张磊 研究员、博士生导师
中国科学院福建物质结构研究所
电子邮件： LZhang@fjirsm.ac.cn
通信地址： 福建省福州市鼓楼区杨桥西路155号物理楼607室
邮政编码： 350002
研究领域
金属氧簇化学；簇基功能材料
包括新型金属氧簇的合成方法、结构设计、性能调控以及应用拓展等
招生信息
招生专业
招生方向
教育背景
工作经历
2014.09-至今 中国科学院福建物质结构研究所 研究员
2013.01-2014.08 德国慕尼黑工业大学化学系 洪堡学者
2009.11-2012.12 爱尔兰都柏林大学圣三一学院化学系 博士后
荣誉与奖励
（1） 国家基金委优秀青年基金获得者（2019）
（2） 中国青年化学家元素周期表“钛”元素代言人（2019）
（3） 福建省第三批特殊支持“双百计划”青年拔尖人才（2018）
（4） 福建省杰出青年科学基金获得者（2017）
（5） 福建省引进高层次人才（海外C类）（2016）
（6） 中国科学院福建物质结构研究所“****”（2014）
（7） Alexander von Humboldt Research Fellowship（2012）
（8） 中国科学院‘朱李月华’优秀博士生（2009）
（9） Government of Ireland Postdoctoral Fellowship（2009）
（10） 南京大学优秀毕业生（2004）
代表性论文
[1] Yu Zhu, Jian Zhang, Lei Zhang*, “A core-shell type alkyl-Sn-oxo cluster of {Sn14As16} bridged by 4-aminophenylarsonate ligand and incorporated with a {Na6} cluster”, Chem. Commun. 2020, 56, 1433-1435.
[2] Simin Hou, Shumei Chen*, Jian Zhang, Lei Zhang*, “Synthesis, Crystal Structure, and Visible Light Responses of Ti4Cu4-Oxo Clusters with Mixed Valence Copper Ions”, Chin. J. Chem. 2020, 38, 87-90.
[3] Ya-Jie Liu, Wei-Hui Fang*, Lei Zhang*, Jian Zhang, “Recent advances in heterometallic polyoxotitanium clusters”, Coord. Chem. Rev. 2020, 404, 213099.
[4] Shuai Chen#, Zhe-Ning Chen#, Wei-Hui Fang, Wei Zhuang*, Lei Zhang*, Jian Zhang*, “Ag10Ti28-Oxo Cluster Containing Single-Atom Silver Sites: Atomic Structure and Synergistic Electronic Properties”, Angew. Chem. Int. Ed. 2019, 58, 10932-10935.
[5] Xi Fan, Junhui Wang, Kaifeng Wu*, Lei Zhang*, Jian Zhang*, “Isomerism in Titanium-Oxo Clusters: Molecular Anatase Model with Atomic Structure and Improved Photocatalytic Activity”, Angew. Chem. Int. Ed. 2019, 58, 1320-1323.
[6] Yu Zhu, Lei Zhang*, Jian Zhang, “Assembly of High-Nuclearity Sn26, Sn34-Oxo Clusters: Solvent Strategy and Inorganic Sn Incorporation”, Chem. Sci. 2019, 10, 9125-9129.
[7] Mei-Yan Gao, Lei Zhang*, Jian Zhang*, “Acid-Controlled Synthesis of Carboxylate-Stabilized Ti44-Oxo Clusters: Scaling up Preparation, Exchangeable Protecting Ligands and Photophysical Properties”, Chem. Eur. J. 2019, 25, 10450-10455.
[8] Yu Zhu, Morgan Rose Olsen, May Nyman*, Lei Zhang*, Jian Zhang, “Stabilizing g-Alkyltin-oxo Keggin Ions by Borate Functionalization”, Inorg. Chem. 2019, 58, 4534-4539.
[9] Xiao-Xue Liu, Shumei Chen, Wei-Hui Fang*, Lei Zhang*, Jian Zhang, “Amino-Polyalcohol-Solvothermal Synthesis of Titanium-Oxo Clusters: from Ti6 to Ti19 with Structural Diversity”, Inorg. Chem. 2019, 58, 7267-7273.
[10] Xi Fan, Hao Fu, Mei-Yan Gao, Lei Zhang*, Jian Zhang*, “One-pot and Post-synthetic Phenol-thermal Synthesis towards Highly Stable Titanium-oxo Clusters”, Inorg. Chem. 2019, 58, 13353-13359.
[11] Yu Zhu, Jian Zhang, Lei Zhang*, “Sn13-Oxo Clusters with Open Hollow Structural Motif and Decorated by Different Functional Ligands”, Inorg. Chem. 2019, 58, 15692-15695.
[12] Xi Fan, Hao Fu, Lei Zhang*, Jian Zhang, “Pyrazole-thermal Synthesis: New Approach towards N-Rich Titanium-Oxo Clusters with Photochromic Behaviors”, Dalton Trans. 2019, 48, 8049-8052.
[13] Qing-Rong Ding, Gui-Lan Xu, Lei Zhang*, Jian Zhang, “Ligand-directed assembly engineering of trapezoidal {Ti5} building blocks stabilized by dimethylglyoxime”, Dalton Trans. 2019, 48, 9916-9919.
[14] Xiao-Xue Liu, Wei-Hui Fang*, Shumei Chen, Lei Zhang*, Jian Zhang, “Wheel-shape heterometallic Ti10M2-oxo clusters (M = Ni, Co) with effective visible light absorption”, Chin. J. Chem. 2019, 37, 233-236.
[15] Guoliang Dong, Wei-Hui Fang*, Lei Zhang*, Jian Zhang, “In situ generated pyroglutamate bridged polyoxotitaniums with strong circular dichroism signal”, Chinese Chem. Lett. 2019, 30, 1005-1008.
[16] Shuai Chen, Wei-Hui Fang, Lei Zhang*, Jian Zhang*, “Atomically Precise Multimetallic Semiconductive Nanoclusters with Optical Limiting Effects”, Angew. Chem. Int. Ed. 2018, 57, 11252-11256.
[17] Wei-Hui Fang, Lei Zhang*, Jian Zhang*, “Synthetic strategies, diverse structures and tuneable properties of polyoxo-titanium clusters”, Chem. Soc. Rev. 2018, 47, 404-421.
[18] Yan-Ping He#, Lv-Bing Yuan#, Jin-Shuai Song, Guang-Hui Chen, Qipu Lin, Chunsen Li, Lei Zhang*, Jian Zhang*, “Optical Resolution of the Water-soluble Ti4(embonate)6 Cages for Enantioselective Recognition of Chiral Drugs”, Chem. Mater. 2018, 30, 7769-7775.
[19] Bang-Chang Zhu, Wei-Hui Fang, Junhui Wang, Yonghua Du, Tianhua Zhou, Kaifeng Wu*, Lei Zhang*, Jian Zhang*, “Host-Guest and Photophysical Behaviours of Ti8L12 Cube with Encapsulated [Ti(H2O)6] Species”, Chem. Eur. J. 2018, 24, 14358-14362.
[20] Lv-Bing Yuan, Yan-Ping He, Lei Zhang*, Jian Zhang, “Embonic Acid Functionalized Nb-Complexes with Selective Dye Sorption Property”, Inorg. Chem. 2018, 57, 4226-4229.
[21] Mei-Yan Gao, Xi Fan, Lei Zhang*, Jian Zhang, “Dicarboxylate Ligands Oriented Assembly of {Ti3(μ3-O)} Units: from Dimer to Coordination Triangles and Rectangles”, Inorg. Chem. 2018, 57, 5642-5647.
[22] Shuai Chen, Wei-Hui Fang*, Lei Zhang*, Jian Zhang, “Synthesis, Structures and Photocurrent Responses of Polyoxo-Titanium Clusters with Oxime Ligands: From Ti4 to Ti18”, Inorg. Chem. 2018, 57, 8850-8856.
[23] Xi Fan, Nagaraju Narayanam, Meiyan Gao, Lei Zhang*, Jian Zhang, “Ligands dependent assembly of trinuclear titanium-oxo units into coordination tetrahedron and capsule”, Dalton Trans. 2018, 47, 663-665.
[24] Nagaraju Narayanam, Kalpana Chintakrind, Wei-Hui Fang, Lei Zhang*, Jian Zhang, “Atomically Precise Zr-Oxo and Zr/Ti-Oxo Nanoclusters by Deep Eutectic-Solvothermal Synthesis”, Acta Phys. -Chim. Sin. 2018, 34, 781-785. [Special Issue “Toward Atomically Precise Nanoclusters and Nanoparticles”]
[25] Bang-Chang Zhu, Wei-Hui Fang*, Perumal Emayavaramban, Lei Zhang*, Jian Zhang, “Structures and photophysical performances of (fluoro)salicylate stabilized polyoxo-titanium clusters”, CrystEngComm. 2018, 20, 5964-5968. [CrystEngComm New Talent 2018 themed issue]
[26] 高美艳, 张磊*, 张健*, “晶态钛氧簇合物的制备与性能研究进展”, 科学通报, 2018, 63, 2731-2744.
[27] Mei-Yan Gao, Xiao-Xue Liu, Wei-Hui Fang, Lei Zhang*, Jian Zhang, “Synthesis and structural characterization of a dumbbell-like phenylphosphonate-stabilized Ti7–oxide cluster”, Acta Cryst. 2018, C74, 1248-1251. [Polyoxometalates special issue]
[28] Yan-Ping He, Lv-Bing Yuan, Guang-Hui Chen, Qi-Pu Lin, Fei Wang, Lei Zhang*, Jian Zhang*, “Water Soluble and Ultra-Stable Ti4L6 Tetrahedron with Coordination Assembly Function”, J. Am. Chem. Soc. 2017, 139, 16845-16851.
[29] Zhiqiang Jiang, Jinxiu Liu, Meiyan Gao, Xi Fan, Lei Zhang*, Jian Zhang*, “Assembling Polyoxo-Titanium Clusters and CdS Nanoparticles to Porous Matrix for Efficient and Tunable H2 Evolution Activities with Visible Light”, Adv. Mater. 2017, 29, 1603369.
[30] Wei-Hui Fang, Jian-Fang Wang, Lei Zhang*, Jian Zhang*, “Titanium-Oxo Cluster Based Precise Assembly for Multi-Dimensional Materials”, Chem. Mater. 2017, 29, 2681-2684.
[31] Wei-Hui Fang, Lei Zhang*, Jian Zhang*, “Assembly of Titanium-Oxo Cations with Copper-Halide Anions to Supersalt-Type Cluster-Based Materials”, Chem. Commun. 2017, 53, 3949-3951.
[32] Nagaraju Narayanam, Wei-Hui Fang, Kalpana Chintakrind, Lei Zhang*, Jian Zhang*, “Deep Eutectic-Solvothermal Synthesis of Titanium-Oxo Clusters Protected by p-Conjugate Chromophores”, Chem. Commun. 2017, 53, 8078-8080.
[33] Jian-Fang Wang, Wei-Hui Fang, Dong-Sheng Li, Lei Zhang*, Jian Zhang, “Cocrystal of {Ti4} and {Ti6} Clusters with Enhanced Photochemical Properties”, Inorg. Chem. 2017, 56, 2367-2370.
[34] Mei-Yan Gao, Wei-Hui Fang*, Tian Wen, Lei Zhang*, Jian Zhang, “Connecting Titanium-Oxo Clusters by Nitrogen Heterocyclic Ligands to Produce Multiple Cluster-Series with Photocatalytic H2 Evolution Activities”, Cryst. Growth Des. 2017, 17, 3592-3595.
[35] Wei-Hui Fang, Lei Zhang*, Jian Zhang, “Synthetic Investigation, Structural Analysis and Photocatalytic Study of a Carboxylate-Phosphonate Bridged Ti18-Oxo Cluster”, Dalton Trans. 2017, 46, 803-807.
[36] Mei-Yan Gao, Shumei Chen, Lan-Xia Hu, Lei Zhang*, Jian Zhang*, “Synthesis and photocatalytic H2 evolution properties of four Titanium-oxo-Clusters based on cyclohex-3-ene-1-carboxylate ligand”, Dalton Trans. 2017, 46, 10630-10634.
[37] Qing-Rong Ding, Jin-Xiu Liu, Nagaraju Narayanam, Lei Zhang*, Jian Zhang, “Construction of molecular rectangles with titanium–oxo clusters and rigid aromatic carboxylate ligands”, Dalton Trans. 2017, 46, 16000-16003.
[38] Zongxiong Xu, Hao Fu, Tian Wen, Lei Zhang*, Jian Zhang*, “Improving the photocatalytic H2 evolution activities of TiO2 by modulating the stabilizing ligands of the nanoscale Ti8O8-cluster precursors”, Int. J. Hydrogen Energ. 2017, 42, 24737-24743.
[39] Wei-Hui Fang, Lei Zhang*, Jian Zhang*, “A 3.6 nm Ti52-Oxo Nanocluster with Precise Atomic Structure”, J. Am. Chem. Soc. 2016, 138, 7480-7483.
[40] Mei-Yan Gao, Fei Wang, Zhi-Gang Gu, De-Xiang Zhang, Lei Zhang*, Jian Zhang*, “Fullerene-Like Polyoxotitanium Cage with High Solution Stability”, J. Am. Chem. Soc. 2016, 138, 2556-2559.
[41] Jin-Xiu Liu, Mei-Yan Gao, Wei-Hui Fang, Lei Zhang*, Jian Zhang*, “Bandgap Engineering of Titanium-Oxo Clusters: Labile Surface Sites Used for Ligand Substitution and Metal Incorporation”, Angew. Chem. Int. Ed. 2016, 55, 5160-5165.
[42] Zhi-Gang Gu, Hao Fu, Tobias Neumann, Zong-Xiong Xu, Wen-Qiang Fu, Wolfgang Wenzel, Lei Zhang*, Jian Zhang*, Christof Wöll*, “Chiral Porous Metacrystals: Employing Liquid-phase Epitaxy to Assemble Enantiopure Metal-Organic Nanoclusters into Molecular Framework Pores”, ACS Nano 2016,10, 977-983.
[43] Nagaraju Narayanam, Kalpana Chintakrinda, Wei-Hui Fang, Yao Kang, Lei Zhang*, Jian Zhang, “Azole Functionalized Polyoxo-Titanium Clusters with Sunlight-Driven Dye Degradation Applications: Synthesis, Structure, and Photocatalytic Studies”, Inorg. Chem. 2016, 55, 10294-10301.
[44] Jin-Xiu Liu, Xian-Chong Zeng, Lei Zhang*, Jian Zhang, “A New Cadmium-Doped Titanium-Oxo Cluster with Stable Photocatalytic H2 Evolution Property”, Dalton Trans. 2016, 45, 4501-4503.
[45] Lei Zhang, Rodolphe Clérac, Pierre Heijboer, Wolfgang Schmitt*, “Influencing the Symmetry of High-Nuclearity and High-Spin Manganese Oxo Clusters: Supramolecular Approaches to Manganese-Based Keplerates and Chiral Solids”, Angew. Chem. Int. Ed. 2012, 51, 3007-3011.
[46] Lei Zhang, Wolfgang Schmitt*, “From Platonic Templates to Archimedean Solids: Successive Construction of Nanoscopic {V16As8}, {V16As10}, {V20As8}, and {V24As8} Polyoxovanadate Cages”, J. Am. Chem. Soc. 2011, 133, 11240-11248.