基本信息
电子邮件：xiangping@dicp.ac.cn
联系电话：0411-84379276
手机号码：13941154646
通信地址：辽宁省大连市中山路457号催化楼109房间化物所2T2组
邮政编码：116023
研究领域
主要从事新型手性配体的设计合成及其在不对称催化反应，特别是炔丙基转化反应中的应用研究。
招生信息
拟招收硕士研究生2 人，博士研究生2人
招生专业
070303-有机化学
招生方向
不对称催化；催化氧化；催化氢化
教育背景
1992.9-1996.7 中国农业大学农业应用化学专业学习，获理学学士学位；
1996.9-1999.7 中国农业大学农药学专业学习，获理学硕士学位；
1999.9-2003.6 中国科学院大连化物所有机化学专业学习，获理学博士学位；
1996.9-1999.7 中国农业大学农药学专业学习，获理学硕士学位；
1999.9-2003.6 中国科学院大连化物所有机化学专业学习，获理学博士学位；
学历
中国科学院大连化学物理研究所 --20030630 研究生毕业
学位
-- 博士
出国学习工作
2005.2-2006.2 英国爱丁堡大学化学系博士后
工作经历
2003.7-2005.2 中国科学院大连化物所工作，助理研究员；
2006.6-2007.10 中国科学院大连化物所工作，助理研究员；
2007.10-2013.6 中国科学院大连化物所工作，副研究员；
2008.10-2011.2 中国科学院大连化物所206组副组长；
2011.5起任中国科学院大连化物所2T2组组长；
2013.7起任中国科学院大连化物所研究员。
2006.6-2007.10 中国科学院大连化物所工作，助理研究员；
2007.10-2013.6 中国科学院大连化物所工作，副研究员；
2008.10-2011.2 中国科学院大连化物所206组副组长；
2011.5起任中国科学院大连化物所2T2组组长；
2013.7起任中国科学院大连化物所研究员。
教授课程
有机化学研究进展
专利与奖励
申请专利55项，授权7项
奖励信息
（1） Thieme Chemistry Journals Award 2015，其他级，2015
（2） 科技创新奖，研究所（学校）级，2014
（2） 科技创新奖，研究所（学校）级，2014
专利成果
[1] 胡向平, 陈松. 一种无磷缓释阻垢剂及其合成方法. CN: CN111099752B, 2022-03-18.[2] 胡向平, 夏金涛. 一种α,α-二取代的含手性季碳中心的α-苯甲酰氨基酸甲酯类化合物的合成方法. CN: CN112142616B, 2021-12-21.[3] 胡向平, 许有伟. 一种手性3,4,4-三取代吡咯烷酮类化合物的催化不对称合成方法. CN: CN111825509B, 2021-12-21.[4] 胡向平, 刘振婷. 一种基于碳-氢键活化的制备四取代呋喃类化合物的方法. CN: CN108976186B, 2021-12-10.[5] 胡向平, 刘振婷, 李玲. 一种手性1,4-二氢吡喃并2,3-c吡唑类化合物的合成方法. CN: CN108976241B, 2021-11-30.[6] 胡向平, 陈松. 以联萘二胺为骨架的席夫碱Cu(Ⅱ)络合物及其制备方法. CN: CN111138312B, 2021-11-09.[7] 胡向平, 阿里·艾杰斯. 一种手性4,6-二氧八氢吡咯并3,4-c吡咯-1-羧酸酯类化合物的合成方法. CN: CN113461690A, 2021-10-01.[8] 胡向平, 杜洪泉. 一种手性膦-亚磷酰胺酯配体及其制备方法和应用. CN: CN112824421A, 2021-05-21.[9] 胡向平, 阿巴斯·查希尔. 一种手性二茂铁-吲哚双膦配体及其制备方法和其应用. CN: CN112824422A, 2021-05-21.[10] 胡向平, 刘振婷. 一种镍催化亚胺不对称氢化制备手性胺化合物的方法. CN: CN112824374A, 2021-05-21.[11] 胡向平, 阿巴斯·查希尔. 一种手性二茂铁膦-吲哚氨基膦配体及其制备方法和应用. CN: CN112824423A, 2021-05-21.[12] 胡向平, 韩姣. 一种(E)-3-芳基-3-(2-甲基肼基)丙酸酯类化合物及其制备方法和应用. CN: CN112824379A, 2021-05-21.[13] 胡向平, 陈修帅. 一种3,4-二甲基吡唑-5-甲酸酯类化合物的制备方法. CN: CN112824393A, 2021-05-21.[14] 胡向平, 刘振婷. 一种钯催化亚胺不对称氢化制备手性胺化合物的方法. CN: CN112824375A, 2021-05-21.[15] 胡向平, 危得全. 一种手性(E)-2-(1,3-二芳基烯丙基)丙二酸二甲酯类化合物及其制备方法. CN: CN112824371A, 2021-05-21.[16] 胡向平, 刘振婷. 铜催化烯烃的不对称环丙烷化方法及其应用. CN: CN112824372A, 2021-05-21.[17] 胡向平, 夏金涛. 一种炔丙基化含连续手性中心的3,3-二取代吲哚啉-2-酮类化合物及其合成方法. CN: CN112824384A, 2021-05-21.[18] 胡向平, 许有伟. 手性1′H-螺吲哚啉-3,4′-吡喃并2,3-c吡唑-2-酮类化合物. CN: CN112824412A, 2021-05-21.[19] 胡向平, 刘振婷. 一种手性二茂铁-咪唑双膦配体及其合成方法和应用. CN: CN112824424A, 2021-05-21.[20] 胡向平, 刘振婷. 铱催化亚胺不对称氢化制备手性胺的方法. CN: CN112824373A, 2021-05-21.[21] 胡向平, 韩姣. 一种3-(1H-吡唑-1-基)丙烯酸乙酯类化合物的制备方法. CN: CN112661700A, 2021-04-16.[22] 胡向平, 胡信虎. 一种手性2,3-二取代四氢喹啉衍生物的合成方法. CN: CN112521333A, 2021-03-19.[23] 胡向平, 胡信虎. 一种手性α-氨基酸酯衍生物的合成方法. CN: CN112279743A, 2021-01-29.[24] 胡向平, 危得全. 一种手性芳基肟醚化合物的制备方法. CN: CN112279779A, 2021-01-29.[25] 胡向平, 杜洪泉. 一种手性N-（2-（磷酰基）-1-苯乙基）酰胺的制备方法及应用. CN: CN112209965A, 2021-01-12.[26] 胡向平, 胡信虎. 一种基于果糖衍生的手性单齿亚磷酸酯配体酮的不对称还原胺化的方法. CN: CN111285770A, 2020-06-16.[27] 胡向平, 陈松. 一种通过催化体系合成聚天冬氨酸的方法. CN: CN111286026A, 2020-06-16.[28] 胡向平, 胡信虎. 一种基于葡萄糖衍生的单齿亚磷酸酯配体不对称氢化制备手性胺方法. CN: CN111285773A, 2020-06-16.[29] 胡向平, 胡信虎. 一种基于果糖衍生的吡啶醇类手性配体应用于酮的不对称还原胺化的方法. CN: CN111285775A, 2020-06-16.[30] 胡向平, 胡信虎. 基于D-甘露醇衍生的手性单齿膦配体不对称氢化亚胺方法. CN: CN111285774A, 2020-06-16.[31] 胡向平, 陈松. 一种采用催化体系合成聚天冬氨酸的方法. CN: CN111217998A, 2020-06-02.[32] 胡向平, 陈松. 一种采用催化体系合成聚琥珀酰亚胺的方法. CN: CN111171316A, 2020-05-19.[33] 胡向平, 陈松. 一种采用催化体系合成聚环氧琥珀酸盐的方法. CN: CN111100283A, 2020-05-05.[34] 胡向平, 陈松. 一种聚环氧琥珀酸复配物的合成方法. CN: CN111100282A, 2020-05-05.[35] 胡向平, 胡信虎. 一种酮的不对称还原胺化制备手性胺的方法. CN: CN110551033A, 2019-12-10.[36] 胡向平, 胡信虎. 一种铱催化酮的不对称还原胺化方法. CN: CN110551035A, 2019-12-10.[37] 胡向平, 胡信虎. 一种铱/手性亚磷酸酯-吡啶催化亚胺不对称氢化方法. CN: CN110551036A, 2019-12-10.[38] 胡向平, 胡信虎. 一种铱/手性双膦体系催化亚胺不对称氢化方法. CN: CN110551037A, 2019-12-10.[39] 胡向平, 胡信虎. 一种酮的不对称还原胺化方法. CN: CN110551034A, 2019-12-10.[40] 胡向平, 胡信虎. 一种铱/线型膦-亚磷酰胺体系催化亚胺不对称氢化方法. CN: CN110548546A, 2019-12-10.[41] 胡向平, 胡信虎. 铱手性膦-胺基膦配体体系催化酮的不对称还原胺化方法. CN: CN110551032A, 2019-12-10.[42] 胡向平, 陈松. 一种制备反式右旋菊酸的方法. CN: CN110467527A, 2019-11-19.[43] 胡向平, 陈松. 一种制备手性反式第一菊酸的方法. CN: CN110343040A, 2019-10-18.[44] 胡向平, 陈松. 一种用于手性反式第一菊酸制备的Salen/Ru催化剂. CN: CN109954516A, 2019-07-02.[45] 胡向平, 陈松. 一种5,5,5-三氯-2-甲基-2-戊烯的合成方法. CN: CN109879718A, 2019-06-14.[46] 胡向平, 刘振婷. 一种九元环化合物的合成方法. CN: CN109851607A, 2019-06-07.[47] 胡向平, 李坤, 刘振婷. 一种手性苯并环状β-酮酯类化合物的合成方法. CN: CN109851504A, 2019-06-07.[48] 胡向平, 邵龙. 一种高位阻手性P,N,N配体及其制备方法和应用. CN: CN109836457A, 2019-06-04.[49] 胡向平, 陈修帅, 侯传金. 一种铱催化不对称氢化制备手性醇的方法. CN: CN109776245A, 2019-05-21.[50] 胡向平, 陈修帅, 侯传金. 基于苯乙胺骨架的手性P,N,N配体类化合物及制备方法与应用. CN: CN109776610A, 2019-05-21.[51] 胡向平, 胡信虎. 一种不对称氢化亚胺制备手性胺的方法. CN: CN109422602A, 2019-03-05.[52] 胡向平, 胡信虎. 一种铱催化不对称氢化亚胺合成手性胺化合物的方法. CN: CN109422603A, 2019-03-05.[53] 胡向平, 邵龙. 一种制备手性炔丙基化的脂肪族六元碳环类化合物的方法. CN: CN108101758A, 2018-06-01.[54] 胡向平, 侯传金. 一种铱催化不对称氢化制备手性β-羟基酯的方法. CN: CN108101785A, 2018-06-01.[55] 胡向平, 邵龙. 一种制备手性4-(2-炔丙基)苯酚类化合物的方法. CN: CN108101755A, 2018-06-01.[56] 胡向平, 张德旸. 一种手性α-氟-β-乙炔基酮化合物的催化不对称合成方法. CN: CN108059591A, 2018-05-22.[57] 胡向平, 侯传金. 一种高位阻手性二茂铁P,N,N配体及制备方法与应用. CN: CN107522751A, 2017-12-29.[58] 胡向平, 邵龙. 一种制备手性炔丙基芳基醚类化合物的方法. CN: CN106866389A, 2017-06-20.[59] 胡向平, 朱付林. 2-位含有手性季碳中心的3-亚甲基-2，3-二氢呋喃的合成方法. CN: CN106854191A, 2017-06-16.[60] 胡向平, 胡信虎. 含PNN结构骨架配体的三元催化剂体系及其应用. CN: CN106853378A, 2017-06-16.[61] 胡向平, 胡信虎. 一种三元催化剂体系及其在乙烯选择性齐聚的应用. CN: CN106853379A, 2017-06-16.[62] 胡向平, 张德旸. 一种制备含有两个手性中心α-氟-β-乙炔基酮化合物的方法. CN: CN106854125A, 2017-06-16.[63] 胡向平, 邵龙. 一种制备手性2-亚甲基-2，3-二氢萘并2，1-b呋喃类化合物的方法. CN: CN106478567A, 2017-03-08.[64] 胡向平, 刘振婷. 一种制备手性二氢1,4-苯并噁嗪类化合物的方法. CN: CN106478539A, 2017-03-08.[65] 胡向平, 张德旸. 一种制备手性4,5-二氢吡唑类化合物的方法. CN: CN105732502A, 2016-07-06.[66] 胡向平, 朱付林. 一种制备手性3-亚甲基-2，3-二氢呋喃类化合物的方法. CN: CN105732550A, 2016-07-06.[67] 胡向平, 朱付林. 一种制备手性2-亚甲基-2，3-二氢呋喃的方法. CN: CN105294372A, 2016-02-03.[68] 胡向平, 王亚辉. 一种手性炔丙基胺化合物的催化不对称合成方法. CN: CN104693143A, 2015-06-10.[69] 胡向平, 王亚辉. 一种手性β-乙炔基酮化合物的催化不对称合成方法. CN: CN104692989A, 2015-06-10.[70] 胡向平, 朱付林. 一种由β-酮酸不对称合成手性β-乙炔基酮的方法. CN: CN104513146A, 2015-04-15.[71] 胡向平, 朱付林. 一种手性β-乙炔基酮化合物的催化不对称合成方法. CN: CN104513117A, 2015-04-15.[72] 胡向平, 张成. 一种手性双环n.3.1化合物的催化不对称合成方法. CN: CN103570513A, 2014-02-12.[73] 胡向平, 侯传金. 一种高位阻手性芳香胺化合物的不对称氢化合成方法. CN: CN103570484A, 2014-02-12.[74] 胡向平, 张成. 一种手性铜催化剂催化合成手性炔丙基胺化合物的方法. CN: CN102826947A, 2012-12-19.[75] 胡向平, 郑卓. 一种手性单齿亚磷酸酯配体及制备方法和应用. CN: CN1951946A, 2007-04-25.[76] 胡向平, 郑卓. 一种膦－亚磷酰胺酯配体和制备方法及应用. CN: CN1951945A, 2007-04-25.[77] 郑卓, 胡向平. 一种以膦－亚磷酰胺酯为配体的催化剂及制法和应用. CN: CN1768944A, 2006-05-10.
出版信息
以第一和通讯作者发表手性配体设计和不对称催化相关论文100余篇，包括J. Am. Chem. Soc. 1篇，Angew. Chem. Int. Ed. 4篇，撰写英文专著章节2章。
发表论文
[1] Wan, YinBo, Hu, XiangPing. Highly Enantioselective Iridium-Catalyzed Hydrogenation of o-Amidophenyl Ketones Enabled by 1,2-Diphenylethylenediamine- Derived P,N,N-Ligands with Tertiary Amine Terminus. ORGANIC LETTERS[J]. 2022, 24(31): 5797-5801, http://dx.doi.org/10.1021/acs.orglett.2c02316.[2] Ma, Jingbo, Wang, Xinhong, Liu, Zhenting, Hu, Xiangping. Highly Diastereo- and Enantioselective Copper-Catalyzed Dipropargylic Amination to Access Bispropargylic Diamines. ASIAN JOURNAL OF ORGANIC CHEMISTRY[J]. 2022, 11(10): http://dx.doi.org/10.1002/ajoc.202200385.[3] Li, Ling, Chen, XiuShuai, Hu, XiangPing. Intramolecular Copper-Catalyzed Asymmetric Propargylic 4+2-Cycloaddition toward Optically Active Tetrahydroisoindolo2,1-aquinoxalines. ORGANIC LETTERS[J]. 2022, 24(29): 5433-5438, http://dx.doi.org/10.1021/acs.orglett.2c02155.[4] Nan, LongFei, Chen, XiuShuai, Chen, Hao, Hu, XinHu, Wang, XinHong, Hu, XiangPing. Development of spirocyclic phosphoramidite-based hybrid diphosphorus ligands for enantioselective iridium-catalyzed hydrogenation of imines. ORGANIC & BIOMOLECULAR CHEMISTRY[J]. 2022, 20(43): 8420-8424, [5] Dong, Chao, Liu, DaoSheng, Zhang, Lei, Hu, XiangPing. Rh-catalyzed asymmetric hydrogenation of alpha-aryl-beta-alkylvinyl esters with chiral ferrocenylphosphine-phosphoramidite ligand. TETRAHEDRON LETTERS[J]. 2021, 65: http://dx.doi.org/10.1016/j.tetlet.2020.152763.[6] Chao Dong, DaoSheng Liu, Lei Zhang, XiangPing Hu. Rh-catalyzed asymmetric hydrogenation of α-aryl-β-alkylvinyl esters with chiral ferrocenylphosphine-phosphoramidite ligand. TETRAHEDRON LETTERS. 2021, 65: http://dx.doi.org/10.1016/j.tetlet.2020.152763.[7] Xia, JinTao, Li, Ling, Hu, XiangPing. Copper-Catalyzed Decarboxylative Propargylic Alkylation of Enol Carbonates: Stereoselective Synthesis of Quaternary alpha-Amino Acids. ACS CATALYSIS[J]. 2021, 11(19): 11843-11848, http://dx.doi.org/10.1021/acscatal.1c03421.[8] Ma, YinFeng, Hou, ChuanJin, Wei, DeQuan, He, Xinwei, Chu, TingTing, Chen, Xiushuai, Hu, XiangPing. Iridium-catalyzed asymmetric hydrogenation of beta-ketophosphonates with chiral ferrocenyl P,N,N-ligands. APPLIED ORGANOMETALLIC CHEMISTRY[J]. 2021, 35(8): http://dx.doi.org/10.1002/aoc.6283.[9] Li, Ling, Liu, ZhenTing, Hu, XiangPing. Copper-Catalyzed One-Pot Cascade Cyclization for the Synthesis of Isoindolo2,1-aquinoxalines. ADVANCED SYNTHESIS & CATALYSIS[J]. 2021, 363(17): 4272-4276, http://dx.doi.org/10.1002/adsc.202100643.[10] Du, HongQuan, Hu, XiangPing. Bicyclic Bridgehead Phosphoramidite-Based Hybrid Diphosphorus Ligands: Design, Synthesis, and Application in Catalytic Asymmetric Hydrogenation. ORGANIC LETTERS[J]. 2021, 23(19): 7678-7682, http://dx.doi.org/10.1021/acs.orglett.1c02978.[11] Abbas, Zaheer, Hu, XinHu, Ali, Aijaz, Xu, YouWei, Hu, XiangPing. New chiral ferrocene/indole-based diphosphine ligands for Rh-catalyzed asymmetric hydrogenation of functionalized olefins. TETRAHEDRON LETTERS[J]. 2020, 61(20): http://dx.doi.org/10.1016/j.tetlet.2020.151860.[12] Han, Jiao, Xu, YouWei, Wang, XueMing, Zhang, Lei, Hu, XiangPing. Copper-catalyzed formal propargylic 3+2 cycloaddition for stereoselective construction of (E)-beta-pyrazolylacrylates. TETRAHEDRON LETTERS[J]. 2020, 61(3): https://www.webofscience.com/wos/woscc/full-record/WOS:000510110600013.[13] Xia, JinTao, Hu, XiangPing. Copper-Catalyzed Asymmetric Propargylic Alkylation with Oxindoles: Diastereo- and Enantioselective Construction of Vicinal Tertiary and All-Carbon Quaternary Stereocenters. ORGANIC LETTERS[J]. 2020, 22(3): 1102-1107, https://www.webofscience.com/wos/woscc/full-record/WOS:000513082700067.[14] Xu, YouWei, Li, Ling, Hu, XiangPing. Enantioselective Copper-Catalyzed 3+3 Cycloaddition of Tertiary Propargylic Esters with 1H-Pyrazol-5(4H)-ones toward Optically Active Spirooxindoles. ORGANIC LETTERS[J]. 2020, 22(24): 9534-9538, https://www.webofscience.com/wos/woscc/full-record/WOS:000607016900025.[15] Zhang, Yutong, Han, Fuzhong, Jia, Lina, Hu, Xiangping. The catalyst-free decarboxylative dearomatization of isoquinolines with beta-keto acids and sulfonyl chlorides in water: access to dihydroisoquinoline derivatives. ORGANIC & BIOMOLECULAR CHEMISTRY[J]. 2020, 18(42): 8646-8652, https://www.webofscience.com/wos/woscc/full-record/WOS:000584879900008.[16] Xiangping Hu. Rh-Catalyzed Asymmetric Hydrogenation of (Z)‑β-Phosphorylated Enamides: Highly Enantioselective Access to β‑Aminophosphines. Org. Lett.. 2019, [17] Du, HongQuan, Hu, XiangPing. Rh-Catalyzed Asymmetric Hydrogenation of (Z)-beta-Phosphorylated Enamides: Highly Enantioselective Access to beta-Arninophosphines. 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Highly enantioselective copper-catalyzed propargylic substitution of propargylic acetates with 1,3-diczrbonyl compounds. ORGANIC LETTERS[J]. 2014, 16: 588-, http://159.226.238.44/handle/321008/119768.[92] 王东, 侯传金, 陈丽凤, 刘小宁, 安庆大, 胡向平. 亚胺的不对称催化氢化研究进展. 有机化学[J]. 2013, 33(7): 1355-, http://159.226.238.44/handle/321008/119644.[93] Guo, Hongchao, Liu, Honglei, Zhu, FuLin, Na, Risong, Jiang, Hui, Wu, Yang, Zhang, Lei, Li, Zhen, Yu, Hao, Wang, Bo, Xiao, Yumei, Hu, XiangPing, Wang, Min. Enantioselective Copper-Catalyzed 3+3 Cycloaddition of Azomethine Ylides with Azomethine Imines. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2013, 52(48): 12641-12645, http://www.irgrid.ac.cn/handle/1471x/858280.[94] Yan, Sheng, Zhang, Cheng, Wang, YaHui, Cao, Zhong, Zheng, Zhuo, Hu, XiangPing. Synthesis of new chiral ferrocenyl P,N-ligands with a benzoxazole ring and their application in Ag-catalyzed asymmetric 3+2 cycloaddition. 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Enantioselective Synthesis of β-Aryl-γ-amino Acid Derivatives via Cu-Catalyzed Asymmetric 1;4-Reductions of γ-Phthalimido-Substituted α;β-Unsaturated Carboxylic Acid Esters. JOURNAL OF ORGANIC CHEMISTRY[J]. 2008, 73(15): 6022-6024, http://159.226.238.44/handle/321008/100243.[138] Yu, SaiBo, Hu, XiangPing, Deng, Jun, Huang, JiaDi, Wang, DaoYong, Duan, ZhengChao, Zheng, Zhuo. Ferrocence-based phosphine-triazine ligands for highly efficient Suzuki-Miyaura cross-coupling reaction of aryl chlorides. TETRAHEDRON LETTERS[J]. 2008, 49(7): 1253-1256, http://dx.doi.org/10.1016/j.tetlet.2007.12.007.[139] Deng, Jun, Hu, XiangPing, Huang, JiaDi, Yu, SaiBo, Wang, DaoYong, Duan, ZhengChao, Zheng, Zhuo. Enantioselective synthesis of beta(2)-Amino acids via Rh-catalyzed asymmetric hydrogenation with BoPhoz-type ligands: Important influence of an N-H proton in the ligand on the enantioselectivity. JOURNAL OF ORGANIC CHEMISTRY[J]. 2008, 73(5): 2015-2017, http://159.226.238.44/handle/321008/141103.[140] 邓军, 胡向平, 黄佳娣, 喻赛波, 王道永, 段正超, 郑卓. Enantioselective Synthesis of β2-Amino Acids via Rh-Catalyzed Asymmetric Hydrogenation with BoPhoz-Type Ligands: Important Influence of an N-H Proton in the Ligand on the Enantioselectivity. JOURNAL OF ORGANIC CHEMISTRY[J]. 2008, 73(5): 2015-2017, http://159.226.238.44/handle/321008/100235.[141] Qiu, Min, Hu, XiangPing, Huang, JiaDi, Wang, DaoYong, Deng, Jun, Yu, SaiBo, Duan, ZhengChao, Zheng, Zhuo. Modular Phosphine-Aminophosphine Ligands Based on Chiral 1,2,3,4-Tetrahydro-1-naphthylamine Backbone: A New Class of Practical Ligands for Enantioselective Hydrogenations. ADVANCED SYNTHESIS & CATALYSIS[J]. 2008, 350(17): 2683-2689, http://159.226.238.44/handle/321008/140991.[142] Qiu, Min, Hu, XiangPing, Wang, DaoYong, Deng, Jun, Huang, JiaDi, Yu, SaiBo, Duan, ZhengChao, Zheng, Zhuo. Chiral 1,2,3,4-tetrahydro-1-naphthylamine-derived phosphine-phosphoramidite ligand (THNAPhos): Application in highly enantioselective hydrogenations of functionalized C=C bonds. ADVANCED SYNTHESIS & CATALYSIS[J]. 2008, 350(9): 1413-1418, http://159.226.238.44/handle/321008/100241.[143] Wang, DaoYong, Hu, XiangPing, Huang, JiaDi, Deng, Jun, Yu, SaiBo, Duan, ZhengChao, Xu, XueFeng, Zheng, Zhuo. Highly enantioselective synthesis of alpha-hydroxy phosphonic acid derivatives by Rh-catalyzed asymmetric hydrogenation with phosphine-phosphoramidite ligands. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2007, 46(41): 7810-7813, http://159.226.238.44/handle/321008/140627.[144] Deng, Jun, Duan, ZhengChao, Huang, JiaDi, Hu, XiangPing, Wang, DaoYong, Yu, SaiBo, Xu, XueFeng, Zheng, Zhuo. Rh-catalyzed asymmetric hydrogenation of gamma-phthalimido-substituted alpha,beta-unsaturated carboxylic acid esters: An efficient enantioselective synthesis of beta-aryl-gamma-amino acids. ORGANIC LETTERS[J]. 2007, 9(23): 4825-4828, http://159.226.238.44/handle/321008/140682.[145] Huang, JiaDi, Hu, XiangPing, Yu, SaiBo, Deng, Jun, Wang, DaoYong, Duan, ZhengChao, Zheng, Zhuo. Readily available phosphine-imine ligands from alpha-phenylethylamine for highly efficient Pd-catalyzed asymmetric allylic alkylation. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL[J]. 2007, 270(1-2): 127-131, http://159.226.238.44/handle/321008/140675.[146] 黄佳娣, 胡向平, 喻赛波, 邓军, 王道永, 段正超, 郑卓. Readily available phosphine–imine ligands from -phenylethylamine for highly efficient Pd-catalyzed asymmetric allylic alkylation. JOURNAL OF MOLECULAR CATALYSIS A[J]. 2007, 270: 127-131, http://159.226.238.44/handle/321008/99399.[147] 王道永, 胡向平, 黄佳娣, 邓军, 喻赛波, 段正超, 徐雪峰, 郑卓. Highly Enantioselective Synthesis of a-Hydroxy Phosphonic Acid Derivatives by Rh-Catalyzed Asymmetric Hydrogenation with Phosphine–Phosphoramidite Ligands. ANGEWANDTE CHEMIE INTERNATIONAL EDITION[J]. 2007, 46: 7810-7813, http://159.226.238.44/handle/321008/99395.[148] 邓军, 段正超, 黄佳娣, 胡向平, 王道永, 喻赛波, 徐雪峰, 郑卓. Rh-Catalyzed Asymmetric Hydrogenation of ç-Phthalimido-Substituted r;â-Unsaturated Carboxylic Acid Esters: An Efficient Enantioselective Synthesis of â-Aryl-ç-amino Acids. ORGANIC LETTERS[J]. 2007, 9(23): 4825-4828, http://159.226.238.44/handle/321008/99397.[149] 曾庆恒, 胡向平, 梁鑫淼, 郑卓. Synthesis of Novel C2-Symmetrical Bidentate Phosphoramidite Ligands for Rh-catalyzed Asymmetric Hydrogenation of β-(Aclamino)acrylates. CHINESE CHEMICAL LETTERS（中国期刊）[J]. 2006, 17(6): 711-713, http://159.226.238.44/handle/321008/98103.[150] 曾庆恒, 胡向平, 段正超, 梁鑫淼, 郑卓. Unsymmetrical Ferrocenylethylamine-Derived Monophosphoramidetes:Highly Efficient Chiral Ligands for Rh-Catalyzed Enantioselective Hydrogenation of Enamides and α-Dehydroamino Acid Derivatives. JOURNAL OF ORGANIC CHEMISTRY[J]. 2006, 71: 393-396, http://159.226.238.44/handle/321008/98101.[151] Zeng, Qing Heng, Hu, Xiang Ping, Liang, Xin Miao, Zheng, Zhuo. Synthesis of novel C-2-symmetrical bidentate phosphoramidite ligands for Rh-catalyzed asymmetric hydrogenation of beta-(acylamino)acrylates. CHINESE CHEMICAL LETTERS[J]. 2006, 17(6): 711-713, http://159.226.238.44/handle/321008/140107.[152] Huang, JiaDi, Hu, XiangPing, Duan, ZhengChao, Zeng, QingHen, Yu, SaiBo, Deng, Jun, Wang, DaoYong, Zheng, Zhuo. Readily available phosphine-phosphoramidite ligands for highly efficient Rh-catalyzed enantioselective hydrogenations. ORGANIC LETTERS[J]. 2006, 8(19): 4367-4370, http://159.226.238.44/handle/321008/98095.[153] 曾庆恒, 胡向平, 梁鑫淼, 郑卓. Synthesis of Novel Monophosphoramidite Ligands Derived from L-Proline for Rh-catalyzed Asymmetric Hydrogenation of α-Dehydroamino Acid Esters. CHINESE CHEMICAL LETTERS（中国期刊）[J]. 2005, 16(10): 1321-1323, http://159.226.238.44/handle/321008/92703.[154] 段正超, 胡向平, 曾庆恒, 郑卓. 聚合手性二茂铁N；O-配体催化苯乙炔对醛的不对称加成反应. 催化学报[J]. 2005, 26(5): 352-354, http://159.226.238.44/handle/321008/92701.[155] 段正超, 胡向平, 曾庆恒, 郑卓. 平面手性二茂铁N，O-配体催化苯乙炔对醛的不对称加成反应. 催化学报[J]. 2005, 26(5): 352-354, http://lib.cqvip.com/Qikan/Article/Detail?id=15935272.[156] 胡向平, 陈惠麟, 郑卓. Ferrocene-Based Chiral Phosphine-Triazines: A New Family of Highly Efficent P;N Ligands for Asymmetric Catalysis. ADVANCED SYNTHESIS & CATALYSIS[J]. 2005, 347(4): 541-548, http://159.226.238.44/handle/321008/92695.[157] 胡向平, 郑卓. practical Rh(I)-Catalyzed Asymmetric Hydrogenation of β-(Acylamino)acrylates Using a New Unsymmetrical Hybrid Ferrocenylphosphine-phosphoramidite Ligand: Crucial Influence of an N-H Proton in the Ligand. ORGANIC LETTERS[J]. 2005, 7(3): 419-422, http://159.226.238.44/handle/321008/92693.[158] 戴慧聪, 胡向平, 陈惠麟, 白长敏, 郑卓. 新型手性双二茂铁希呋碱亚胺配体的合成及其在不对称环丙烷化反应中的应用. 分子催化[J]. 2004, 18(1): 1-5, http://lib.cqvip.com/Qikan/Article/Detail?id=9101747.[159] 戴慧聪, 胡向平, 陈惠麟, 白长敏, 郑卓. Efficient P;N;N-type ligands for Ru(II)-catalyzed asymmetric cyclopropanations. JOURNAL OF MOLECULAR CATAYLSIS A:CHEMICAL[J]. 2004, 211: 17-21, http://159.226.238.44/handle/321008/82131.[160] 胡向平, 陈惠麟, 戴慧聪, 胡信全, 郑卓. Synthesis and Potential Application of Novel C2-Symmetrical Bis(ferrocenyl)P2N Ligand. 中国化学快报[J]. 2003, 14(11): 1113-1115, http://159.226.238.44/handle/321008/82765.[161] Dai Huicong, Hu Xiangping, Chen Huilin, Bai Changmin, Zheng Zhuo. Chiral Schiff Base Ligands Containing Ferrocene and Pyridine Units for Ruthenium-Catalyzed Assmmetric Transfer Hydrogenation. CHINESE JOURNAL OF CATALYSIS[J]. 2003, 24(8): 565-566, http://sciencechina.cn/gw.jsp?action=detail.jsp&internal_id=1196878&detailType=1.[162] 胡向平. 平面手性二茂铁配体的设计、合成及其Pd-配合物在催化不对称烯丙基取代反应中的应用研究. 2003, http://159.226.238.44/handle/321008/104206.[163] 胡向平, 陈惠麟, 胡信全, 戴慧聪, 白长敏, 郑卓. Knochel双膦配体合成新方法及其在Pd-催化不对称烯丙基取代反应中的应用. 分子催化[J]. 2003, 17(4): 279-282, http://lib.cqvip.com/Qikan/Article/Detail?id=8193351.[164] 胡向平, 陈惠麟, 胡信全, 戴慧聪, 白长敏, 王军伟, 郑卓. Syntheses of novel ferrocenylphosphine-amidine ligands and their application in Pd-catalyzed asymmetric allylic alkylation. TETRAHEDRON LETTERS[J]. 2002, 43(50): 9179-9182, http://159.226.238.44/handle/321008/84815.[165] 胡向平, 陈惠麟, 胡信全, 郑卓. Highly effective phosphine-imine ligands for Pd-catalyzed asymmetric allylic alkylation. 14th international conference on organic synthesisnull. 2000, 273/1-, http://159.226.238.44/handle/321008/111206.[166] 胡向平, 陈惠麟, 胡信全, 郑卓. 高效手性膦-亚胺配体用于Pd-催化不对称烯丙基取代反应. 14th international conference on organic synthesisnull. 2000, 273/1-, http://159.226.238.44/handle/321008/111206.[167] Jiao Han, YouWei Xu, XueMing Wang, Lei Zhang, XiangPing Hu. Copper-catalyzed formal propargylic 3 + 2 cycloaddition for stereoselective construction of (E)-β-pyrazolylacrylates. TETRAHEDRON LETTERS. http://dx.doi.org/10.1016/j.tetlet.2019.151409.
发表著作
英文专著章节：
1. Xiang-Ping Hu, Zhuo Zheng, “Bidentate Ligands for Enantioselective Enamide Reduction”, Chapter 9 in Chiral Amine Synthesis: Methods, Developments and Application, Ed. Thomas C. Nugent, Wiley-VCH: Weinheim, 2010.
2. Xiang-Ping Hu, Duo-Sheng Wang, Chang-Bin Yu, Yong-Gui Zhou, Zhuo Zheng, " Adventure in Asymmetric Hydrogenation: Synthesis of Chiral Phosphorus Ligands and Asymmetric Hydrogenation of Heteroaromatics", in Topics in Organometallic Chemistry 2011, 36, in press.
1. Xiang-Ping Hu, Zhuo Zheng, “Bidentate Ligands for Enantioselective Enamide Reduction”, Chapter 9 in Chiral Amine Synthesis: Methods, Developments and Application, Ed. Thomas C. Nugent, Wiley-VCH: Weinheim, 2010.
2. Xiang-Ping Hu, Duo-Sheng Wang, Chang-Bin Yu, Yong-Gui Zhou, Zhuo Zheng, " Adventure in Asymmetric Hydrogenation: Synthesis of Chiral Phosphorus Ligands and Asymmetric Hydrogenation of Heteroaromatics", in Topics in Organometallic Chemistry 2011, 36, in press.
科研活动
科研项目
（ 1 ） 新型配体设计、合成及在功能有机分子合成中的应用研究, 主持, 市地级, 2011-04--2016-04（ 2 ） 精细化学品及关键中间体的技术开发, 主持, 研究所（学校）, 2013-07--2016-07（ 3 ） 3,3-亚氨基二丙腈制备氨基丙腈技术, 主持, 研究所（学校）, 2013-05--2016-05（ 4 ） 氢化催化剂和配体的技术开发, 主持, 研究所（学校）, 2014-06--2019-06（ 5 ） Cu-催化炔丙醇酯与双亲核试剂间的不对称环加成反应研究, 主持, 国家级, 2016-01--2019-12（ 6 ） 新型手性P,N,N-配体的构建及其在Cu-催化不对称炔丙基取代反应中的应用研究, 主持, 国家级, 2018-01--2021-12