1. 能量高效转换燃料电池膜电极研究

质子交换膜燃料电池是将化学能直接转化为电能的发电装置，具有高效、易启动、污染小等优点，被誉为21世纪最有发展前景的高效清洁发电技术。膜电极是燃料电池的“心脏”，是燃料电池发生电极反应、把化学能转化电能的重要场所。研究低成本，高活性、长寿命的膜电极可大大推进燃料电池技术的发展。

3. 膜电极内电极反应强化机制的研究

燃料电池电极反应需要在同时兼具催化活性位、质子导体、电子导体及反应物/产物的传输通道的三相反应界面区域进行。通过设计合理的电极结构，强化提高三相界面域的面积及结构稳定性，可有效提高催化剂的利用率，提高电极性能。

3. 二氧化碳电催化转化制小分子燃料的研究

近年来，能源与环境问题受到广泛关注。CO₂电催化还原制甲酸为可再生新能源技术提供了一种储能方式，同时有助于温室气体CO₂的减排。通过设计合成具有高催化活性的电极材料，可有效降低生成甲酸的反应过电位，提高生成甲酸的电解电流密度，提高能量转化效率。

燃料电池多孔膜电极电催化研究  1-2名 硕士

070304-物理化学（含：化学物理）

电催化/电化学工程

2001-09--2008-01   大连化学物理研究所305组   博士
1997-09--2001-07   青岛科技大学（原青岛化工学院）应用化学系   学士

2014.12-今  大连化学物理研究所DNL0311组  副研究员

2011.07-2014.11  大连化学物理研究所DNL03T3组 副研究员

2009.08-2011.06 香港大学化学系  博士后

2008.01-2009.07 大连化学物理研究所305组 研究助理

   

（1） 直接醇类燃料电池电催化剂材料应用基础研究, 部委级, 2014

[1] 王素力, 李焕巧, 孙公权. 一种复合催化剂及其制备方法. CN: CN113751035A, 2021-12-07.

[2] 王素力, 李焕巧, 孙公权. 一种燃料电池催化层及其制备方法. CN: CN113594475A, 2021-11-02.

[3] 王素力, 李焕巧, 孙公权. 一种燃料电池膜电极检漏装置及检漏方法. CN: CN111103100B, 2021-08-10.

[4] 王素力, 马文佳, 孙公权, 李焕巧. 一种阳离子交换膜成膜方法及由其制备的阳离子交换膜. CN: CN111249923B, 2021-08-03.

[5] 王素力, 李焕巧, 孙公权. 一种纳米催化剂中表面活性剂定量检测方法. CN: CN112986040A, 2021-06-18.

[6] 王素力, 李焕巧, 孙公权. 纳米催化剂中表面活性剂的温和去除方法. CN: CN112973802A, 2021-06-18.

[7] 王素力, 李焕巧, 孙公权. 一种用于燃料电池催化层中活性组分载量的测试方法. CN: CN112986042A, 2021-06-18.

[8] 王素力, 李焕巧, 孙公权. 一种纳米催化剂中表面活性剂的去除方法. CN: CN112973801A, 2021-06-18.

[9] 王素力, 李焕巧, 孙公权. 一种燃料电池导电气体扩散层及其制备方法. CN: CN111162285B, 2021-06-04.

[10] 王素力, 李焕巧, 孙公权. Pt基多组元过渡金属合金纳米电催化剂及制备和应用. CN: CN112825357A, 2021-05-21.

[11] 王素力, 李焕巧, 孙公权. 基于贫氢重整气进料高温质子膜燃料电池膜电极及制备与应用. CN: CN112825366A, 2021-05-21.

[12] 王素力, 李焕巧, 孙公权. 一种高金属载量的催化剂及其制备和应用. CN: CN112823880A, 2021-05-21.

[13] 王素力, 李焕巧, 孙公权. 改善磷酸电解质高温膜燃料电池放电性能与运行寿命方法. CN: CN110970641B, 2021-05-04.

[14] 王素力, 马文佳, 孙公权, 李焕巧. 一种ePTFE增强型质子交换膜成型方法. CN: CN111261915A, 2020-06-09.

[15] 王素力, 李焕巧, 孙公权. 一种高温磷酸燃料电池一体化膜电极及其制备和应用. CN: CN110970643A, 2020-04-07.

[16] 王素力, 李焕巧, 孙公权. 一种检测多孔气体扩散电极透气性及电导性的装置、检测系统及方法. CN: CN109959594A, 2019-07-02.

[17] 王素力, 李焕巧, 孙公权. 一种PTFE粘结剂与电极关键组分材料均匀分布的方法及在电池行业中的应用. CN: CN109935843A, 2019-06-25.

[18] 孙公权, 李焕巧, 王素力. 一种溶解氧海水电池的亲水阴极及其制备和应用. CN: CN108615959A, 2018-10-02.

[19] 王素力, 魏伟, 孙公权, 李焕巧. 一种燃料电池膜电极的制备方法和燃料电池. CN: CN108461785A, 2018-08-28.

[20] 孙公权, 李焕巧, 王素力. 一种过氧化氢燃料电池阴极及其制备和应用. CN: CN108232203A, 2018-06-29.

[21] 孙公权, 李焕巧, 王素力, 闫树华. 一种导电透气阻液膜及其制备和应用. CN: CN106910924A, 2017-06-30.

[22] 孙公权, 杨林林, 王素力, 李焕巧, 谷领峥. 一种燃料电池电极的制备和采用该方法制备电极的装置. CN: CN106898782A, 2017-06-27.

[23] 孙公权, 李焕巧, 王素力. 铟基双组元或三组元纳米催化剂及其制备和应用. CN: CN106890639A, 2017-06-27.

[24] 孙公权, 李焕巧, 王素力, 闫树华. 一种多孔电催化膜及其制备和应用. CN: CN106890676A, 2017-06-27.

[25] 宋玉江, 李焕巧, 王丹. 一种形貌可控铟纳米催化剂的制备方法及其应用. CN: CN104707590A, 2015-06-17.

[26] 宋玉江, 李焕巧. 一种担载型铂基多金属催化剂的一步制备方法和应用. CN: CN104174392A, 2014-12-03.

[27] 李焕巧, 宋玉江. 一种用于非常温电化学实验的参比电极系统. CN: CN203720141U, 2014-07-16.

[28] 李焕巧, 宋玉江. 一种酸、碱、盐三电解质溶液共存的铅酸电池. CN: CN103928716A, 2014-07-16.

[29] 宋玉江, 李焕巧. 一种以双极膜为隔膜的电化学还原CO 2 电解池及其应用. 中国: CN102912374A, 2013-02-06.

[30] 宋玉江, 李焕巧. 一种以双极膜为隔膜的电化学还原CO 2 电解池及其应用. CN: CN102912374A, 2013-02-06.

[31] 辛勤, 李焕巧, 孙公权, 李文震, 周振华, 周卫江, 姜鲁华. 质子交换膜燃料电池阴极电催化剂及其应用. CN: CN1632975A, 2005-06-29.

   

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[2] 徐欢, 夏章讯, 孙牧, 张子楠, 黄基才, 李焕巧, 景粉宁, Dexin Feng, 王素力, 孙公权. Non-uniform Anode Design for High-Temperature Polymer Electrolyte Membrane Fuel Cells with Mitigated Hydrogen Starvation. Energy & Fuels[J]. 2023, [3] Zhao An, Huanqiao Li, Xiaoming Zhang, Xinlong Xu, Zhangxun Xia, Shansheng Yu, Wenling Chu, Suli Wang, Gongquan Sun. Structural Evolution of a PtRh Nanodendrite Electrocatalyst and Its Ultrahigh Durability toward Oxygen Reduction Reaction. ACS Catal. 2022, 12, 6, 3302–3308[J]. 2022, [4] Zhang, Xiaoming, Li, Huanqiao, Xia, Zhangxun, Yu, Shansheng, Wang, Suli, Sun, Gongquan. Effect of an external electric field, aqueous solution and specific adsorption on segregation of Pt-ML/M-ML/Pt(111) (M = Cu, Pd, Au): a DFT study. PHYSICAL CHEMISTRY CHEMICAL PHYSICS[J]. 2021, 23(2): 1584-1589, http://dx.doi.org/10.1039/d0cp04223d.
[5] Wu, Chuchu, Zhang, Xiaoming, Li, Huanqiao, Xia, Zhangxun, Yu, Shansheng, Wang, Suli, Sun, Gongquan. Iron-based binary metal-organic framework nanorods as an efficient catalyst for the oxygen evolution reaction. CHINESE JOURNAL OF CATALYSIS[J]. 2021, 42(4): 637-647, http://dx.doi.org/10.1016/S1872-2067(20)63686-5.
[6] Xu, Xinlong, Zhang, Xiaoming, Xia, Zhangxun, Sun, Ruili, Li, Huanqiao, Wang, Junhu, Yu, Shansheng, Wang, Suli, Sun, Gongquan. Solid phase microwave-assisted fabrication of Fe-doped ZIF-8 for single-atom Fe-N-C electrocatalysts on oxygen reduction. JOURNALOFENERGYCHEMISTRY[J]. 2021, 54(3): 579-586, http://lib.cqvip.com/Qikan/Article/Detail?id=7104209058.
[7] 吴楚楚, 张晓明, 李焕巧, 夏章讯, 于陕升, 王素力, 孙公权. 具有高效析氧催化性能的铁基双元金属有机框架纳米棒研究. 催化学报[J]. 2021, 42(4): 637-647, http://lib.cqvip.com/Qikan/Article/Detail?id=7103978630.
[8] 吴楚楚, 张晓明, 李焕巧, 夏章讯, 于陕升, 王素力, 孙公权. Iron‐based binary metal‐organic framework nanorods as an efficient catalyst for the oxygen evolution reaction. CHINESE JOURNAL OF CATALYSIS[J]. 2021, 637-647, https://kns.cnki.net/KCMS/detail/detail.aspx?dbcode=CJFQ&dbname=CJFDLAST2021&filename=CHUA202104011&v=MjIyNjc0SE5ETXE0OUVaWVI4ZVgxTHV4WVM3RGgxVDNxVHJXTTFGckNVUjd1ZlllZG5GQ3JsV3J2UEppWGViN0c=.
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[13] Zhang, Xiaoming, Xia, Zhangxun, Li, Huanqiao, Yu, Shansheng, Wang, Suli, Sun, Gongquan. Theoretical study of the strain effect on the oxygen reduction reaction activity and stability of FeNC catalyst. NEW JOURNAL OF CHEMISTRY[J]. 2020, 44(17): 6818-6824, https://www.webofscience.com/wos/woscc/full-record/WOS:000532252100015.
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[16] Tan, Xiangdong, Li, Huanqiao, Li, Xianru, Sun, Wenjing, Jin, Chengyu, Chen, Lili, Wei, Huangzhao, Sun, Chenglin. A novel isophorone wastewater treatment technology-wet electrocatalytic oxidation and its degradation mechanism study. JOURNAL OF HAZARDOUS MATERIALS[J]. 2020, 389: http://dx.doi.org/10.1016/j.jhazmat.2020.122035.
[17] Xu, Xinlong, Xia, Zhangxun, Zhang, Xiaoming, Sun, Ruili, Sun, Xuejing, Li, Huanqiao, Wu, Chuchu, Wang, Junhu, Wang, Suli, Sun, Gongquan. Atomically dispersed Fe-N-C derived from dual metal-organic frameworks as efficient oxygen reduction electrocatalysts in direct methanol fuel cells. APPLIED CATALYSIS B-ENVIRONMENTAL[J]. 2019, 259: http://dx.doi.org/10.1016/j.apcatb.2019.118042.
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[24] 吕洋, 宋玉江, 刘会园, 李焕巧. 内核含Pd的Pt基核壳结构电催化剂. 物理化学学报[J]. 2017, 33(2): 283-294, http://lib.cqvip.com/Qikan/Article/Detail?id=671163687.
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[27] 李焕巧. Platinum Whiskers Decorated Polyaniline Nanoarrays as Ordered Electrode Enable High Catalysts Efficiency and Enhanced Mass Transport for PEMFCs. J Mater Chem A. 2017, [28] Fu, Xudong, Wang, Suli, Li, Huanqiao, Xia, Zhangxun, Jiang, Luhua, Sun, Gongquan. Hybrid polymer matrix composite containing polyaniline and Nafion as novel precursor of the enhanced catalyst for oxygen reduction reaction. RSC ADVANCES[J]. 2016, 6(65): 59961-59969, http://cas-ir.dicp.ac.cn/handle/321008/170434.
[29] 姚瑞, 宋玉江, 李焕巧, 李佳, 刘建国. 担载型纳米金的制备参数优化及电催化性能探索. 电化学[J]. 2016, 22(2): 147-156, http://sciencechina.cn/gw.jsp?action=detail.jsp&internal_id=5700253&detailType=1.
[30] 李焕巧. 具有核壳结构的PtPdAu三元纳米电催化剂的可控制备及氧还原反应活性. J Physical Chemistry C. 2015, [31] Li, Shushuang, Li, Huanqiao, Zhang, Yansheng, Garcia, Robert M, Li, Jia, Xie, Yan, Yin, Jie, Li, Mingrun, Wang, Junhu, Shelnutt, John A, Zhang, Tao, Song, Yujiang. One-step synthesis of carbon-supported foam-like platinum with enhanced activity and durability. JOURNAL OF MATERIALS CHEMISTRY A[J]. 2015, 3(43): 21562-21568, https://www.webofscience.com/wos/woscc/full-record/WOS:000364020400020.
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[39] 张艳生, 李焕巧, 李书双, 李佳, 谢妍, 吕洋, 宋玉江. Designed Synthesis of Carbon-supported Foam-like Platinum Nanocatalyst with Enhanced Activity and Durability by Using a Bi-functional Reaction Micro-environment. MRS FALL MEETINGnull. 2012, 0-, http://159.226.238.44/handle/321008/117106.
[40] 司维峰, 李焕巧, 宋玉江. Zinc (II) Porphyrin-Controlled Synthesis of Uniform Platinum Nanodendrites with Markedly Enhanced Electrocatalytic Performance. SEVENTH INTERNATIONAL CONFERENCE ON PORPHYRINS AND PHTHALOCYANINESnull. 2012, 0-, http://159.226.238.44/handle/321008/117157.
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[44] 李焕巧. Three Electrolytes High Voltage Acid-alkaline Hybrid Rechargeable Battery. Electrochimica Acta. 2011, [45] 张涛. Monomorphic platinum octapod and tripod nanocrystals synthesized by an iron nitrate modified polyol process. CHEM COMMUN. 2011, 47(43): ,11966-11968, [46] Zhu, Mingyuan, Sun, Gongquan, Yan, Shiyou, Li, Huanqiao, Xin, Qin. Preparation, Structural Characterization, and Activity for Ethanol Oxidation of Carbon-Supported PtSnIn Catalyst. ENERGY & FUELS[J]. 2009, 23(1-2): 403-407, http://159.226.238.44/handle/321008/102421.
[47] 张媛媛, 李相一, 李焕巧. Nafion修饰Pt/C电催化剂的制备与表征. 电源技术[J]. 2009, 33(5): 379-382, http://lib.cqvip.com/Qikan/Article/Detail?id=30418061.
[48] 朱明远, 孙公权, 李焕巧, 曹雷, 辛勤. Sn（Ⅱ）／Sn（Ⅳ）对PtSn／C乙醇电化学氧化活性的影响. 催化学报[J]. 2008, 29(8): 765-770, http://lib.cqvip.com/Qikan/Article/Detail?id=28153188.
[49] Zhu Mingyuan, Sun Gongquan, Li Huanqiao, Cao Lei, Xin Qin. Effect of the Sn(I)/Sn(IV) redox couple on the activity of PtSn/C for ethanol electro-oxidation. CHINESE JOURNAL OF CATALYSIS[J]. 2008, 29(8): 765-770, http://159.226.238.44/handle/321008/140877.
[50] Li, Huanqiao, Sun, Gongquan, Cao, Lei, Jiang, Luhua, Xin, Qin. Comparison of different promotion effect of PtRu/C and PtSn/C electrocatalysts for ethanol electro-oxidation. ELECTROCHIMICA ACTA[J]. 2007, 52(24): 6622-6629, http://dx.doi.org/10.1016/j.electacta.2007.04.056.
[51] 王素力, 李焕巧, 孙公权. 直接醇类燃料电池研究进展. 第十四次全国电化学会议null. 2007, 1329/1-, http://159.226.238.44/handle/321008/112668.
[52] Li, Huanqiao, Sun, Gongquan, Jiang, Qian, Zhu, Mingyuan, Sun, Shiguo, Xin, Qin. Synthesis of highly dispersed Pd/C electro-catalyst with high activity for formic acid oxidation. ELECTROCHEMISTRY COMMUNICATIONS[J]. 2007, 9(6): 1410-1415, http://dx.doi.org/10.1016/j.elecom.2007.01.032.
[53] Li, Huanqiao, Sun, Gongquan, Jiang, Qian, Zhu, Mingyuan, Sun, Shiguo, Xin, Qin. Preparation and characterization of Pd/C catalyst obtained in NH3-mediated polyol process. JOURNAL OF POWER SOURCES[J]. 2007, 172(2): 641-649, http://dx.doi.org/10.1016/j.jpowsour.2007.05.024.
[54] Cao, Lei, Sun, Gongquan, Li, Huanqiao, Xin, Qin. Carbon-supported IrSn catalysts for a direct ethanol fuel cell. ELECTROCHEMISTRY COMMUNICATIONS[J]. 2007, 9(10): 2541-2546, http://dx.doi.org/10.1016/j.elecom.2007.07.031.
[55] Li, Huanqiao, Sun, Gongquan, Gaot, Yan, Jiang, Qian, Jia, Ziqi, Xin, Qin. Effect of reaction atmosphere on the electrocatalytic activities of Pt/C and PtRu/C obtained in a polyol process. JOURNAL OF PHYSICAL CHEMISTRY C[J]. 2007, 111(42): 15192-15200, http://159.226.238.44/handle/321008/99287.
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（ 1 ） 中科院大连化物所所创新基金, 参与, 市地级, 2010-01--2014-12
（ 2 ） 博士科研探索基金, 主持, 市地级, 2012-01--2012-12
（ 3 ） 石墨烯担载的In基纳米材料用于CO2电催化转化制甲酸, 主持, 国家级, 2014-01--2016-12
（ 4 ） 基于Pd-Au/碳纳米管阵列的过氧化氢电还原过程的研究, 主持, 部委级, 2015-06--2016-06

（1）A Novel Pt Nano-chrysanthemum Catalyst   第十六届全国催化学术会   Huanqiao Li, Shushuang Li, Yan Xie, Jia Li, Yang Lv, Yujiang Song   2012-10-16