081705-工业催化

羰基化反应，选择加氢，单原子催化

2008-09--2014-07   中国科学院大连化学物理研究所   博士
2004-09--2008-06   兰州大学   学士

   

2018-07~现在, 中国科学院大连化学物理研究所, 副研究员
2014-07~2018-07,中国科学院大连化学物理研究所, 助理研究员

   

[1] 王爱琴, 虞周楠, 张磊磊, 张盛鑫, 张涛. 一种负载型Rh单原子催化剂在烯烃氢甲酰化反应中的应用. CN: CN114163318A, 2022-03-11.
[2] 王爱琴, 任煜京, 张磊磊, 张涛. 负载型单原子分散贵金属催化剂的制备方法. CN: CN111135840B, 2021-11-23.
[3] 王爱琴, 任煜京, 张磊磊, 张涛. 高分散贵金属负载催化剂在芳香硝基化合物加氢中应用. CN: CN111135822B, 2021-11-09.
[4] 张磊磊, 王爱琴, 张涛. 一种合成α，β不饱和酮的方法. CN: CN113480419A, 2021-10-08.
[5] 王爱琴, 张磊磊, 张涛. 一种负载型催化剂在烯烃羰基化合成酮反应中的应用. CN: CN112979440A, 2021-06-18.
[6] 王爱琴, 张磊磊, 张涛. 一种负载型催化剂在烯烃氢甲酰化反应中的应用. CN: CN112973678A, 2021-06-18.
[7] 王爱琴, 王安, 任煜京, 张磊磊, 张涛. 一种负载型单原子贵金属催化剂在不饱和烃羧甲酯化反应中的应用. CN: CN112830877A, 2021-05-25.
[8] 王爱琴, 任煜京, 张磊磊, 张涛. 负载型单原子分散贵金属催化剂及制备方法. CN: CN111215053A, 2020-06-02.
[9] 王爱琴, 张帆, 张磊磊, 张涛. 一种负载型M 1 -M 2 -载体双功能催化剂及其制备方法和应用. CN: CN109833871A, 2019-06-04.
[10] 张磊磊, 王爱琴, 张涛, 刘文刚. 一种负载型非贵金属催化剂及其制备和应用. CN: CN108114723A, 2018-06-05.
[11] 王爱琴, 刘文刚, 张涛, 张涛. 一种负载型非贵金属催化剂及其制备和应用. CN: CN108114723A, 2018-06-05.
[12] 张磊磊, 王爱琴, 张涛, 刘文刚. 一种负载型Fe基催化剂及其制备和应用. CN: CN108114722A, 2018-06-05.
[13] 刘晓艳, 谭媛, 张磊磊, 刘菲, 王爱琴, 张涛. 一种高效催化不饱和醛酮选择加氢生成不饱和醇的金原子簇催化剂. CN: CN107857692A, 2018-03-30.
[14] 王爱琴, 刘文刚, 张磊磊, 张涛. 一种负载型非贵金属催化剂及其制备和在腈合成上的应用. CN: CN106881131A, 2017-06-23.
[15] 刘晓艳, 裴广贤, 王爱琴, 张涛, 张磊磊. 一种含镍的合金催化剂在炔烃选择加氢反应中的应用. CN: CN106861715A, 2017-06-20.
[16] 刘晓艳, 谭媛, 王爱琴, 张涛, 张磊磊. 一种负载型金原子簇催化剂的应用. CN: CN105985208A, 2016-10-05.
[17] 张磊磊, 王爱琴, 张涛. 一种负载型金钯催化剂及其制备和应用. CN: CN102806105A, 2012-12-05.

   

[1] J. Am. Chem. Soc.. 2024,   通讯作者  
[2] J. Am. Chem. Soc.. 2023,   通讯作者  
[3] Leilei Zhang, Aiqin Wang. Site density as an approach to regulating single-atom catalysis. CHEM CATALYSIS. 2023, 第 1 作者3(5): http://dx.doi.org/10.1016/j.checat.2023.100620.
[4] Shi, Jiajia, Wei, Yao, Zhang, Leilei, Zhou, Dan, Yu, Zhounan, Zhang, Shengxin, Yang, Xiaofeng, Yang, Ji, Su, Yang, Jiang, Zheng, Wang, Aiqin. Potassium-promoted single-atom Co-N-C catalyst f or direct dehydrogenation of ethylbenzene. NANO RESEARCH[J]. 2023, 第 3 作者16(3): 3687-3694, http://dx.doi.org/10.1007/s12274-022-4828-y.
[5] Leilei Zhang, Ji Yang, Xiaofeng Yang, Aiqin Wang, Tao Zhang. Structural evolution of single-atom catalysts. CHEM CATALYSIS. 2023, 第 1 作者3(3): http://dx.doi.org/10.1016/j.checat.2023.100560.
[6] Zhou, Dan, Zhang, Leilei, Liu, Xiaoyan, Qi, Haifeng, Liu, Qinggang, Yang, Ji, Su, Yang, Ma, Jingyuan, Yin, Jianzhong, Wang, Aiqin. Tuning the coordination environment of single-atom catalyst M-N-C towards selective hydrogenation of functionalized nitroarenes. NANO RESEARCH[J]. 2022, 第 2 作者  通讯作者  15(1): 519-527, http://apps.webofknowledge.com/CitedFullRecord.do?product=UA&colName=WOS&SID=5CCFccWmJJRAuMzNPjj&search_mode=CitedFullRecord&isickref=WOS:000660374800002.
[7] Shi, Jiajia, Wei, Yao, Zhou, Dan, Zhang, Leilei, Yang, Xiaofeng, Miao, Zhili, Qi, Haifeng, Zhang, Shengxin, Li, Anqi, Liu, Xiaoyan, Yan, Wensheng, Jiang, Zheng, Wang, Aiqin, Zhang, Tao. Introducing Co-O Moiety to Co-N-C Single-Atom Catalyst for Ethylbenzene Dehydrogenation. ACS CATALYSIS. 2022, 第 4 作者http://dx.doi.org/10.1021/acscatal.2c01873.
[8] Zhang, Yue, Li, Lin, Liu, Fei, Qi, Haifeng, Zhang, Leilei, Guan, Weixiang, Liu, Yuefeng, Wang, Aiqin, Zhang, Tao. Synergy between Ru and WOxEnables EfficientHydrodeoxygenation of Primary Amides to Amines. ACS CATALYSIS[J]. 2022, 第 5 作者12(11): 6302-6312, 
[9] 郝睿, 关伟翔, 刘菲, 张磊磊, 王爱琴. Lewis酸催化纤维素制乳酸机理研究. 物理化学学报[J]. 2022, 第 4 作者38(10): 57-64, http://lib.cqvip.com/Qikan/Article/Detail?id=7108278130.
[10] Yang, Ji, Qi, Haifeng, Li, Anqi, Liu, Xiaoyan, Yang, Xiaofeng, Zhang, Shengxin, Zhao, Qiao, Jiang, Qike, Su, Yang, Zhang, Leilei, Li, JianFeng, Tian, ZhongQun, Liu, Wei, Wang, Aiqin, Zhang, Tao. Potential-Driven Restructuring of Cu Single Atoms to Nanoparticles for Boosting the Electrochemical Reduction of Nitrate to Ammonia. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY[J]. 2022, 第 10 作者144(27): 12062-12071, 
[11] Nat. Commun.. 2021,   通讯作者  
[12] Zhou, Dan, Zhang, Leilei, Liu, Wengang, Xu, Gang, Yang, Ji, Jiang, Qike, Wang, Aiqin, Yin, Jianzhong. Reaction kinetics and phase behavior in the chemoselective hydrogenation of 3-nitrostyrene over Co-N-C single-atom catalyst in compressed CO2. CHINESE JOURNAL OF CATALYSIS[J]. 2021, 第 2 作者  通讯作者  42(9): 1617-1624, http://dx.doi.org/10.1016/S1872-2067(20)63785-8.
[13] Tan, Yuan, Liu, Xiaoyan, Zhang, Leilei, Liu, Fei, Wang, Aiqin, Zhang, Tao. Producing of cinnamyl alcohol from cinnamaldehyde over supported gold nanocatalyst. CHINESE JOURNAL OF CATALYSIS[J]. 2021, 第 3 作者42(3): 470-481, http://dx.doi.org/10.1016/S1872-2067(20)63678-6.
[14] 周丹, 张磊磊, 刘文刚, 徐刚, 杨级, 蒋齐可, 王爱琴, 银建中. 压缩CO2中Co-N-C催化3-硝基苯乙烯选择性加氢反应动力学及相行为. 催化学报[J]. 2021, 第 2 作者42(9): 1617-1624, http://lib.cqvip.com/Qikan/Article/Detail?id=7104542110.
[15] 谭媛, 刘晓艳, 张磊磊, 刘菲, 王爱琴, 张涛. 纳米金催化肉桂醛选择加氢制肉桂醇（英文）. CHINESE JOURNAL OF CATALYSIS. 2021, 第 3 作者470-481, https://kns.cnki.net/KCMS/detail/detail.aspx?dbcode=CJFQ&dbname=CJFDLAST2021&filename=CHUA202103012&v=MzIxOTBoMVQzcVRyV00xRnJDVVI3dWZZZWRuRkNybVZMdktKaVhlYjdHNEhORE1ySTlFWm9SOGVYMUx1eFlTN0Q=.
[16] Qi, Haifeng, Zhang, Leilei, Yang, Jingyi, Su, Yang, Zeng, Guang, Wang, Aiqin, Zhang, Tao. Highly efficient Co single-atom catalyst for epoxidation of plant oils. JOURNAL OF CHEMICAL PHYSICS[J]. 2021, 第 2 作者  通讯作者  154(13): https://www.webofscience.com/wos/woscc/full-record/WOS:000636821700003.
[17] Liu, Qiaoyun, Qiao, Botao, Liu, Fei, Zhang, Leilei, Su, Yang, Wang, Aiqin, Zhang, Tao. Catalytic production of 1,4-pentanediol from furfural in a fixed-bed system under mild conditions (vol 22, pg 3532, 2020). GREEN CHEMISTRY. 2020, 第 4 作者22(15): 5179-5179, http://dx.doi.org/10.1039/d0gc90075c.
[18] Qi, Haifeng, Liu, Fei, Zhang, Leilei, Li, Lin, Su, Yang, Yang, Jingyi, Hao, Rui, Wang, Aiqin, Zhang, Tao. Modulating trans-imination and hydrogenation towards the highly selective production of primary diamines from dialdehydes. GREEN CHEMISTRY[J]. 2020, 第 3 作者22(20): 6897-6901, https://www.webofscience.com/wos/woscc/full-record/WOS:000579757000018.
[19] Zhang, Leilei, Zhou, Maoxiang, Wang, Aiqin, Zhang, Tao. Selective Hydrogenation over Supported Metal Catalysts: From Nanoparticles to Single Atoms. CHEMICAL REVIEWS. 2020, 第 1 作者120(2): 683-733, http://dx.doi.org/10.1021/acs.chemrev.9b00230.
[20] Yujing Ren, Yan Tang, Leilei Zhang, Xiaoyan Liu, Lin Li, Shu Miao, Dang Sheng Su, Aiqin Wang, Jun Li, Tao Zhang. Unraveling the coordination structure-performance relationship in Pt-1/Fe2O3 single-atom catalyst. NATURE COMMUNICATIONS[J]. 2019, 第 3 作者10(1): https://doaj.org/article/a66b003a03564c0aa00f8da44b8277e5.
[21] Yang, Man, Qi, Haifeng, Liu, Fei, Ren, Yujing, Pan, Xiaoli, Zhang, Leilei, Liu, Xiaoyan, Wang, Hua, Pang, Jifeng, Zheng, Mingyuan, Wang, Aiqin, Zhang, Tao. One-Pot Production of Cellulosic Ethanol via Tandem Catalysis over a Multifunctional Mo/Pt/WOx Catalyst. JOULE[J]. 2019, 第 6 作者3(8): 1937-1948, http://dx.doi.org/10.1016/j.joule.2019.05.020.
[22] Tang, Hailian, Su, Yang, Guo, Yalin, Zhang, Leilei, Li, Tianbo, Zang, Ketao, Liu, Fei, Li, Lin, Luo, Jun, Qiao, Botao, Wang, Junhu. Oxidative strong metal-support interactions (OMSI) of supported platinum-group metal catalysts. CHEMICAL SCIENCE[J]. 2018, 第 4 作者9(32): 6679-6684, https://www.webofscience.com/wos/woscc/full-record/WOS:000442605300011.
[23] Zhang, Leilei, Ren, Yujing, Liu, Wengang, Wang, Aiqin, Zhang, Tao. Single-atom catalyst: a rising star for green synthesis of fine chemicals. NATIONAL SCIENCE REVIEW[J]. 2018, 第 1 作者5(5): 653-672, http://lib.cqvip.com/Qikan/Article/Detail?id=6100230339.
[24] Chen, Fang, Jiang, Xunzhu, Zhang, Leilei, Lang, Rui, Qiao, Botao. Single-atom catalysis: Bridging the homo- and heterogeneous catalysis. CHINESE JOURNAL OF CATALYSIS[J]. 2018, 第 3 作者39(5): 893-898, http://cas-ir.dicp.ac.cn/handle/321008/167140.
[25] Liu, Wengang, Chen, Yinjuan, Qi, Haifeng, Zhang, Leilei, Yan, Wensheng, Liu, Xiaoyan, Yang, Xiaofeng, Miao, Shu, Wang, Wentao, Liu, Chenguang, Wang, Aiqin, Li, Jun, Zhang, Tao. A Durable Nickel Single-Atom Catalyst for Hydrogenation Reactions and Cellulose Valorization under Harsh Conditions. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2018, 第 4 作者57(24): 7071-7075, http://dx.doi.org/10.1002/anie.201802231.
[26] Liu, Wengang, Zhang, Leilei, Liu, Xin, Liu, Xiaoyan, Yang, Xiaofeng, Miao, Shu, Wang, Wentao, Wang, Aiqin, Zhang, Tao. Discriminating Catalytically Active FeNx Species of Atomically Dispersed Fe-N-C Catalyst for Selective Oxidation of the C-H Bond. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY[J]. 2017, 第 2 作者139(31): 10790-10798, http://cas-ir.dicp.ac.cn/handle/321008/149816.
[27] Pei, Guang Xian, Liu, Xiao Yan, Yang, Xiaofeng, Zhang, Leilei, Wang, Aiqin, Li, Lin, Wang, Hua, Wang, Xiaodong, Zhang, Tao. Performance of Cu-Alloyed Pd Single-Atom Catalyst for Semihydrogenation of Acetylene under Simulated Front-End Conditions. ACS CATALYSIS[J]. 2017, 第 4 作者7(2): 1491-1500, http://cas-ir.dicp.ac.cn/handle/321008/169642.
[28] Tan, Yuan, Liu, Xiao Yan, Zhang, Leilei, Wang, Aiqin, Li, Lin, Pan, Xiaoli, Miao, Shu, Haruta, Masatake, Wei, Haisheng, Wang, Hua, Wang, Fangjun, Wang, Xiaodong, Zhang, Tao. ZnAl-Hydrotalcite-Supported Au-25 Nanoclusters as Precatalysts for Chemoselective Hydrogenation of 3-Nitrostyrene. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2017, 第 3 作者56(10): 2709-2713, http://cas-ir.dicp.ac.cn/handle/321008/169614.
[29] Chai, Meng Qian, Tan, Yuan, Pei, Guang Xian, Li, Lin, Zhang, Leilei, Liu, Xiao Yan, Wang, Aiqin, Zhang, Tao. Crystal Plane Effect of ZnO on the Catalytic Activity of Gold Nanoparticles for the Acetylene Hydrogenation Reaction. JOURNAL OF PHYSICAL CHEMISTRY C[J]. 2017, 第 5 作者121(36): 19727-19734, http://cas-ir.dicp.ac.cn/handle/321008/150171.
[30] Yang, Jinfan, Li, Shanshan, Zhang, Leilei, Liu, Xiaoyan, Wang, Junhu, Pan, Xiaoli, Li, Ning, Wang, Aiqin, Cong, Yu, Wang, Xiaodong, Zhang, Tao. Hydrodeoxygenation of furans over Pd-FeOx/SiO2 catalyst under atmospheric pressure. APPLIED CATALYSIS B-ENVIRONMENTAL[J]. 2017, 第 3 作者201: 266-277, http://cas-ir.dicp.ac.cn/handle/321008/169936.
[31] Ren, Yujing, Wei, Haisheng, Yin, Guangzhao, Zhang, Leilei, Wang, Aiqin, Zhang, Tao. Oxygen surface groups of activated carbon steer the chemoselective hydrogenation of substituted nitroarenes over nickel nanoparticles. CHEMICAL COMMUNICATIONS[J]. 2017, 第 4 作者53(12): 1969-1972, http://cas-ir.dicp.ac.cn/handle/321008/169512.
[32] Wei, Haisheng, Ren, Yujing, Wang, Aiqin, Liu, Xiaoyan, Liu, Xin, Zhang, Leilei, Miao, Shu, Li, Lin, Liu, Jingyue, Wang, Junhu, Wang, Guofu, Su, Dangsheng, Zhang, Tao. Remarkable effect of alkalis on the chemoselective hydrogenation of functionalized nitroarenes over high-loading Pt/FeOx catalysts. CHEMICAL SCIENCE[J]. 2017, 第 6 作者8(7): 5126-5131, https://www.webofscience.com/wos/woscc/full-record/WOS:000404617300050.
[33] Liu, Wengang, Zhang, Leilei, Yan, Wensheng, Liu, Xiaoyan, Yang, Xiaofeng, Miao, Shu, Wang, Wentao, Wang, Aiqin, Zhang, Tao. Single-atom dispersed Co-N-C catalyst: structure identification and performance for hydrogenative coupling of nitroarenes. CHEMICAL SCIENCE[J]. 2016, 第 2 作者7(9): 5758-5764, http://www.corc.org.cn/handle/1471x/2375170.
[34] 周茂祥, 张磊磊, Jeffrey, T., MILLER, 杨小峰, 刘晓艳, 王爱琴, 张涛. Au6Pd／resin催化伯醇和仲醇氧化偶联一转移加氢反应制备酮类化合物. 催化学报[J]. 2016, 第 2 作者37(10): 1764-1770, http://lib.cqvip.com/Qikan/Article/Detail?id=670385601.
[35] Zhou, Maoxiang, Zhang, Leilei, Miller, Jeffrey T, Yang, Xiaofeng, Liu, Xiaoyan, Wang, Aiqin, Zhang, Tao. Hydrogen auto-transfer under aerobic oxidative conditions: Efficient synthesis of saturated ketones by aerobic C-C cross-coupling of primary and secondary alcohols catalyzed by a Au6Pd/resin catalyst. CHINESE JOURNAL OF CATALYSIS[J]. 2016, 第 2 作者37(10): 1764-1770, http://cas-ir.dicp.ac.cn/handle/321008/169836.
[36] Zhang, Leilei, Wang, Aiqin, Wang, Wentao, Huang, Yanqiang, Liu, Xiaoyan, Miao, Shu, Liu, Jingyue, Zhang, Tao. Co-N-C Catalyst for C-C Coupling Reactions: On the Catalytic Performance and Active Sites. ACS CATALYSIS[J]. 2015, 第 1 作者5(11): 6563-6572, http://cas-ir.dicp.ac.cn/handle/321008/148226.
[37] 刘晓艳, 魏海生, 王爱琴, 张磊磊, 张涛. XAS Characterization of FeOx-Supported Platinum Single-Atom and Pseudo-Single-Atom Catalysts for Chemoselective Hydrogenation of Functionalized Nitroarenes. 16th international conference on x-ray absorption structure. 2015, 第 4 作者http://cas-ir.dicp.ac.cn/handle/321008/143401.
[38] Zhang, Leilei, Wang, Aiqin, Miller, Jeffrey T, Liu, Xiaoyan, Yang, Xiaofeng, Wang, Wentao, Li, Lin, Huang, Yanqiang, Mou, ChungYuan, Zhang, Tao. Efficient and Durable Au Alloyed Pd Single-Atom Catalyst for the Ullmann Reaction of Aryl Chlorides in Water. ACS CATALYSIS[J]. 2014, 第 1 作者4(5): 1546-1553, http://cas-ir.dicp.ac.cn/handle/321008/145828.
[39] Wei, Haisheng, Liu, Xiaoyan, Wang, Aiqin, Zhang, Leilei, Qiao, Botao, Yang, Xiaofeng, Huang, Yanqiang, Miao, Shu, Liu, Jingyue, Zhang, Tao. FeOx-supported platinum single-atom and pseudo-single-atom catalysts for chemoselective hydrogenation of functionalized nitroarenes. NATURE COMMUNICATIONS[J]. 2014, 第 4 作者5(1): http://cas-ir.dicp.ac.cn/handle/321008/143945.
[40] Wang, Wentao, Cong, Yu, Zhang, Leilei, Huang, Yanqiang, Wang, Xiaodong, Zhang, Tao. Aerobic oxidative transformation of primary alcohols and amines to amides promoted by a hydroxyapatite-supported gold catalyst in water. TETRAHEDRON LETTERS[J]. 2014, 第 3 作者55(1): 124-127, http://dx.doi.org/10.1016/j.tetlet.2013.10.133.
[41] 张磊磊, 王文涛, 王爱琴, 刘晓艳, 杨小峰, 张涛. Green synthesis of amide and imine through aerobic oxidative coupling of alcohol and amine over Au-Pd/resin. the 6th aisa-pacific congress on catalysis. 2013, 第 1 作者83, http://159.226.238.44/handle/321008/120210.
[42] 张磊磊, 王爱琴, 黄延强, 张涛. A highly efficient ion-exchange resin supported Au-Pd alloy catalyst for Suzuki cross-coupling and Ullmann reactions in water. 15TH INTERNATION CONGRESS ON CATALYSIS. 2012, 第 1 作者0, http://159.226.238.44/handle/321008/117184.

   

（ 1 ） 氢甲酰化反应高选择性、抗流失单原子催化剂的研制, 负责人, 国家任务, 2022-01--2025-12
（ 2 ） 乙烯/乙炔羧酯化反应多功能单原子催化剂的构筑, 参与, 国家任务, 2022-01--2026-12
（ 3 ） 用于长链烯烃羰基化反应的单原子催化剂创制, 参与, 国家任务, 2022-01--2026-12