基本信息
龚昱  男  博导  中国科学院上海应用物理研究所
电子邮件: gongyu@sinap.ac.cn
通信地址: 上海市嘉定区嘉罗公路2019号
邮政编码:

研究领域

锕系和镧系化合物在熔盐和溶液中的配位结构及其与分离效果和熔盐堆运行间的关系、熔盐体系中锕系和镧系元素的综合利用,为阐明钍铀循环过程中关键元素在堆运行、后处理和再利用过程中的化学行为和规律提供科学基础,具体包括:

1. 钍铀循环关键元素的新型分离方法与机制研究
2. 新型锕系和镧系化合物的合成、结构与性质
3. 基于光谱和质谱方法的锕系和镧系配位化学研究
4. 镧系和锕系元素化合物的综合利用研究

招生信息

   
招生专业
070301-无机化学
招生方向
镧系和锕系元素化学
乏燃料后处理
基于谱学的配位化学

教育背景

2005-09--2010-07   复旦大学化学系   博士
2001-09--2005-07   复旦大学化学系   学士
学历

研究生

学位

博士

工作经历

   
工作简历
2015-02~现在, 中国科学院上海应用物理研究所, 研究员
2014-09~2014-11,美国弗吉尼亚大学(University of Virginia), 博士后
2012-02~2014-08,美国劳伦斯伯克利国家实验室(Lawrence Berkeley National Laboratory), 博士后
2010-08~2012-01,美国弗吉尼亚大学(University of Virginia), 博士后

教授课程

核能科学与技术概论
锕系化学前沿

专利与奖励

   
奖励信息
(1) 瞬态新奇分子的光谱、成键和反应研究, 二等奖, 国家级, 2018
(2) 上海市研究生优秀成果(学位论文), 市地级, 2012
(3) 吴征铠奖学金, 研究所(学校), 2010
(4) 张存浩优秀研究生奖, 国家级, 2007
专利成果
[1] 季男, 黄卫, 龚昱, 蒋锋, 彭浩, 佘长锋, 朱铁建. 一种氯化物熔盐体系中将稀土氧化物还原为稀土金属单质的方法. CN: CN112391653A, 2021-02-23.

[2] 周金豪, 陈梓, 孙波, 窦强, 黄卫, 龚昱, 李晴暖. 一种固态盐加热熔融装置及方法. CN: CN108295776B, 2020-03-27.

出版信息

已在Chem. Rev, J. Am. Chem. Soc., Angew. Chem. Int. Ed., Inorg. Chem.和J. Phys. Chem. 等期刊上发表第一和通讯作者论文80余篇。

发表论文
(1) Influence of Fluoride Ions on the Speciation and Electrochemical Behavior of Th(IV) in Molten LiCl-KCl with a Copper Electrode, JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2021, 第 3 作者
(2) HMNTA Complexes of Tetravalent Metal Ions: On the Roles of Carbonyl Oxygen and Amine Nitrogen in the Stabilization of Gas-Phase M(HMNTA)(2)(4+) Complexes, JOURNAL OF THE AMERICAN SOCIETY FOR MASS SPECTROMETRY, 2021, 第 3 作者
(3) Mass spectrometric and theoretical study on the formation of uranyl hydride from uranyl carboxylate, PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2021, 第 3 作者
(4) Molten salt synthesis of samarium borides with controllable stoichiometry and morphology, Journal of Alloys and Compounds, 2021, 
(5) Photoluminescence of LaI3 switched on and off by association and dissociation of non-luminescent tetrahydrofuran, DALTON TRANSACTIONS, 2021, 第 3 作者
(6) Oxo-sulfido molybdenum and tungsten fluorides with M-O and M-S multiple bonds, PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2021, 第 4 作者
(7) Vanadium, niobium and tantalum complexes with terminal sulfur radical ligands, DALTON TRANSACTIONS, 2021, 第 4 作者
(8) On the Structures of Thorium Fluoride and Oxyfluoride Anions in Molten FLiBe and FLiNaK, JOURNAL OF PHYSICAL CHEMISTRY B, 2021, 第 3 作者
(9) End-On Cyanogen Complexes of Iridium, Palladium, and Platinum, INORGANIC CHEMISTRY, 2020, 第 4 作者
(10) Complexation of Ln(3+) with Pyridine-2,6-dicarboxamide: Formation of the 1:2 Complexes in Solution and Gas Phase, INORGANIC CHEMISTRY, 2020, 第 3 作者
(11) Sulfur Dioxide Complexes of Main-Group Elements: from SO20 to SO2- and SO22- upon Coordination to Aluminum and Silicon Difluorides, INORGANIC CHEMISTRY, 2020, 第 3 作者
(12) Electrochemical separation of uranium from lanthanide (La, Eu, Gd) fluorides in molten LiCl-KCl, SEPARATION AND PURIFICATION TECHNOLOGY, 2020, 第 3 作者
(13) Raman Spectroscopic and Theoretical Study of Scandium Fluoride and Oxyfluoride Anions in Molten FLiNaK, JOURNAL OF PHYSICAL CHEMISTRY B, 2020, 第 4 作者
(14) Sulfur-substituted uranyl stabilized by fluoride ligands: matrix preparation of U(O)(S)F(2)viaoxidation of U(0) by SOF2, CHEMICAL COMMUNICATIONS, 2020, 第 3 作者
(15) Infrared Spectroscopic and Theoretical Studies of the 3d Transition Metal Oxyfluoride Molecules, INORGANIC CHEMISTRY, 2019, 第 6 作者
(16) Efficient Removal of Azo-Dyes in Aqueous Solution by CeB6 Nanocrystals, ACS APPLIED NANO MATERIALS, 2019, 第 3 作者
(17) Synthesis of a dinuclear europium(III) complex through deprotonation and oxygen-atom transfer of trimethylamine N-oxide, DALTON TRANSACTIONS, 2019, 第 3 作者
(18) Side-On OMoF2(eta(2)-SO) and OWF2(eta(2)-SO) Complexes Featuring Peroxo-Like Sulfur Monoxide Ligand, INORGANIC CHEMISTRY, 2019, 第 3 作者
(19) Formation of Cerium and Neodymium Isocyanides in the Reactions of Cyanogen with Ce and Nd Atoms in Argon Matrices, JOURNAL OF PHYSICAL CHEMISTRY A, 2019, 第 4 作者
(20) Side-On Sulfur Monoxide Complexes of Tantalum, Niobium, and Vanadium Oxyfluorides, INORGANIC CHEMISTRY, 2019, 第 3 作者
(21) End-On Oxygen-Bound Sulfur Monoxide Complex of Titanium Oxyfluoride, INORGANIC CHEMISTRY, 2019, 第 3 作者
(22) Tetrapositive Hafnium-Diamide Complexes in the Gas Phase: Formation, Structure and Reaction, JOURNAL OF THE AMERICAN SOCIETY FOR MASS SPECTROMETRY, 2019, 第 2 作者
(23) Electrochemical and Raman Spectroscopic Investigations on the Speciation and Behavior of Chromium Ions in Fluoride Doped Molten LiCl-KCl, JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2019, 第 5 作者
(24) Coordination Structures of the Uranyl(VI)-Diamide Complexes: A Combined Mass Spectrometric, EXAFS Spectroscopic, and Theoretical Study, INORGANIC CHEMISTRY, 2019, 第 3 作者
(25) Bidentate SO2 Complexes of Zirconium and Hafnium Difluorides with Highly Activated S-O Bonds, JOURNAL OF PHYSICAL CHEMISTRY A, 2019, 第 3 作者
(26) Bidentate Sulfur Dioxide Complexes of Scandium, Yttrium, and Lanthanum Difluorides, INORGANIC CHEMISTRY, 2019, 第 3 作者
(27) Formation and Characterization of Zr4+ Stabilized by Neutral Tridentate Ligands in the Gas Phase, JOURNAL OF THE AMERICAN SOCIETY FOR MASS SPECTROMETRY, 2018, 第 3 作者
(28) Electrochemical deposition of neodymium in LiF-CaF2 from Nd2O3 assisted by AlF3, ELECTROCHIMICA ACTA, 2018, 第 7 作者
(29) Reactions of Laser-Ablated Aluminum Atoms with Cyanogen: Matrix Infrared Spectra and Electronic Structure Calculations for Aluminum Isocyanides Al(NC)(1,2,3) and Their Novel Dimers, JOURNAL OF PHYSICAL CHEMISTRY A, 2018, 第 3 作者
(30) Infrared Spectroscopic and Theoretical Studies of Group 3 Metal Isocyanide Molecules, JOURNAL OF PHYSICAL CHEMISTRY A, 2018, 第 4 作者
(31) Infrared Spectra of the SO2F2- Anion in Solid Argon and Neon, JOURNAL OF PHYSICAL CHEMISTRY A, 2018, 第 3 作者
(32) Infrared Spectroscopic and Theoretical Studies of Group 3 Metal Isocyanide Molecules, JOURNAL OF PHYSICAL CHEMISTRY A, 2018, 第 4 作者
(33) Formation and Fragmentation Chemistry of Tripositive Ln(TMGA)(3)(3+) Complexes in the Gas Phase, JOURNAL OF THE AMERICAN SOCIETY FOR MASS SPECTROMETRY, 2017, 第 3 作者
(34) Gas phase chemistry of the Ln(III)-TMGA/TMTGA complexes, ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2017, 第 3 作者
(35) Coordination Structure and Fragmentation Chemistry of the Tripositive Lanthanide-Thio-Diglycolamide Complexes, JOURNAL OF PHYSICAL CHEMISTRY A, 2017, 第 3 作者
(36) Electrochemical behavior and electrowinning of uranium(IV) from FLiNaK molten salt, JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY, 2017, 第 8 作者
(37) Matrix Infrared Spectra of Manganese and Iron Isocyanide Complexes, JOURNAL OF PHYSICAL CHEMISTRY A, 2017, 第 4 作者
(38) Infrared Spectroscopic and Theoretical Studies on the OMF2 and OMF (M = Cr, Mo, W) Molecules in Solid Argon, JOURNAL OF PHYSICAL CHEMISTRY A, 2017, 第 3 作者
(39) Recent progress on the development of pyroprocessing techniques for TMSR in SINAP, ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2017, 第 1 作者
(40) Formation and Characterization of Homoleptic Thorium Isocyanide Complexes, INORGANIC CHEMISTRY, 2017, 第 3 作者
(41) Gas Phase Uranyl Activation: Formation of a Uranium Nitrosyl Complex from Uranyl Azide, JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2015, 第 1 作者
(42) Reactions of laser-ablated U atoms with (CN)(2): infrared spectra and electronic structure calculations of UNC, U(NC)(2), and U(NC)(4) in solid argon, CHEMICAL COMMUNICATIONS, 2015, 第 1 作者
(43) Electrospray production and collisional dissociation of lanthanide/methylsulfonyl anion complexes: Sulfur dioxide anion as a ligand, INTERNATIONAL JOURNAL OF MASS SPECTROMETRY, 2015, 第 1 作者
(44) Reactions of Laser-Ablated U Atoms with HCN: Infrared Spectra in Solid Argon and Quantum Chemical Calculations for HUNC, EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2015, 第 1 作者
(45) Crown Ether Complexes of Uranyl, Neptunyl, and Plutonyl: Hydration Differentiates Inclusion versus Outer Coordination, INORGANIC CHEMISTRY, 2014, 第 1 作者
(46) Activation of Gas-Phase Uranyl: From an Oxo to a Nitrido Complex, JOURNAL OF PHYSICAL CHEMISTRY A, 2014, 第 1 作者
(47) Tetrapositive Plutonium, Neptunium, Uranium, and Thorium Coordination Complexes: Chemistry Revealed by Electron Transfer and Collision Induced Dissociation, JOURNAL OF PHYSICAL CHEMISTRY A, 2014, 第 1 作者
(48) Dissociation of Diglycolamide Complexes of Ln(3+) (Ln = La-Lu) and An(3+) (An = Pu, Am, Cm): Redox Chemistry of 4f and 5f Elements in the Gas Phase Parallels Solution Behavior, INORGANIC CHEMISTRY, 2014, 第 1 作者
(49) Experimental and Theoretical Studies on the Fragmentation of Gas-Phase Uranyl-, Neptunyl-, and Plutonyl-Diglycolamide Complexes, JOURNAL OF PHYSICAL CHEMISTRY A, 2013, 第 1 作者
(50) A Tetrapositive Metal Ion in the Gas Phase: Thorium(IV) Coordinated by Neutral Tridentate Ligands, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2013, 第 1 作者
(51) Formation and Characterization of the Uranyl-SO2 Complex, UO2(CH3SO2)(SO2)(-), JOURNAL OF PHYSICAL CHEMISTRY A, 2013, 第 1 作者
(52) Matrix Infrared Spectroscopic and Theoretical of the Difluoroamino Metal Fluoride Molecules: F2NMF (M = Cu, Ag, Au), INORGANIC CHEMISTRY, 2012, 第 1 作者
(53) Methane to Methanol Conversion Induced by Thorium Oxide through the CH3Th(O)H Intermediate in Solid Argon, INORGANIC CHEMISTRY, 2012, 第 1 作者
(54) Spectroscopic Observation of a Group 12 Oxyfluoride: A Matrix-Isolation and Quantum-Chemical Investigation of Mercury Oxyfluorides, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2012, 
(55) Reactions of Group 3 Metals with OF2: Infrared Spectroscopic and Theoretical Investigations of the Group 3 Oxydifluoride OMF2 and Oxyfluoride OMF Molecules, JOURNAL OF PHYSICAL CHEMISTRY A, 2012, 第 1 作者
(56) Infrared Spectra of Rh12C and Rh13C in Solid Neon and Solid Argon, Chemical Physics Letters, 2012, 
(57) Infrared spectroscopic and theoretical studies of the OTiF2, OZrF2 and OHfF2 molecules with terminal oxo ligands, DALTON TRANSACTIONS, 2012, 第 1 作者
(58) Formation of Metal Oxyfluorides from Specific Metal Reactions with Oxygen Difluoride: Infrared Spectroscopic and Theoretical Investigations of the OScF2 Radical and OScF with Terminal Single and Triple Sc?O Bonds, CHEMISTRY-A EUROPEAN JOURNAL, 2012, 第 1 作者
(59) Infrared Spectroscopic and Theoretical Investigations of the OUF2 and OThF2 Molecules with Triple Oxo Bond Character, INORGANIC CHEMISTRY, 2012, 第 1 作者
(60) Reactions of Late Lanthanide Metal Atoms and Methanol in Solid Argon: A Matrix Isolation Infrared Spectroscopic and Theoretical Study, JOURNAL OF PHYSICAL CHEMISTRY A, 2011, 第 1 作者
(61) Matrix infrared spectroscopic and density functional theoretical investigations on thorium and uranium atom reactions with dimethyl ether, DALTON TRANSACTIONS, 2011, 第 1 作者
(62) Is rhodium tetroxide in the formal oxidation state VIII stable? a quantum chemical and matrix isolation investigation of rhodium oxides, THEORETICAL CHEMISTRY ACCOUNTS, 2011, 第 1 作者
(63) Infrared Spectrum of the CH3OCH2 Radical in Solid Argon, JOURNAL OF PHYSICAL CHEMISTRY A, 2011, 第 1 作者
(64) Matrix Infrared Spectra and Theoretical Studies of Thorium Oxide Species: ThOx, and Th2Oy, JOURNAL OF PHYSICAL CHEMISTRY A, 2011, 第 2 作者
(65) Matrix Infrared Spectroscopic and Theoretical Investigations of Uranium Atom and Methanol Reaction Products, INORGANIC CHEMISTRY, 2011, 第 1 作者
(66) Matrix Infrared Spectroscopic and Theoretical Studies on the Reactions of Scandium, Yttrium, and Lanthanide Metal Atoms with Dimethyl Ether, JOURNAL OF PHYSICAL CHEMISTRY A, 2011, 
(67) Infrared Spectra and Quantum Chemical Calculations of the Bridge-Bonded HC(F)LnF(2) (Ln = La-Lu) Complexes, ORGANOMETALLICS, 2011, 第 1 作者
(68) Water Adsorption on Platinum Dioxide and Dioxygen Complex: Matrix Isolation Infrared Spectroscopic and Theoretical Study of Three PtO2-H2O Complexes, CHEMPHYSCHEM, 2010, 第 1 作者
(69) Infrared spectra of zinc and cadmium dioxide anions in solid neon, CHEMICAL PHYSICS LETTERS, 2010, 第 1 作者
(70) Infrared Spectra of Transition-Metal Dioxide Anions: MO2- (M = Rh, Ir, Pt, Au) in Solid Argon, JOURNAL OF PHYSICAL CHEMISTRY A, 2009, 第 1 作者
(71) Formation and characterization of the CuO5, CuO4 and CuO4- complexes in solid argon, PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2009, 第 1 作者
(72) Spectroscopic and Theoretical Studies of Transition Metal Oxides and Dioxygen Complexes, CHEMICAL REVIEWS, 2009, 第 1 作者
(73) Spectroscopic Characterization of a Copper(III) Trisuperoxide Complex Bearing Both Side-On and End-On Ligands, JOURNAL OF PHYSICAL CHEMISTRY A, 2009, 第 1 作者
(74) Formation and Characterization of the Iridium Tetroxide Molecule with Iridium in the Oxidation State plus VIII, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 第 1 作者
(75) Infrared Spectra of Oxygen-Rich Yttrium and Lanthanum Dioxygen/Ozonide Complexes in Solid Argon, JOURNAL OF PHYSICAL CHEMISTRY A, 2009, 第 1 作者
(76) Formation and Characterization of ZrO3 and HfO3 Molecules in Solid Argon, Formation and Characterization of ZrO3 and HfO3 Molecules in Solid Argon, CHINESE JOURNAL OF CHEMICAL PHYSICS, 2009, 第 1 作者
(77) Is the FeO2- Anion Bent or Linear?, JOURNAL OF PHYSICAL CHEMISTRY A, 2008, 第 2 作者
(78) Matrix infrared spectra and density functional calculations of TiO3 and TiO5 in solid argon, JOURNAL OF PHYSICAL CHEMISTRY A, 2008, 第 1 作者
(79) Matrix isolation infrared spectroscopic and theoretical study of the hydrolysis of boron dioxide in solid argon, JOURNAL OF PHYSICAL CHEMISTRY A, 2008, 第 1 作者
(80) Formation and Characterization of Two FeO3 Isomers in Solid Argon, JOURNAL OF PHYSICAL CHEMISTRY A, 2008, 第 1 作者
(81) Formation and characterization of mononuclear and dinuclear manganese oxide-dioxygen complexes in solid argon, JOURNAL OF PHYSICAL CHEMISTRY A, 2008, 第 1 作者
(82) Formation and characterization of the tetranuclear scandium nitride: Sc4N4, JOURNAL OF PHYSICAL CHEMISTRY A, 2007, 第 1 作者
(83) Formation and characterization of the photochemically interconvertible side-on and end-on bonded dioxygen-iron dioxide complexes in solid argon, JOURNAL OF PHYSICAL CHEMISTRY A, 2007, 
(84) Formation and characterization of the oxygen-rich hafnium Dioxygen complexes: OHf(eta(2)-O-2)(eta(2)-O-3), Hf(eta(2)-O-2)(3), and Hf(eta(2)-O-2)(4), JOURNAL OF PHYSICAL CHEMISTRY A, 2007, 第 1 作者
(85) Matrix isolation infrared spectroscopic and theoretical study of group IV metal oxide clusters: M2O2 and M2O4, JOURNAL OF PHYSICAL CHEMISTRY A, 2007, 第 1 作者
(86) Interconvertible side-on- and end-on-bonded oxo-superoxo titanium ozonide complexes, JOURNAL OF PHYSICAL CHEMISTRY A, 2007, 
(87) Formation and characterization of the oxygen-rich scandium oxide/dioxygen complexes ScOn (n=4, 6, 8) in solid argon, JOURNAL OF PHYSICAL CHEMISTRY A, 2007, 第 1 作者
(88) Remarkable dinitrogen activation and cleavage by the Gd dimer: From dinitrogen complexes to ring and cage nitrides, ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 

科研活动

   
科研项目
( 1 ) 青年人才项目, 主持, 国家级, 2016-10--2020-07
( 2 ) 燃料盐中锕系元素化合物的结构,性质与反应, 主持, 市地级, 2015-03--2020-12
( 3 ) 锕系金属氟化物红外光谱研究, 主持, 国家级, 2016-09--2018-08
( 4 ) 钍镤铀-中性二酰胺配合物的气相结构与反应研究, 主持, 国家级, 2018-01--2021-12
( 5 ) 锕系和裂变产物氟化物与含氧分子反应的红外光谱和理论计算研究, 主持, 省级, 2020-07--2023-06
( 6 ) 钍基燃料盐的物化性质和转化规律研究, 主持, 省级, 2021-12--2026-11
参与会议
(1)Mass spectrometric studies on the diamide complexes of lanthanide and actinide ions   2021-12-20
(2)钍铀循环化学研究进展   第五届全国核化学与放射化学青年学术研讨会   2019-07-18
(3)锕系配位化合物的质谱和红外光谱研究   第三届锕系物理与化学学术交流会   2018-07-20
(4)金属氟氧化物的红外光谱研究   第4次环境放射化学战略研讨会   2017-10-26
(5)Recent progress on the development of pyroprocessing techniques for TMSR in SINAP   2017-04-02
(6)Recent progress on the development of pyroprocessing techniques for TMSR in SINAP   2016-07-19
(7)质谱和红外光谱方法在锕系化学   第三届全国核化学与放射化学青年学术研讨会   龚昱   2015-11-29
(8)质谱方法在锕系化学中的应用   第六届全国环境放射化学学术研讨会   龚昱   2015-09-02
(9)质谱方法在锕系化学中的应用   第十四届全国应用化学年会   龚昱   2015-07-23

指导学生

已指导学生

杨甜宏  硕士研究生  070301-无机化学  

陈秀婷  博士研究生  070301-无机化学  

魏睿  博士研究生  070301-无机化学  

王晨阳  博士研究生  070301-无机化学  

现指导学生

李杨娟  博士研究生  070301-无机化学  

刘西艳  博士研究生  070301-无机化学  

胡靖雯  硕士研究生  070301-无机化学  

熊志欣  博士研究生  070301-无机化学  

冷德基  硕士研究生  070301-无机化学  

曹满鑫  硕士研究生  070301-无机化学  

何清秀  硕士研究生  070301-无机化学