闫隆 研究员   博士生导师

​电子邮件:yanlong@sinap.ac.cn

联系电话:021-39194773
手机号码:13917613546
通信地址:上海市嘉定区嘉罗公路2019号
邮政编码:201800

研究领域

主要从事纳米材料结构和性能的调控、新型结构功能材料的改性和材料的服役行为和评价研究。近年来,逐渐聚焦在碳基纳米材料和基于熔盐技术的材料改性研究。目前研究方向包括:

1)纳米材料的结构和性能调控研究

2)新型结构和功能材料的改性研究

3)材料的服役行为和评价研究


主要科研成果: 

1.      纳米材料结构、性能调控研究

在碳纳米材料调控下的盐溶液结构及应用研究工作,发现了盐在碳纳米管内自发超高富集现象,管内盐浓度比管外稀溶液盐浓度高一百到一万倍,这打破了长期认为是毛细作用使盐溶液进入碳纳米管的观念。作为并列通讯作者发表在Physical Review Letters 上(Physical Review Letter,121 (2018) 226102)。编审指出该工作是“一项重要的碳纳米管对离子进行富集的实验研究工作,会在实验和理论方面推动未来的研究工作”。

在常温常压条件下,利用盐溶液和石墨烯的独特相互作用,在石墨烯基底上制备出反常化学计量比CaCl二维晶体,通过实验证明了Ca离子的+1价以及晶体的各种超常规性质和应用,包括室温铁磁性、金属性以及由此产生的石墨烯–CaCl异质结、压电性。该工作发表在National Science Review上

发展出一种独特离子束调控碳纳米管结构和性能技术,使碳纳米管网络的连接、导电和场发射性能大幅度提高。相关国际期刊的综述文章(Journal of Applied Physics, 107 (2010) 71301; Nanoscale, 3 (2011) 4503)把碳纳米材料结构和性能的离子束调控方面的研究作为为未来纳米器件制备指出一个新方向

在金属纳米线的制备和磁各向异性的调控的研究工作被收录在美国出版的磁性和先进磁性材料手册中(Handbook of Magnetism and Advanced Magnetic Materials. 2007 John Wiley & Sons, Ltd. ISBN: 978-0-470-02217-7)。

 

代表性论文: National Science Review, 2021 (in press)         (IF 16.7)

Physical Review Letters, 2018, 121, 226102        (IF 9.2)

Nature Chemistry, 2018, 10,776  (主要参加人)    (IF 23.2)

Carbon, 2011, 49 (6), 2141                      (IF 7.5)

Carbon, 2008, 46 (2), 376                       (IF 7.5)

Applied Physics Letters, 2005, 86 (10), 102503      (IF 3.5)

 

2.      新型结构和功能材料的改性研究

研究高性能陶瓷、半导体材料和非晶合金等材料在非平衡态的微结构演化机理,并分析评价其在极端环境下的服役行为。开发了一种利用离子束辐照技术在SiC等超硬材料表面进行大面积三维微纳米加工的方法,开拓了纳米三维成型的新方法、新领域,具有良好的应用前景,相关工作申请了发明专利(CN201710725202.6 CN201810354253.7),并发表在Carbon上(Carbon, 2019, 148, 387)。在MAX相材料方面,发现了一种在高辐照剂量下,可以使不同种类原子位置互换,从而保持晶格结构完好的MAX相材料——Cr2AlCActa Materialia, 2016,110, 1)。

代表性论文:Carbon, 2019, 148, 387                          (IF 7.5)

Acta Materialia, 2016, 110, 1                      (IF 7.3)

Journal of Applied Physics, 2015,118, 35308         (IF 2.3)

 

3.      材料的服役行为和评价研究

研究反应堆结构材料的辐照效应,评价核材料的抗辐照性能。与中国核动力研究设计院合作,首次在中国成功实现镍基合金650度高温反应堆中子辐照试验,被中国核工业集团评价为“我国材料高温辐照考验方面的重大突破”。

研究熔盐环境下的在SiC材料和高温合金表面的结构改变。在高温熔盐环境中,发现使Si元素能从辐照的SiC表面流失(Corrosion Science, 2017,125,194)。该工作就被Journal of Nuclear Materials综述文章认为该工作是评价SiC材料服役行为的重要依据。

研究高温熔盐中金属的溶解行为。首次证实了金属能以零价形式溶解到熔盐中,并以原子团簇的形式存在,推翻了以前对金属溶解在熔盐中必须有电荷转移的观念。

代表性论文: Corrosion Science, 2019, 153, 47                   (IF 6.4)

Journal of Alloys and Compounds, 2018, 746, 153     (IF 4.6)

Corrosion Science, 2017, 125, 194                  (IF 6.4)

Journal of Nuclear Materials, 2017, 489, 180          (IF 2.5)




招生方向

1.  082703核技术及应用 , 04先进核科学技术及应用

2. 082701核能科学与工程, 02反应堆材料与工程

3.  085800能源动力(专业学位),01热能储存、传输和转换技术

教育背景

   
学历

1992年9月--1996年7月 河南大学物物理系  理学学士
1996年9月--1999年7月 吉林大学超硬材料国家重点实验室 理学硕士
1999年9月--2002年7月 中国科学院物理研究所 理学博士
 

学位
-- 理学博士学位
出国学习工作

2016/05—2016/08    美国麻省理工学院                                     高级访问学者

2004/11—2006/01    韩国延世大学                                           Research fellow

2002/09—2004/09    德国马克思-普朗克微结构物理研究所          博士后


工作经历

2013/01至今             中国科学院上海应用物理研究所        研究员                                                

2006/02—2012/12    中国科学院上海应用物理研究所        副研究员


教授课程

反应堆材料-陶瓷材料

专利与奖励

   
专利成果
[1] 王学良, 闫隆, 方海平, 应哲冕. 一种磁性石墨烯复合纳米线及其制备方法和应用. CN: CN113830754A, 2021-12-24.

[2] 闫隆, 汪颖, 周玉莹, 张泽军. 一种无机盐纳米薄膜的制备方法以及由此得到的无机盐纳米薄膜. CN: CN111962070A, 2020-11-20.

[3] 方海平, 闫隆, 石国升, 梁珊珊, 王学良, 方钢. 一种基于碳基材料的离子收集方法. CN: CN108928812B, 2020-10-20.

[4] 闫隆, 汪颖, 周玉莹, 胡钧, 阴慧琴. 一种盐纳米颗粒的制备方法. CN: CN109231241A, 2019-01-18.

[5] 闫隆, 王学良. 一种尺寸可控的纳米氧化铈颗粒的制备方法. CN: CN109179477A, 2019-01-11.

[6] 周玉莹, 汪颖, 闫隆, 胡钧. 一种具有周期性的表面电势梯度的材料的制备方法. CN: CN108766877A, 2018-11-06.

[7] 汪颖, 周玉莹, 闫隆, 胡钧. 一种三维微纳米加工方法. CN: CN107500245A, 2017-12-22.

[8] 周广颖, 闫隆. 一种提高碳纳米管网络导电性的方法. CN: CN101830456A, 2010-09-15.

出版信息

   
发表论文
[1] Xiangmin Xie, Xian Tang, Long Yan, Guodong Cheng, Jianjian Li, Jingjing Liao, Yang Zhang. Morphological and microstructural evolutions of chemical vapor reaction-fabricated SiC under argon ion irradiation. NUCLEAR INST. AND METHODS IN PHYSICS RESEARCH, B. 2023, 541: 151-160, http://dx.doi.org/10.1016/j.nimb.2023.05.066.
[2] Ying, Zhemian, Zhang, Zejun, Zhou, Yuying, Wang, Ying, Zhang, Wei, Huang, Qing, Shen, Yue, Fang, Haiping, Hou, Huiqi, Yan, Long. Unexpected hygroscopic behaviors of individual sub-50 nm NaNO3 nanoparticles observed by in situ atomic force microscopy. SCIENCE OF THE TOTAL ENVIRONMENT[J]. 2022, 852: http://dx.doi.org/10.1016/j.scitotenv.2022.158441.
[3] Qiang, Yu, Wang, Xueliang, Ying, Zhemian, Zhou, Yuying, Liu, Renduo, Gao, Siyan, Yan, Long. High-Efficiency Ion Enrichment inside Ultra-Short Carbon Nanotubes. NANOMATERIALS[J]. 2022, 12(19): http://dx.doi.org/10.3390/nano12193528.
[4] 闫隆. 1. Unexpected Selective Absorption of Lithium in Thermally Reduced Graphene Oxide Membranes. Chinese Physics Letters[J]. 2021, [5] Yin, Huiqin, Zhou, Yuying, Liu, Qi, Wang, Yang, Tang, Zhongfeng, Yan, Long. Corrosion behavior and mechanism of GH3535 alloy in NaOH, HF and H2O2 solution. JOURNAL OF ALLOYS AND COMPOUNDS[J]. 2021, 887: http://dx.doi.org/10.1016/j.jallcom.2021.161387.
[6] 崔二闯, wang chengbin, Zuo Yong, 冷滨, Yu, Guojun, wei zhang, long yan, xingchao li. Preparation of iridium‑hafnium intermetallic compound coatings in molten salts. SURFACEANDCOATINGSTECHNOLOGY[J]. 2021, 427: [7] Zhou, Yuying, Wang, Ying, Lei, Qiantao, Huang, Qing, Zhang, Wei, Yan, Long. Nanostructures and nanomechanical properties of ion-irradiated HOPG. CARBON LETTERS[J]. 2021, 31(4): 593-599, [8] Cao, Penghui, So, Kang Pyo, Yang, Yang, Park, Jong Gil, Li, Mingda, Yan, Long, Hu, Jing, Kirk, Mark, Li, Meimei, Lee, Young Hee, Short, Michael P, Li, Ju. Carbon nanotube (CNT) metal composites exhibit greatly reduced radiation damage. ACTA MATERIALIA[J]. 2021, 203: http://dx.doi.org/10.1016/j.actamat.2020.116483.
[9] 曹明鹏, 付崇龙, 曹建清, 邓琦, 雷前涛, 闫隆. 固溶元素对二元镍基合金的微结构及其抗辐照性能的影响. 核技术[J]. 2020, 43(5): 90-96, https://kns.cnki.net/KCMS/detail/detail.aspx?dbcode=CJFQ&dbname=CJFDLAST2020&filename=HJSU202005014&v=MjM5NzhNMUZyQ1VSN3FlWitSdkZpdmdXNy9BTFNmWWU3RzRITkhNcW85RVlJUjhlWDFMdXhZUzdEaDFUM3FUclc=.
[10] Wang, Xueliang, Liu, Yiyang, Shen, Miao, Fu, Xiaobin, Han, Ling, Ma, Guohong, Liu, Hongtao, Yan, Long. The investigation of molten ZnCl2 natural particle suspensions. ANALYTICAL METHODS[J]. 2020, 12(9): 1229-1236, https://www.webofscience.com/wos/woscc/full-record/WOS:000519116000006.
[11] Cao, Guoqin, Yang, Lei, Yuan, Gaihuan, Hu, Junhua, Shao, Guosheng, Yan, Long. Chemical diversity of iron species and structure evolution during the oxidation of C14 Laves phase Zr(Fe,Nb)(2) in subcritical environment. CORROSION SCIENCE[J]. 2020, 162: http://dx.doi.org/10.1016/j.corsci.2019.108218.
[12] Yang, Haijun, Yang, Yizhou, Sheng, Shiqi, Wen, Binghai, Sheng, Nan, Liu, Xing, Wan, Rongzheng, Yan, Long, Hou, Zhengchi, Lei, Xiaoling, Shi, Guosheng, Fang, Haiping. Controlling the Coffee Ring Effect on Graphene and Polymer by Cations. CHINESE PHYSICS LETTERS[J]. 2020, 37(2): 78-81, http://lib.cqvip.com/Qikan/Article/Detail?id=7102046399.
[13] Li, Jianjian, Yan, Long, Huang, Hefei, Huang, Qing, Ren, CuiLan, Lei, Guanhong, Lin, Jun, Fu, Chonglong, Bai, Juju. Corrosion behavior of ion-irradiated SiC in FLiNaK molten salt. CORROSION SCIENCE[J]. 2020, 163: http://dx.doi.org/10.1016/j.corsci.2019.108229.
[14] Zhou, Yuying, Yin, Huiqin, Wang, Xueliang, Cao, Mingpeng, Yang, Xu, Wu, Yanping, Wu, Boheng, Yan, Long. Corrosion behaviors of the UNS N10003 alloy in Fenton's reagent. MATERIALS AND CORROSION-WERKSTOFFE UND KORROSION[J]. 2020, 71(7): 1113-1117, https://www.webofscience.com/wos/woscc/full-record/WOS:000507109500001.
[15] Cao, Mingpeng, Chen, Huaican, Zhang, Wei, Ming, Tang, Wang, Yongqiang, Yan, Long. Effects of irradiation temperature on Ne ion irradiated binary nickel-based alloys. PHILOSOPHICAL MAGAZINE[J]. 2020, 100(24): 3061-3069, https://www.webofscience.com/wos/woscc/full-record/WOS:000558471300001.
[16] Wang, Xueliang, Yin, Huiqin, Liu, Wenguan, Yu, Guojun, He, Jian, Tang, Zhongfeng, Yan, Long. Ni, Cr, and Fe surfaces corroded by molten ZnCl2. MATERIALS AND CORROSION-WERKSTOFFE UND KORROSION[J]. 2020, 71(6): 931-937, https://www.webofscience.com/wos/woscc/full-record/WOS:000501678500001.
[17] Huiqin Yin, Shuang Wu, Xueliang Wang, Long Yan, Wenguan Liu, Zhongfeng Tang. Dataset for the thermodynamic description for the NaF-KF-RbF-ZnF2 system. DATA IN BRIEF[J]. 2019, 22: 1088-1093, http://dx.doi.org/10.1016/j.dib.2018.10.087.
[18] Wang, Peixue, Zhou, Dawei, Fei, Yuqing, Long, Yan, Deng, Youquan. Formation and Depolymerization of Oligomers during Thermal Cracking of Silicon-Containing Carbamates. CHEMPLUSCHEM[J]. 2019, 84(8): 1039-1045, [19] Fei, Yuqing, Liu, Shimin, Long, Yan, Lu, Liujin, He, Yude, Ma, Xiangyuan, Deng, Youquan. Single Lithium-ion Solid Conductors Based on Tetrazolate Anion and -Si-O- Species with Polyethylene Glycol Chains. CHEMELECTROCHEM[J]. 2019, 6(8): 2219-2223, https://www.webofscience.com/wos/woscc/full-record/WOS:000477022600012.
[20] 雷冠虹, 杨斯达, 刘仁多, 李健健, 黄庆, 李诚, 黄鹤飞, 闫隆. He泡对镍基合金腐蚀性能的影响. 核技术[J]. 2019, 42(4): 83-89, http://lib.cqvip.com/Qikan/Article/Detail?id=7001668781.
[21] Lei, Guanhong, Yang, Sida, Huang, Hefei, Huang, Qing, Liu, Renduo, Zhang, Wei, Yu, Guojun, Yan, Long. Corrosion-driven outward migration and growth of helium bubbles in a nickel-based alloy in high-temperature molten salt environment. CORROSION SCIENCE[J]. 2019, 153: 47-52, http://dx.doi.org/10.1016/j.corsci.2019.03.026.
[22] Zhang, Wei, Han, Han, Dai, Jianxing, Ren, Cuilan, Wang, Chengbin, Yan, Long, Huang, Hefei, Zhu, Zhiyuan. Simulation of migration and coalescence of helium bubbles in nickel. JOURNAL OF NUCLEAR MATERIALS[J]. 2019, 518: 48-53, http://dx.doi.org/10.1016/j.jnucmat.2019.02.023.
[23] Yan Long, Jian Li, Lanlan Wu, Qishun Wang, Yu Liu, Xiao Wang, Shuyan Song, Hongjie Zhang. Construction of trace silver modified core@shell structured Pt-Ni nanoframe@CeO2 for semihydrogenation of phenylacetylene. 纳米研究:英文版[J]. 2019, 12(4): 869-875, http://lib.cqvip.com/Qikan/Article/Detail?id=7001880743.
[24] Chen, Huaican, Hai, Yang, Liu, Renduo, Lei, Qiantao, Ye, Linfeng, Xu, Juping, Wang, Gang, Yin, Wen, Yan, Long, Zhou, Xingtai. The microstructure and mechanical properties of He ion irradiated Zr55Cu30Al10Ni5 bulk metallic glass. INTERMETALLICS[J]. 2019, 104: 52-58, http://www.corc.org.cn/handle/1471x/2164388.
[25] Fei, Yuqing, Liu, Shimin, Long, Yan, Lu, Liujin, He, Yude, Ma, Xiangyuan, Deng, Youquan. New single lithium ion conducting polymer electrolyte derived from delocalized tetrazolate bonding to polyurethane. ELECTROCHIMICA ACTA[J]. 2019, 299: 902-913, http://dx.doi.org/10.1016/j.electacta.2019.01.071.
[26] Zhou, Yuying, Li, Shimin, Wang, Ying, Huang, Qing, Zhang, Wei, Yao, Yao, Hao, Jiaming, Sun, Yan, Tang, Ming, Li, Bin, Zhang, Yi, Hu, Jun, Yan, Long. One-step ion beam irradiation manufacture of 3D micro/nanopatterned structures in SiC with tunable work functions. CARBON[J]. 2019, 148: 387-393, http://dx.doi.org/10.1016/j.carbon.2019.04.011.
[27] Yin, Huiqin, Wu, Shuang, Wang, Xueliang, Yan, Long, Liu, Wenguan, Tang, Zhongfeng. Thermodynamic description for the NaF-KF-RbF-ZnF2 system. JOURNAL OF FLUORINE CHEMISTRY[J]. 2019, 217: 90-96, http://dx.doi.org/10.1016/j.jfluchem.2018.09.008.
[28] Chen, Huaican, Hai, Yang, Liu, Renduo, Jiang, Li, Ye, Xiangxi, Li, Jianjian, Xue, Wandong, Wang, Wanxia, Tang, Ming, Yan, Long, Yin, Wen, Zhou, Xingtai. The irradiation hardening of Ni-Mo-Cr and Ni-W-Cr alloy under Xe26+ ion irradiation. NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS[J]. 2018, 421: 50-58, http://dx.doi.org/10.1016/j.nimb.2018.02.018.
[29] Wu, LanLan, Wang, QiShun, Li, Jian, Long, Yan, Liu, Yu, Song, ShuYan, Zhang, HongJie. Co9S8 Nanoparticles-Embedded N/S-Codoped Carbon Nanofibers Derived from Metal-Organic Framework-Wrapped CdS Nanowires for Efficient Oxygen Evolution Reaction. SMALL[J]. 2018, 14(20): https://www.webofscience.com/wos/woscc/full-record/WOS:000434172700010.
[30] Huang, Qing, Lei, Guanhong, Liu, Renduo, Li, Jianjian, Yan, Long, Li, Cheng, Liu, Weihua, Wang, Mouhua. Microstructure, hardness and modulus of carbon-ion-irradiated new SiC fiber (601-4). JOURNAL OF NUCLEAR MATERIALS[J]. 2018, 503: 91-97, http://dx.doi.org/10.1016/j.jnucmat.2018.02.044.
[31] Shi, Guosheng, Chen, Liang, Yang, Yizhou, Li, Deyuan, Qian, Zhe, Liang, Shanshan, Yan, Long, Li, Lu Hua, Wu, Minghong, Fang, Haiping. Two-dimensional Na-Cl crystals of unconventional stoichiometries on graphene surface from dilute solution at ambient conditions. NATURE CHEMISTRY[J]. 2018, 10(7): 776-779, http://www.corc.org.cn/handle/1471x/2179271.
[32] Huaican Chen, Yang Hai, Renduo Liu, Li Jiang, Xiangxi Ye, Jianjian Li, Wandong Xue, Wanxia Wang, Ming Tang, Long Yan, Wen Yin, Xingtai Zhou. The irradiation hardening of Ni-Mo-Cr and Ni-W-Cr alloy under Xe26+ ion irradiation. NUCLEAR INST. AND METHODS IN PHYSICS RESEARCH, B. 2018, 421: 50-58, http://dx.doi.org/10.1016/j.nimb.2018.02.018.
[33] Long, Yan, Song, Shuyan, Li, Jian, Wu, Lanlan, Wang, Qishun, Liu, Yu, Jin, Rongchao, Zhang, Hongjie. Pt/CeO2@MOF Core@Shell Nanoreactor for Selective Hydrogenation of Furfural via the Channel Screening Effect. ACS CATALYSIS[J]. 2018, 8(9): 8506-8512, http://dx.doi.org/10.1021/acscatal.8b01851.
[34] Wang, Xueliang, Shi, Guosheng, Liang, Shanshan, Liu, Jian, Li, Deyuan, Fang, Gang, Liu, Renduo, Yan, Long, Fang, Haiping. Unexpectedly High Salt Accumulation inside Carbon Nanotubes Soaked in Dilute Salt Solutions. PHYSICAL REVIEW LETTERS[J]. 2018, 121(22): http://www.corc.org.cn/handle/1471x/2168810.
[35] Lei, Guanhong, Xie, Ruobing, Huang, Hefei, Liu, Renduo, Huang, Qing, Li, Jianjian, Zhou, Yuying, Li, Cheng, Lei, Qiantao, Deng, Qi, Wang, Yongqi, Wang, Chengbin, Zhang, Wei, Yan, Long, Tang, Ming. The effect of He bubbles on the swelling and hardening of UNS N10003 alloy. JOURNAL OF ALLOYS AND COMPOUNDS[J]. 2018, 746: 153-158, http://dx.doi.org/10.1016/j.jallcom.2018.02.291.
[36] Wang, Peixue, Fei, Yuqing, Long, Yan, Deng, Youquan. Catalytic polymerization of CO2 to polyureas over K3PO4 catalyst. JOURNAL OF CO2 UTILIZATION[J]. 2018, 28: 403-407, http://dx.doi.org/10.1016/j.jcou.2018.10.020.
[37] Xu, Xia, Long, Yan, Lei, Pengpeng, Dong, Lile, Du, Kaimin, Feng, Jing, Zhang, Hongjie. A pH-responsive assembly based on upconversion nanocrystals and ultrasmall nickel nanoparticles. JOURNAL OF MATERIALS CHEMISTRY C[J]. 2017, 5(37): 9666-9672, http://dx.doi.org/10.1039/c7tc02665j.
[38] Huang, Qing, Lei, Qiantao, Deng, Qi, Tang, Hui, Wang, Yongqi, Li, Jianjian, Huang, Hefei, Yan, Long, Lei, Guanhong, Xie, Ruobing. Raman spectra and modulus measurement on the cross section of proton-irradiated graphite. NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS[J]. 2017, 412(-): 221-226, http://dx.doi.org/10.1016/j.nimb.2017.09.004.
[39] 黄庆, 李健健, 黄鹤飞, 闫隆, 朱智勇. 核石墨的氙离子辐照效应. 核动力工程[J]. 2017, "67-70", http://ir.sinap.ac.cn/handle/331007/28270.
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