Nanomaterials for clean energy

Electrocatalysis

Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences

2020/01 Prof.

2013/10-2019/12 A/Prof.

[1]       Cao, M.; Lin, J.; Yang, H.; Cao, R.* Facile synthesis of palladium nanoparticles with high chemical activity using cucurbit[6]uril as protecting agent. Chem. Commun. 2010, 46, 5088-90.

[2]       Cao, M.; Lin, J.; Lu, J.; You, Y.; Liu, T.; Cao, R.* Development of a polyoxometallate-based photocatalyst assembled with cucurbit[6]uril via hydrogen bonds for azo dyes degradation. J. Hazard. Mater. 2011, 186, 948-51.

[3]       Cao, M.; Wu, D.; Gao, S.; Cao, R.* Platinum nanoparticles stabilized by cucurbit[6]uril with enhanced catalytic activity and excellent poisoning tolerance for methanol electrooxidation. Chemistry 2012, 18, 12978-85.

[4]       Cao, M. N.; Wei, Y.; Gao, S. Y.; Cao, R.* Synthesis of palladium nanocatalysts with cucurbit[n]uril as both a protecting agent and a support for suzuki and heck reactions. Catal. Sci. Technol. 2012, 2, 156-163.

[5]       Gao, S. Y.; Wu, D. S.; Cao, M. N.; Cao, R.* Self-assembled pd-dicyanobiphenyl multilayer films and their application in electrocatalytic oxidation of methanol in alkaline medium. Thin Solid Films 2012, 524, 173-178.

[6]       Li, H.; Cao, M.; Liu, T.; Cao, R.* Activation energy of the reaction between hexacyanoferrate (capital sha, cyrillic) and thiosulfate ions catalyzed by platinum nanoparticles confined in nanometer space. Journal of colloid and interface science 2012, 369, 352-7.

[7]       Wu, D.; Zheng, Z.; Gao, S.; Cao, M.; Cao, R.* Mixed-phase pdru bimetallic structures with high activity and stability for formic acid electrooxidation. Physical chemistry chemical physics : PCCP 2012, 14, 8051-7.

[8]       Lu, J.; Lin, J. X.; Cao, M. N.; Cao, R.* Cucurbituril: A promising organic building block for the design of coordination compounds and beyond. Coordination Chemistry Reviews 2013, 257, 1334-1356.

[9]       Cao, M. N.; Wu, D. S.; Cao, R.* Recent advances in the stabilization of platinum electrocatalysts for fuel-cell reactions. Chemcatchem 2014, 6, 26-45.

[10]     Gao, S. Y.; Cao, M. N.; Li, W. J.; Cao, R.* Palladium nanoparticles in situ generated in metal-organic films for catalytic applications. J. Mater. Chem. A 2014, 2, 12185-12193.

[11]     Wu, D.; Cao, M.; Cao, R.* Ru-assisted synthesis of {111}-faceted pd truncated bipyramids: A highly reactive, stable and restorable catalyst for formic acid oxidation. Chem. Commun. 2014, 50, 12970-2.

[12]     Wu, D. S.; Cao, M. N.; Shen, M.; Cao, R.* Sub-5 nm pd-ru nanoparticle alloys as efficient catalysts for formic acid electrooxidation. Chemcatchem 2014, 6, 1731-1736.

[13]     Cao, M.; Wu, D.; Su, W.; Cao, R.* Palladium nanocrystals stabilized by cucurbit[6]uril as efficient heterogeneous catalyst for direct c–h functionalization of polyfluoroarenes. J. Catal. 2015, 321, 62-69.

[14]     Shen, M.; Huang, Y. B.; Wu, D. S.; Lu, J.; Cao, M. N.; Liu, M. M.; Yang, Y. L.; Li, H. F.; Guo, B. B.; Cao, R.* Facile ultrafine copper seed-mediated approach for fabricating quasi-two-dimensional palladium-copper bimetallic trigonal hierarchical nanoframes. Nano Res 2017, 10, 2810-2822.

[15]     Yi, J. D.; Shi, P. C.; Liang, J.; Cao, M. N.; Huang, Y. B.; Cao, R.* Porous hollow mos2 microspheres derived from core-shell sulfonated polystyrene microspheres@mos2 nanosheets for efficient electrocatalytic hydrogen evolution. Inorg Chem Front 2017, 4, 741-747.

[16]     Chen, R.; Cao, M.*; Wang, J.; Li, H.; Cao, R.* Decamethylcucurbit[5]uril based supramolecular assemblies as efficient electrocatalysts for the oxygen reduction reaction. Chem. Commun. 2019, 55, 11687-11690.

[17]     Chen, R.; Cao, M.*; Yang, W.; Wang, H.; Zhang, S.; Li, H.; Cao, R.* Ultra-small pd nanoparticles derived from a supramolecular assembly for enhanced electrochemical reduction of co2 to co. Chem. Commun. 2019, 55, 9805-9808.

[18]     Wu, D.; Cao, M.*; You, H.; Zhao, C.; Cao, R.* N-doped holey carbon materials derived from a metal-free macrocycle cucurbit[6]uril assembly as an efficient electrocatalyst for the oxygen reduction reaction. Chem. Commun. 2019, 55, 13832-13835.

[19]     Wu, D. S.; Cao, M.*; Cao, R.* Replacing pvp by macrocycle cucurbit[6]uril to cap sub-5 nm pd nanocubes as highly active and durable catalyst for ethanol electrooxidation. Nano Res 2019, 12, 2628-2633.

[20]     You, H.; Wu, D.; Chen, Z.-n.; Sun, F.; Zhang, H.; Chen, Z.; Cao, M.*; Zhuang, W.*; Cao, R.* Highly active and stable water splitting in acidic media using a bifunctional iridium/cucurbit[6]uril catalyst. ACS Energy Lett. 2019, 4, 1301-1307.

nanomaterials for clean energy 

electrocatalysis