 2017, 320: 63-73, http://dx.doi.org/10.1016/j.cej.2017.03.029.
[27] Xu, Jiayu, Xiao, Qinglin, Zhang, Jun, Sun, Yuhan, Zhu, Yan. NiO-MgO nanoparticles confined inside SiO2 frameworks to achieve highly catalytic performance for CO2 reforming of methane. MOLECULAR CATALYSIS[J]. 2017, 432: 31-36, http://dx.doi.org/10.1016/j.mcat.2017.02.019.
[28] Sun, Yongnan, Shen, Yue, Song, Jianjun, Ba, Rongbin, Huang, Shuangshuang, Zhao, Yonghui, Zhang, Jun, Sun, Yuhan, Zhu, Yan. Facet-Controlled CeO2 Nanocrystals for Oxidative Coupling of Methane. JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY[J]. 2016, 16(5): 4692-4700, http://www.corc.org.cn/handle/1471x/2233181.
[29] Fu, Yu, Li, Shenggang, Zhang, Jun, Sun, Yuhan. Effective Macroporous Core-Shell Structure of Alumina-Supported Spinel Ferrite for Carbon Dioxide Splitting Based on Chemical Looping. ENERGY TECHNOLOGY[J]. 2016, 4(11): 1349-1357, [30] Fu, Yu, Zhang, Jun, Li, Shenggang, Huang, Jincheng, Sun, Yuhan. Self-regeneration of ferrites incorporated into matched matrices for thermochemical CO2 splitting. JOURNAL OF MATERIALS CHEMISTRY A[J]. 2016, 4(14): 5026-5031, https://www.webofscience.com/wos/woscc/full-record/WOS:000373119500003.
[31] Jiang, Tao, Song, Jianjun, Huo, Minfeng, Yang, NaTing, Liu, Jingwei, Zhang, Jun, Sun, Yuhan, Zhu, Yan. La2O3 catalysts with diverse spatial dimensionality for oxidative coupling of methane to produce ethylene and ethane. RSC ADVANCES[J]. 2016, 6(41): 34872-34876, https://www.webofscience.com/wos/woscc/full-record/WOS:000374049700093.
[32] 张军. Effective macroporous core-shell structure of NiFe2O4 Al2O3 for CO2 splitting based on chemical looping. ENERGY TECHNOLOGY. 2016, [33] Song, Jianjun, Sun, Yongnan, Ba, Rongbin, Huang, Shuangshuang, Zhao, Yonghui, Zhang, Jun, Sun, Yuhan, Zhu, Yan. Monodisperse Sr-La2O3 hybrid nanofibers for oxidative coupling of methane to synthesize C-2 hydrocarbons. NANOSCALE[J]. 2015, 7(6): 2260-2264, http://www.corc.org.cn/handle/1471x/2269939.
[34] 康敏, 张军, 赵宁, 魏伟, 孙予罕. 铁酸镍用于热化学循环反应CO2分解制CO的研究. 燃料化学学报[J]. 2014, 68-73, http://lib.cqvip.com/Qikan/Article/Detail?id=48361330.
[35] Wang, Changzhen, Sun, Nannan, Zhao, Ning, Wei, Wei, Zhang, Jun, Zhao, Tiejun, Sun, Yuhan, Sun, Chenggong, Liu, Hao, Snape, Colin E. The Properties of Individual Carbon Residuals and Their Influence on The Deactivation of Ni-CaO-ZrO2 Catalysts in CH4 Dry Reforming. CHEMCATCHEM[J]. 2014, 6(2): 640-648, https://www.webofscience.com/wos/woscc/full-record/WOS:000337637100032.
[36] 张军. Enhanced thermochemical CO2 splitting over porous Mg- and Ca-doped ceria/zirconia solid solutions. RSC Advances. 2013, [37] Huang, Ping, Zhao, Yonghui, Zhang, Jun, Zhu, Yan, Sun, Yuhan. Exploiting shape effects of La2O3 nanocatalysts for oxidative coupling of methane reaction. NANOSCALE[J]. 2013, 5(22): 10844-10848, https://www.webofscience.com/wos/woscc/full-record/WOS:000326225500016.
[38] Chen, Q J, Zhang, J, Jin, Q W, Pan, B R, Kong, W B, Zhao, T J, Sun, Y H. Effect of reflux digestion treatment on the catalytic performance of Ni-CaO-ZrO2 nanocomposite catalysts for CO2 reforming of CH4. CATALYSIS TODAY[J]. 2013, 215: 251-259, http://dx.doi.org/10.1016/j.cattod.2013.06.011.
[39] Kang, Min, Zhang, Jun, Wang, Changzhen, Wang, Feng, Zhao, Ning, Xiao, Fukui, Wei, Wei, Sun, Yuhan. CO2 splitting via two step thermochemical reactions over doped ceria/zirconia solid solutions. RSC ADVANCES[J]. 2013, 3(41): 18878-18885, http://dx.doi.org/10.1039/c3ra43742f.
[40] Zhang, Jun, Zhao, Ning, Wei, Wei, Sun, Yuhan. Partial oxidation of methane over Ni/Mg/Al/La mixed oxides prepared from layered double hydrotalcites. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY[J]. 2010, 35(21): 11776-11786, http://dx.doi.org/10.1016/j.ijhydene.2010.08.025.
[41] Zhang, Jun, Wei, Wei, Sun, Yuhan. Fluorine-Modified Mesoporous Ni-Mg-Al Mixed Oxides for Partial Oxidation of Methane. CATALYSIS LETTERS[J]. 2010, 135(3-4): 321-329, http://www.corc.org.cn/handle/1471x/2405732.

   

（ 1 ） MFe2O4/N-CexZrl-xO2复合储氧材料两步循环法分解CO2/H2O制合成气, 主持, 国家级, 2014-01--2016-12
（ 2 ） H2 production from H2O via two-step thermochemical, 主持, 国家级, 2013-01--2014-01
（ 3 ） CO2工业废气大规模重整转化制合成气关键技术与示范, 参与, 国家级, 2012-09--2015-12
（ 4 ） CH4和CO2重整制合成气中新型催化剂关键技术研究, 参与, 省级, 2011-06--2014-06
（ 5 ） CO2与CH4重整转化制备合成气关键技术与工程示范, 参与, 国家级, 2012-06--2015-12
（ 6 ） CO2甲烷重整制合成气, 主持, 院级, 2011-11--2016-12
（ 7 ） 乙醇高温裂解, 主持, 院级, 2015-05--2016-02
（ 8 ） 新一代重整技术, 主持, 院级, 2017-06--2021-06

已指导学生

黄金成  博士研究生  070304-物理化学  

江涛  硕士研究生  085216-化学工程  

黄爽爽  博士研究生  070304-物理化学  

现指导学生

孔文波  博士研究生  081701-化学工程  

郝洁  硕士研究生  085216-化学工程  

白洁茹  硕士研究生  085216-化学工程