金属有机笼状配合物，软物质

   

070303-有机化学

超分子化学，笼状化合物的设计合成及应用

2008-09--2013-12   吉林大学   博士
2004-08--2008-06   吉林大学   本科

研究生

博士

2014.1-2017.12  中国科学院福建物质结构研究所  助理研究员

2018.0-至今        中国科学院福建物质结构研究所  副研究员

   

[1] Chen, Ran, Yan, QianQian, Hu, ShaoJun, Guo, XiaoQing, Zhou, LiPeng, Sun, QingFu. Dinuclear mono-bridged or polymeric lanthanide complexes from one ligand: structural transformation and chiral induction. DALTON TRANSACTIONS[J]. 2023, 52(1): 37-43, [2] Hu, ShaoJun, Guo, XiaoQing, Zhou, LiPeng, Cai, LiXuan, Tian, ChongBin, Sun, QingFu. Ionic Radius Dependent Kinetic Behavior for the Self-Assemblyand Chiral Amplification of Lanthanide Tetrahedral Cages. CHINESE JOURNAL OF CHEMISTRY. 2023, http://dx.doi.org/10.1002/cjoc.202200649.
[3] Lin, XiaoShan, Liao, WenHua, Zhou, LiPeng, Sun, QingFu. Embedding Lanthanide Organic Polyhedra into Mesoporous Silica Nanoparticles for the Photocatalytic Degradation of Organic Dyes. CHEMISTRY-AN ASIAN JOURNAL[J]. 2023, 18(6): http://dx.doi.org/10.1002/asia.202201249.
[4] Yan, DanNi, Cai, LiXuan, Hu, ShaoJun, Zhou, YanFang, Zhou, LiPeng, Sun, QingFu. An Organo-Palladium Host Built from a Dynamic Macrocyclic Ligand: Adaptive Self-Assembly, Induced-Fit Guest Binding, and Catalysis. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2022, 61(42): http://dx.doi.org/10.1002/anie.202209879.
[5] Lin, XiaoShan, Yu, Yanzi, Zhou, LiPeng, He, Lizhen, Chen, Tianfeng, Sun, QingFu. Mesoporous silica nanoparticle-embedded lanthanide organic polyhedra for enhanced stability, luminescence and cell imaging. DALTON TRANSACTIONS[J]. 2022, 51(12): 4836-4842, http://dx.doi.org/10.1039/d1dt04313g.
[6] Hu, ShaoJun, Guo, XiaoQing, Zhou, LiPeng, Yan, DanNi, Cheng, PeiMing, Cai, LiXuan, Li, XiaoZhen, Sun, QingFu. Guest-Driven Self-Assembly and Chiral Induction of Photofunctional Lanthanide Tetrahedral Cages. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY[J]. 2022, 144(9): 4244-4253, http://dx.doi.org/10.1021/jacs.2c00760.
[7] Jiang, Chen, Hu, ShaoJun, Zhou, LiPeng, Yang, Jian, Sun, QingFu. Lanthanide-organic pincer hosts with allosteric-controlled metal ion binding specificity. CHEMICAL COMMUNICATIONS[J]. 2022, 58(36): 5494-5497, http://dx.doi.org/10.1039/d2cc01379g.
[8] Wang, ZiCheng, Zhang, Ting, Zhou, LiPeng, Cai, LiXuan, Wu, LiXin, Sun, QingFu, Cheng, XiuYan. Self-Healable Poly(vinyl alcohol)-Metal-Organic Hybrid Gel Electrolyte for Flexible Capacitor Sensors. ACS APPLIED POLYMER MATERIALS[J]. 2022, 4(9): 6487-6494, http://dx.doi.org/10.1021/acsapm.2c00896.
[9] Chen, Ran, Yan, QianQian, Hu, ShaoJun, Guo, XiaoQing, Cai, LiXuan, Yan, DanNi, Zhou, LiPeng, Sun, QingFu. Dinuclear helicate or mononuclear pincer lanthanide complexes from one ligand: stereo-controlled assembly and catalysis. ORGANIC CHEMISTRY FRONTIERS[J]. 2021, 8(11): 2576-2582, http://dx.doi.org/10.1039/d1qo00369k.
[10] Cai, LiXuan, Yan, DanNi, Cheng, PeiMing, Xuan, JinJin, Li, ShaoChuan, Zhou, LiPeng, Tian, ChongBin, Sun, QingFu. Controlled Self-Assembly and Multistimuli-Responsive Interconversions of Three Conjoined Twin-Cages. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY[J]. 2021, 143(4): 2016-2024, http://dx.doi.org/10.1021/jacs.0c12064.
[11] Cheng, Kai, Bai, QiXia, Hu, ShaoJun, Guo, XiaoQing, Zhou, LiPeng, Xie, TingZheng, Sun, QingFu. Water-stable lanthanide-organic macrocycles from a 1,2,4-triazole-based chelate for enantiomeric excess detection and pesticide sensing. DALTON TRANSACTIONS[J]. 2021, 50(17): 5759-5764, http://dx.doi.org/10.1039/d1dt00726b.
[12] Wang, Heng, Zhou, LiPeng, Zheng, Yu, Wang, Kun, Song, Bo, Yan, Xuzhou, Wojtas, Lukasz, Wang, XuQing, Jiang, Xin, Wang, Ming, Sun, QingFu, Xu, Bingqian, Yang, HaiBo, Sue, Andrew C H, Chan, YiTsu, Sessler, Jonathan L, Jiao, Yang, Stang, Peter J, Li, Xiaopeng. Double-Layered Supramolecular Prisms Self-Assembled by Geometrically Non-equivalent Tetratopic Subunits. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2021, 60(3): 1298-1305, http://dx.doi.org/10.1002/anie.202010805.
[13] Wang Zhuo, Zhou LiPeng, Cai LiXuan, Tian ChongBin, Sun QingFu. From a mononuclear FeL2 complex to a Fe4L4 molecular square: Designed assembly and spin-crossover property. NANO RESEARCH[J]. 2021, 14(2): 398-403, http://lib.cqvip.com/Qikan/Article/Detail?id=7103999364.
[14] Guo, XiaoQing, Zhou, LiPeng, Hu, ShaoJun, Cai, LiXuan, Cheng, PeiMing, Sun, QingFu. Hexameric Lanthanide-Organic Capsules with Tertiary Structure and Emergent Functions. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY[J]. 2021, 143(16): 6202-6210, http://dx.doi.org/10.1021/jacs.1c01168.
[15] Wang, Heng, Wang, Kun, Xu, Yaping, Wang, Wu, Chen, Shaohua, Hart, Matthew, Wojtas, Lukasz, Zhou, LiPeng, Gan, Lin, Yan, Xuzhou, Li, Yiming, Lee, Juhoon, Ke, XianSheng, Wang, XuQing, Zhang, ChangWei, Zhou, Shasha, Zhai, Tianyou, Yang, HaiBo, Wang, Ming, He, Jiaqing, Sun, QingFu, Xu, Bingqian, Jiao, Yang, Stang, Peter J, Sessler, Jonathan L, Li, Xiaopeng. Hierarchical Self-Assembly of Nanowires on the Surface by Metallo-Supramolecular Truncated Cuboctahedra. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY[J]. 2021, 143(15): 5826-5835, http://dx.doi.org/10.1021/jacs.1c00625.
[16] Cheng, Peiming, Cai, Lixuan, Yan, Danni, Zhou, Lipeng, Sun, Qingfu. Molecular Cage Promoted Aerobic Oxidation or Photo-Induced Rearrangement of Spiroepoxy Naphthalenone. CATALYSTS[J]. 2021, 11(4): https://doaj.org/article/4ebe749e16cc497eaef1101cbea18319.
[17] Feng, XiaoShan, Li, XiaoZhen, Hu, ShaoJun, Yan, DanNi, Zhou, LiPeng, Sun, QingFu. Base- and Metal-Dependent Self-Assembly of Lathanide-Organic Coordination Polymers or Macrocycles with Tetradentate Acylhydrazone-based Ditopic Ligands. CHEMISTRY-AN ASIAN JOURNAL[J]. 2021, 16(11): 1392-1397, http://dx.doi.org/10.1002/asia.202100256.
[18] Li, XiaoZhen, Zhou, LiPeng, Hu, ShaoJun, Cai, LiXuan, Guo, XiaoQing, Wang, Zhuo, Sun, QingFu. Metal ion adaptive self-assembly of photoactive lanthanide-based supramolecular hosts. CHEMICAL COMMUNICATIONS[J]. 2020, 56(32): 4416-4419, https://www.webofscience.com/wos/woscc/full-record/WOS:000529215100003.
[19] Cheng, PeiMing, Cai, LiXuan, Li, ShaoChuan, Hu, ShaoJun, Yan, DanNi, Zhou, LiPeng, Sun, QingFu. Guest-Reaction Driven Cage to Conjoined Twin-Cage Mitosis-Like Host Transformation. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2020, 59(52): 23569-23573, https://www.webofscience.com/wos/woscc/full-record/WOS:000577475400001.
[20] Han, ShiLong, Yang, Jian, Tripathy, Debakanta, Guo, XiaoQing, Hu, ShaoJun, Li, XiaoZhen, Cai, LiXuan, Zhou, LiPeng, Sun, QingFu. Self-Assembly of Lanthanide-Covalent Organic Polyhedra: Chameleonic Luminescence and Efficient Catalysis. INORGANIC CHEMISTRY[J]. 2020, 59(19): 14023-14030, http://dx.doi.org/10.1021/acs.inorgchem.0c01780.
[21] Wang, Zhuo, He, Lizhen, Liu, Bingqing, Zhou, LiPeng, Cai, LiXuan, Hu, ShaoJun, Li, XiaoZhen, Li, Zhikai, Chen, Tianfeng, Li, Xiaopeng, Sun, QingFu. Coordination-Assembled Water-Soluble Anionic Lanthanide Organic Polyhedra for Luminescent Labeling and Magnetic Resonance Imaging. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY[J]. 2020, 142(38): 16409-16419, http://dx.doi.org/10.1021/jacs.0c07514.
[22] Zhu, QiangYu, Zhou, LiPeng, Cai, LiXuan, Li, XiaoZhen, Zhou, Jin, Sun, QingFu. Chiral auxiliary and induced chiroptical sensing with 5d/4f lanthanide-organic macrocycles. CHEMICAL COMMUNICATIONS[J]. 2020, 56(19): 2861-2864, https://www.webofscience.com/wos/woscc/full-record/WOS:000519216400005.
[23] He, Lizhen, Cai, LiXuan, Li, MengHua, Zhang, GuangLu, Zhou, LiPeng, Chen, Tianfeng, Lin, MeiJin, Sun, QingFu. Designing a highly stable coordination-driven metallacycle for imaging-guided photodynamic cancer theranostics. CHEMICAL SCIENCE[J]. 2020, 11(30): 7940-7949, https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8163381/.
[24] Wu, ShiYu, Guo, XiaoQing, Zhou, LiPeng, Sun, QingFu. Fine-Tuned Visible and Near-Infrared Luminescence on Self-Assembled Lanthanide-Organic Tetrahedral Cages with Triazole-Based Chelates. INORGANIC CHEMISTRY[J]. 2019, 58(10): 7091-7098, http://dx.doi.org/10.1021/acs.inorgchem.9b00756.
[25] Yan, QianQian, Zhou, LiPeng, Zhou, HaiYue, Wang, Zhuo, Cai, LiXuan, Guo, XiaoQing, Sun, XiaoQi, Sun, QingFu. Metallopolymers cross-linked with self-assembled Ln(4)L(4) cages. DALTON TRANSACTIONS[J]. 2019, 48(21): 7080-7084, https://www.webofscience.com/wos/woscc/full-record/WOS:000472454100005.
[26] Wang, Heng, Wang, Kun, Xu, Yaping, Chen, Shaohua, Hart, Matthew, Wojtas, Lukasz, Zhou, LiPeng, Gan, Lin, Yan, Xuzhou, Li, Yiming, Lee, Juhoon, Wang, XuQing, Zhang, ChangWei, Zhou, Shasha, Zhai, Tianyou, Yang, HaiBo, Wang, Ming, Sun, QingFu, Xu, Bingqian, Jiao, Yang, Stang, Peter, Sessler, Jonathan, Li, Xiaopeng. Self-assembly of supramolecular truncated cuboctahedron into double helical nanowires with non-natural parastichy pattern. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETYnull. 2019, 257: https://www.webofscience.com/wos/woscc/full-record/WOS:000478861205259.
[27] Zhu, QiangYu, Zhou, LiPeng, Sun, QingFu. Strongly luminescent 5d/4f heterometal-organic macrocycles with open metal sites: post-assembly modification and sensing. DALTON TRANSACTIONS[J]. 2019, 48(14): 4479-4483, https://www.webofscience.com/wos/woscc/full-record/WOS:000467173800005.
[28] Li, ShaoChuan, Cai, LiXuan, Zhou, LiPeng, Guo, Fang, Sun, QingFu. Supramolecular synthesis of coumarin derivatives catalyzed by a coordination-assembled cage in aqueous solution. SCIENCE CHINA-CHEMISTRY[J]. 2019, 62(6): 713-718, https://www.webofscience.com/wos/woscc/full-record/WOS:000470762900009.
[29] ShaoChuan Li, LiXuan Cai, LiPeng Zhou, Fang Guo, QingFu Sun. Supramolecular synthesis of coumarin derivatives catalyzed by a coordination-assembled cage in aqueous solution. 中国科学:化学英文版[J]. 2019, 62(6): 713-718, https://www.webofscience.com/wos/woscc/full-record/WOS:000470762900009.
[30] Hu, ShaoJun, Guo, XiaoQing, Zhou, LiPeng, Cai, LiXuan, Sun, QingFu. Coordination-Assembled Lanthanide-Organic Ln(3)L(3) Sandwiches or Ln(4)L(4) Tetrahedron: Structural Transformation and Luminescence Modulation. CHINESE JOURNAL OF CHEMISTRY[J]. 2019, 37(7): 657-662, http://lib.cqvip.com/Qikan/Article/Detail?id=7002884888.
[31] Fu, Lei, Li, Shangda, Cai, Zhihua, Ding, Yongzheng, Guo, XiaoQing, Zhou, LiPeng, Yuan, Daqiang, Sun, QingFu, Li, Gang. Ligand-enabled site-selectivity in a versatile rhodium(II)-catalysed aryl C-H carboxylation with CO2. NATURECATALYSIS[J]. 2018, 1(6): 469-478, https://www.webofscience.com/wos/woscc/full-record/WOS:000446615700019.
[32] XiaoZhen Li, LiPeng Zhou, LiangLiang Yan, YaMin Dong, ZhuanLing Bai, XiaoQi Sun, Juan Diwu, Shuao Wang, JeanClaude Bnzli, QingFu Sun. A supramolecular lanthanide separation approach based on multivalent cooperative enhancement of metal ion selectivity. NATURE COMMUNICATIONS[J]. 2018, 9(1): https://doaj.org/article/bc61ed4054804fd6bfb3409b32afad75.
[33] Guo, XiaoQing, Zhou, LiPeng, Cai, LiXuan, Sun, QingFu. Self-Assembled Bright Luminescent Lanthanide-Organic Polyhedra for Ratiometric Temperature Sensing. CHEMISTRY-A EUROPEAN JOURNAL[J]. 2018, 24(27): 6936-6940, https://www.webofscience.com/wos/woscc/full-record/WOS:000431975000009.
[34] Zhang, Ting, Zhang, GuangLu, Yan, QianQian, Zhou, LiPeng, Cai, LiXuan, Guo, XiaoQing, Sun, QingFu. Self-Assembly of a Tetraphenylethylene-Based Capsule Showing Both Aggregation- and Encapsulation-Induced Emission Properties. INORGANIC CHEMISTRY[J]. 2018, 57(7): 3596-3601, https://www.webofscience.com/wos/woscc/full-record/WOS:000429283200015.
[35] Li, ShaoChuan, Zhang, Ting, Deng, Xingping, Guo, XiaoQing, Zhou, LiPeng, Guo, Fang, Sun, QingFu. Squaric acid-directed transformation of metal-organic macrocycles. INORGANIC CHEMISTRY COMMUNICATIONS[J]. 2018, 92: 69-73, http://dx.doi.org/10.1016/j.inoche.2018.04.008.
[36] Wang, Zhuo, Zhou, LiPeng, Zhao, TongHan, Cai, LiXuan, Guo, XiaoQing, Duan, PengFei, Sun, QingFu. Hierarchical Self-Assembly and Chiroptical Studies of Luminescent 4d-4f Cages. INORGANIC CHEMISTRY[J]. 2018, 57(13): 7982-7992, https://www.webofscience.com/wos/woscc/full-record/WOS:000438006700053.
[37] Cai, LiXuan, Yan, LiangLiang, Li, ShaoChuan, Zhou, LiPeng, Sun, QingFu. Stereocontrolled self-assembly and photochromic transformation of lanthanide supramolecular helicates. DALTON TRANSACTIONS[J]. 2018, 47(40): 14204-14210, https://www.webofscience.com/wos/woscc/full-record/WOS:000447708900009.
[38] Yan, QianQian, Hu, ShaoJun, Zhang, GuangLu, Zhang, Ting, Zhou, LiPeng, Sun, QingFu. Coordination-Enhanced Luminescence on Tetra-Phenylethylene-Based Supramolecular Assemblies. MOLECULES[J]. 2018, 23(2): https://doaj.org/article/e801f36a36e144a4961b8473e2f91f9e.
[39] Cai, LiXuan, Li, ShaoChuan, Yan, DanNi, Zhou, LiPeng, Guo, Fang, Sun, QingFu. Water-Soluble Redox-Active Cage Hosting Polyoxometalates for Selective Desulfurization Catalysis. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY[J]. 2018, 140(14): 4869-4876, [40] Li, XiaoZhen, Zhou, LiPeng, Yang, LiangLiang, Yuan, DaQiang, Lin, ChenSheng, Sun, QingFu. Evolution of Luminescent Supramolecular Lanthanide M2nL3n Complexes from Helicates and Tetrahedra to Cubes. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY[J]. 2017, 139(24): 8237-8244, [41] Zhang Ting, Zhang GuangLu, Zhou LiPeng, Guo XiaoQing, Sun QingFu. Stereocontrolled self-assembly of luminescent lanthanide helicates and their enantiodifferentiation using Δ -TRISPHAT as the NMR resolving agent. TETRAHEDRON: ASYMMETRY[J]. 2017, [42] Ting Zhang, LiPeng Zhou, XiaoQing Guo, LiXuan Cai, QingFu Sun. Adaptive self-assembly and induced-fit transformations of anion-binding metal-organic macrocycles. NATURE COMMUNICATIONS[J]. 2017, 8(1): https://doaj.org/article/ce157becc59a46a88987a133489f941a.
[43] Liu, CuiLian, Zhang, RuiLing, Lin, ChenSheng, Zhou, LiPeng, Cai, LiXuan, Kong, JinTao, Yang, SongQiu, Han, KeLi, Sun, QingFu. Intraligand Charge Transfer Sensitization on Self-Assembled Europium Tetrahedral Cage Leads to Dual-Selective Luminescent Sensing toward Anion and Cation. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY[J]. 2017, 139(36): 12474-12479, http://dx.doi.org/10.1021/jacs.7b05157.
[44] Zhang, Ting, Zhang, GuangLu, Zhou, LiPeng, Guo, XiaoQing, Sun, QingFu. Stereocontrolled self-assembly of luminescent lanthanide helicates and their enantiodifferentiation using Delta-TRISPHAT as the NMR resolving agent. TETRAHEDRON-ASYMMETRY[J]. 2017, 28(4): 550-554, https://www.webofscience.com/wos/woscc/full-record/WOS:000401382700009.
[45] Ting Zhang, GuangLu Zhang, LiPeng Zhou, XiaoQing Guo, QingFu Sun. Stereocontrolled self-assembly of luminescent lanthanide helicates and their enantiodifferentiation using Δ -TRISPHAT as the NMR resolving agent. TETRAHEDRON: ASYMMETRY. 2017, 550-554, http://dx.doi.org/10.1016/j.tetasy.2017.03.007.
[46] Liu, CuiLian, Zhou, LiPeng, Tripathy, Debakanta, Sun, QingFu. Self-assembly of stable luminescent lanthanide supramolecular M4L6 cages with sensing properties toward nitroaromatics. CHEMICAL COMMUNICATIONS[J]. 2017, 53(16): 2459-2462, https://www.webofscience.com/wos/woscc/full-record/WOS:000395872900011.
[47] Zhang Guanglu, Zhang Ting, Zhou Lipeng, Sun Qingfu. Capsid-Inspired Multi-Component Self-Assembly of Nanocontainers : Structure, Functionalization, and Applications. PROGRESS IN CHEMISTRY[J]. 2016, 28(9): 1289-1298, https://www.webofscience.com/wos/woscc/full-record/WOS:000386542000001.
[48] Zhang Guanglu, Zhang Ting, Zhou Lipeng, Sun Qingfu. Capsid-Inspired Multi-Component Self-Assembly of Nanocontainers : Structure, Functionalization, and Applications. PROGRESS IN CHEMISTRY[J]. 2016, 28(9): 1289-1298, https://www.webofscience.com/wos/woscc/full-record/WOS:000386542000001.
[49] Zhou, LiPeng, Sun, QingFu. A self-assembled Pd2L4 cage that selectively encapsulates nitrate. CHEMICAL COMMUNICATIONS[J]. 2015, 51(94): 16767-16770, https://www.webofscience.com/wos/woscc/full-record/WOS:000365014400004.
[50] Yan, LiangLiang, Tan, ChunHong, Zhang, GuangLu, Zhou, LiPeng, Bunzli, JeanClaude, Sun, QingFu. Stereocontrolled Self-Assembly and Self-Sorting of Luminescent Europium Tetrahedral Cages. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY[J]. 2015, 137(26): 8550-8555, https://www.webofscience.com/wos/woscc/full-record/WOS:000357964400041.
[51] Zhang, GuangLu, Zhou, LiPeng, Yuan, DaQiang, Sun, QingFu. Bottom-Up Construction of Mesoporous Nanotubes from 78-Component Self-Assembled Nanobarrels. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2015, 54(34): 9844-9848, https://www.webofscience.com/wos/woscc/full-record/WOS:000360215100012.

   

（ 1 ） 以纳米容器为基元的超分子晶态材料构筑及功能研究, 主持, 国家级, 2017-01--2019-12
（ 2 ） “晶态分子烧瓶”的多级自组装构筑及其应用探索, 主持, 省级, 2016-04--2019-04