基本信息

麻生明  男  博导  中国科学院上海有机化学研究所

中国科学院院士(2005-)发展国家科学院院士(2008-)
电子邮件: masm@sioc.ac.cn
通信地址: 上海市零陵路345号中科院上海有机所金属有机化学国家重点实验室
邮政编码: 200032

研究领域

有机化学:方法学、目标分子合成、化学-区域-立体选择性控制


特别关注:

1)联烯化学:合成新方法、新反应、目标分子合成的应用、药物化学

2)炔烃化学

3)二氧化碳的活化

4)不对称催化与合成

招生信息

有机化学

招生专业
070303-有机化学
招生方向
有机合成化学
金属有机化学

教育背景

1988-12--1990-12   中国科学院上海有机化学研究所   博士
1986-09--1988-12   中国科学院上海有机化学研究所   硕士
1982-09--1986-08   杭州大学化学系   本科
学历

1.      1986.9—1990.12        中国科学院上海有机化学研究所,分别于198812月及199012

                                            获得理学硕士及博士学位(师从中科院院士陆熙炎研究员)

2.      1990.12—1992.9        中科院上海有机化学研究所,助理研究员、副研究员

3.      1992.9 –1993.10         瑞士苏黎世联邦理工大学(ETH)从事博士后研究工作 (with Prof. Venanzi)

4.      1993.10—1997.3        美国普渡大学(Purdue University)从事博士后研究工作 (with Prof. Negishi)


学位
博士, 1988,中科院上海有机所

工作经历

1.      1997.3—2007.10        中国科学院上海有机化学研究所,副研究员、研究员。

                                             20032月中国科学院上海有机化学研究所和浙江大学

                                             共聘为教育部长江学者奖励计划特聘教授;

                                             200511月当选为中国科学院院士

2.      2007.10—2014.8        华东师范大学教授和中国科学院上海有机化学研究所

                                             特聘研究员及浙江大学求是特聘教授;

                                             2008年当选为发展中国家科学院院士

3.      2014.9—至今              中国科学院上海有机化学研究所特聘研究员

                                             及浙江大学、 复旦大学教授



教授课程

金属有机化学

专利与奖励

For the contribution as a graduate student with Prof Xiyan Lu:

1. 1992         First-Class Natural Science Awards of Chinese Academy of Sciences

2. 1994         Research Accomplishments Award

3. 1997         First-Class Natural Science Awards of Chinese Academy of Sciences

4. 1999         Second-Class National Natural Science Awards

 

For the contribution as a PI:

5. 2004         Mr. and Mrs. Sun Chan Memorial Award in Organic Chemistry

6. 2004         First-Class Award for Progress in Science and Technology of Shanghai

7. 2005         OMCOS 13 Award

8. 2006         Second-Class National Natural Science Awards

9. 2010         First-Class Natural Science Awards of Shanghai


奖励信息
(1) 上海市自然科学奖, 一等奖, 省级, 2010
(2) 中国科学院优秀研究生指导教师奖, , 部委级, 2009
(3) 中国科学院优秀研究生指导教师, , 部委级, 2008
(4) 第三届中国化学会黄耀曾金属有机, , 其他, 2008
(5) 国家自然科学奖, 二等奖, 国家级, 2006
(6) 中科院研究生院优秀教育工作者, , 部委级, 2006
(7) OMCOS 13 Award, , 专项, 2005
(8) 第五届上海市自然科学牡丹奖, , 省级, 2004
(9) 上海市科技进步奖, 一等奖, 省级, 2004
(10) 中国化学会有机化学专业委员会“, , 其他, 2004
(11) Mr. and Mrs. Su, , 专项, 2004
(12) 中国科学院优秀研究生指导教师, , 部委级, 2004
(13) 中国科学院优秀研究生导师奖, , 部委级, 2003
(14) 全国留学回国人员成就奖, , 国家级, 2003
(15) 中国科学院青年科学家奖, 一等奖, 部委级, 1999
(16) 求是基金杰出青年学者奖, , 专项, 1999
(17) 国家自然科学奖, 二等奖, 国家级, 1999
(18) 中国化学会青年化学奖, , 部委级, 1999
(19) 中国科学院自然科学奖, 一等奖, 部委级, 1997
(20) 中科院院长奖学金特别奖, , 部委级, 1991
专利成果
( 1 ) α-萘甲基取代的螺环双噁唑啉配体、合成及其在合成吡咯烷衍生物中的应用, 发明, 2009, 第 1 作者, 专利号: 200910051785.4
( 2 ) β-萘甲基取代的螺环双噁唑啉配体、合成方法及其应用, 发明, 2009, 第 2 作者, 专利号: 200910196167.9
( 3 ) 一种氧气氧化醇制备醛或酮的方法, 发明, 2014, 第 1 作者, 专利号: 201010237170.3
( 4 ) 一种氧气氧化醇制备醛或酮的方法, 发明, 2012, 第 1 作者, 专利号: PCT/CN2010/075608
( 5 ) 吲哚并八元环双烯化合物、合成方法及其应用于伊普吲哚的合成, 发明, 2014, 第 1 作者, 专利号: ZL201210165288.9
( 6 ) 光学活性轴手性?-联烯醇、合成方法和用途, 发明, 2014, 第 1 作者, 专利号: ZL201210193176.4
( 7 ) Process for Producing Aldehydes or Ketones by Oxidizing Alcohols with Oxygen, 发明, 2014, 第 1 作者, 专利号: US 8,748,669 B2
( 8 ) Process for Producing Aldehydes or Ketones by Oxidizing Alcohols with Oxygen, 发明, 2016, 第 1 作者, 专利号: 2599765
( 9 ) 一种氧气氧化醇制备醛或酮的方法, 发明, 2014, 第 1 作者, 专利号: 特许第5496366号
( 10 ) 多取代吲哚、合成方法及其应用于吲哚美辛的合成, 发明, 2015, 第 1 作者, 专利号: 201310024285.8

科研活动

   
科研项目
( 1 ) 子课题:二氧化碳的固定和转化, 参与, 国家级, 2015-01--2019-08
( 2 ) 过渡金属催化的基于不饱和键的反应方法学研究, 主持, 国家级, 2013-01--2017-12
参与会议
(1)Unique Reactions of Terminal Alkynes and Aldehydes in the Presence of Amines   麻生明   2014-11-20
(2)Recent Advances on Enantioselective Synthesis of Allenes   麻生明   2014-09-08
(3)Naturally occurring carbazoles from allenols   Shengming Ma   2011-12-07
(4)\   \   2011-07-25
(5)Cyclization Reactions Involving Two Allene Moieties   Shengming Ma   2010-11-23
(6)/   /   2010-10-08
(7)Stereoselective Synthesis based on the Chemistry of Allenes   Shengming Ma   2010-08-01
(8)Efficient constructions of heterocycles from allenes   Shengming Ma   2010-07-01
(9)Development of New o-Alkoxyphenyl Dicyclohexyl Phosphine Ligands for C-C    Shengming Ma   2010-06-23
(10)Electrophilic Reactions of Allenes and the Application   Shengming Ma   2009-07-01

曾经指导的部分学生

已指导学生

于飞  01  19132  

吴滨  01  19132  

陆梁华  01  19132  

焦宁  01  19132  

张俊良  01  19132  

倪步阔  01  19132  

王利莎  01  19132  

高文忠  01  19132  

俞瞻前  01  19132  

何绮雯  01  19132  

张爱斌  01  19132  

施章杰  01  19132  

余世超  01  19132  

徐镇江  01  19132  

程鑫  01  19132  

顾振华  01  19132  

郭浩  01  19132  

姜雪峰  01  19132  

陆平  01  19132  

赵金钵  01  19132  

白涛  01  19132  

舒伟  01  19132  

陈洁  01  19132  

练雄东  01  19132  

倪圣军  02  19132  

李苏华  01  19132  

成佳佳  01  19132  

叶俊涛  01  19132  

陈波  01  19132  

朱灿  01  19132  

汤鑫军  01  19132  

现指导学生

曹陶  01  19132  

林渭龙  01  19132  

蔡毓娟  02  67935  

杨正  02  19132  

韩玉林  01  19132  

翟毅展  02  19132  

刘琦  02  19132  

唐阳  01  19132  

姜兴国  01  19132  

发表论文情况

Since 1988

1. J. Am. Chem. Soc.

19

2. Angew. Chem. Int. Ed.

35

3. Acc. Chem. Res.

3

4. Chem. Sci.

3

5. Nature Communications

4

6. Chem. Rev.  

1

7. Aldrichimica Acta  

1

发表论文目录(2012-)

1. Allenes in Catalytic Asymmetric Synthesis and Natural Product Syntheses
Shichao Yu and Shengming Ma*
Angew. Chem. Int. Ed. 2012, 51, 3074-3112.
 
2. One-Pot Approach to Installing Eight-Membered Rings onto Indoles
Can Zhu, Xue Zhang, Xiongdong Lian, and Shengming Ma*
Angew. Chem. Int. Ed. 2012, 51, 7817-7820.
 
3. Palladium-Catalyzed Cyclization Reactions of 2,3-Allenyl Amines with Propargylic Carbonates
Juntao Ye, Suhua Li, and Shengming Ma*
Org. Lett. 2012, 14, 2312-2315.
 
4. Palladium-Catalyzed Decarboxylation of Allenyl 3-Oxoalkanoates: An Efficient Synthesis of 3,4-Allenyl Ketones
Baoqiang Wan, Guochen Jia*, and Shengming Ma*
Org. Lett. 2012, 14, 46-49.

 

5. Catalytic Asymmetric Synthesis of Optically Active Allenes from Terminal Alkynes
Juntao Ye, Suhua Li, Bo Chen,Wu Fan, Jinqiang Kuang, Jinxian Liu, Yu Liu, Bukeyan Miao, Baoqiang Wan, Yuli Wang, Xi Xie, Qiong Yu, Weiming Yuan, and Shengming Ma*
Org. Lett. 2012, 14, 1346-1349.
 
6. Tuning of Regioselectivity in Inorganic Iodide-Catalyzed Alkylation of 2-Methoxyfurans via Electronic and Steric Effects
Jie Chen, Shengjun Ni, and Shengming Ma*
Adv. Synth. Catal. 2012, 354, 1114-1128.
 
7. Electronic Effect Directed Au(I)-Catalyzed Cyclic C2-H Bond Functionalization of 3-Allenylindoles
Bo Chen, Wu Fan, Guobi Chai, and Shengming Ma*
Org. Lett. 2012, 14, 3616-3619.
 
8. CO2-Activation for γ-Butyrolactones and Its Application in the Total Synthesis of (±)-Heteroplexisolide E
Suhua Li and Shengming Ma*
Chem. Asian J. 2012, 7, 2411-2418.
 
9. Quadri-Synergtic Effect for Highly Effective Carbon Dioxide Fixation and Its Application to Indoloquinolinone
Suhua Li and Shengming Ma*
Adv. Synth. Catal. 2012, 354, 2387-2394.
 
10. Electrophilic Cyclization of 2-(2’,3’-Allenyl)acetylacetates with Iodine Using Calcium Hydride as the Base
Baoqiang Wan, Xuefeng Jiang, Guochen Jia,* and Shengming Ma*

Eur. J. Org. Chem. 2012, 4373-4379.

 

11. Efficient synthesis of N-(buta-2,3-dienyl) amides from terminal N-propargyl amides and their synthetic potential towards oxazoline derivatives
Bo Chen, Nan Wang, Wu Fan and Shengming Ma*

Org. Biomol. Chem. 2012, 10, 8465-8470.

 
12. FeCl3-catalyzed cyclization of -sulfonamido-allenes with aldehydes—the substituent effect
Jiajia Cheng, Xinjun Tang, Yihua Yu and Shengming Ma*
Chem. Commun. 2012, 48, 12074-12076.
 
13. Benzofurans or Isochromenes via the Ring-Opening Cyclization of Cyclopropene Derivatives with Organolithiums
Yu Liu and Shengming Ma*
Org. Lett. 2012, 14, 720-723.

 

14. Copper (I) Iodide-Catalyzed One-Step Preparation of Functionalized Allenes from Terminal Alkynes: Amine Effect
Jinqiang Kuang, Hongwen Luo, and Shengming Ma*
Adv. Synth. Catal. 2012, 354, 933-944.
 
15. Aerobic Oxidation of Propargylic Alcohols to α,β-Unsaturated Alkynals or Alkynones Catalyzed by Fe(NO3)3.9H2O, TEMPO and Sodium Chloride in Toluene
Jinxian Liu, Xi Xie, Shengming Ma*
Synthesis 2012, 44, 1569-1576.
 
16. CuCl-Catalyzed Aerobic Oxidation of Allylic and Propargylic Alcohols to Aldehydes or Ketones with 1∶1 Combination of Phenanthroline and Bipyridine as the Ligands
Yu Liu, Shengming Ma*
Chin. J. Chem. 2012, 30, 29-34.

 

17. CuCl–K2CO3-Catalyzed Highly Selective Borylcupration of Internal Alkynes–Ligand Effect
Weiming Yuan and Shengming Ma*             
Org. Biomol. Chem. 2012, 10, 7266-7268.
 
18. Efficient Synthesis of 4-Halo-2,5-dihydro-1,2-oxaphosphole 2-Oxides from 1,2-Allenylphosphonates and CuX2 and Subsequent Suzuki Cross-Coupling of the C–Cl Bonds
Ning Xin and Shengming Ma*
Eur. J. Org. Chem. 2012, 3806-3817.
 
19. Ligand Controlled Highly Selective Copper-Catalyzed Borylcuprations of Allenes with Bis(pinacolato)diboron
Weiming Yuan and Shengming Ma*
Adv. Synth. Catal. 2012, 354, 1867-1872.
 
20. Lewis acid-catalyzed unexpected selective C–C bond cleavage: an efficient and mild construction of cyclopentenes
Qiong Yu and Shengming Ma*
Chem. Commun. 2012, 48, 11784-11786.
 
21. Efficient Synthesis of Carbazoles via PtCl2-Catalyzed RT Cyclization of
1-(Indol-2-yl)-2,3-allenols: Scope and Mechanism
Wangqing Kong, Chunling Fu, and Shengming Ma*                      
Org. Biomol. Chem. 2012, 10, 2164–2173.
 
22. Application of LB-Phos·HBF4 in the Suzuki Coupling Reaction of
2-Bromoalken-3-ols with Alkylboronic Acids
Binjie Guo, Chunling Fu, and Shengming Ma*
Eur. J. Org. Chem. 2012, 4034-4041.
 
23. Highly Selective Mild Stepwise Allylation of N-Methoxybenzamides
with Allenes
Rong Zeng, Chunling Fu, and Shengming Ma*
J. Am. Chem. Soc. 2012, 134, 9597−9600.
 
24. Controlled Reactions of 2,3-Allenoates with a 1,3-Diketone Catalyst Effect 
Zhao Fang, Chunling Fu, and Shengming Ma*
Eur. J. Org. Chem. 2012, 2585–2596.
 
25. Formal Alkylation of Allenes through Highly Selective Radical Cyclizations of
Allene-enes
Rong Zeng, Chunling Fu,* and Shengming Ma*
Angew. Chem. Int. Ed. 2012, 51, 3888 –3891.
 
26. CuCl-Catalyzed Stereoselective Conjugate Addition of Grignard Reagents to
2,3-Allenoates
Jian He, Zhan Lu, Guobi Chai, Chunling Fu, Shengming Ma*
Tetrahedron 2012, 68, 2719-2724.
 
27. Stereoselective Iodolactonization of 4-Allenoic Acids with Efficient Chirality
Transfer: Development of a New Electrophilic Iodination Reagent
Xiaobing Zhang, Chunling Fu, Yihua Yu, and Shengming Ma*
Chem. Eur. J. 2012, 18, 13501 – 13509.
 
28. Iron-Catalyzed Unexpected Easy Access to Stereodefined Trimethylsilyl Vinyl
Ketenes
Guobi Chai, Chunling Fu, and Shengming Ma*
Org. Lett., 2012, 14, 4058-4061.
 
29. Carbon-Carbon Bond Formation via the Electrophilic Addition of Carbocations to
Allenes
Bo Meng and Shengming Ma*
Org. Lett. 2012, 14, 2674-2677.
 
30. Exclusive 1,2-Aryl Shift in Platinum(II) Chloride-Catalyzed Cyclization of
1-(Indol-2-yl)-2,3-allenols
Wangqing Kong, Youai Qiu, Xue Zhang, Chunling Fu, and Shengming Ma*
Adv. Synth. Catal. 2012, 354, 2339 – 2347.
 
31. Catalytic Asymmetric Allenylation of Malonates with the Generation
of Central Chirality
Qiankun Li, Chunling Fu, and Shengming Ma*
Angew. Chem. Int. Ed. 2012, 51, 11783–11786.
 
32. Carbazoles via AuCl3-Catalyzed Cyclization of 1-(Indol-2-yl)-3-alkyn-1-ols
Youai Qiu, Wangqing Kong, Chunling Fu, and Shengming Ma*
Org. Lett. 2012, 14, 6198-6201.

33. Tert-Butyldimethylsilyl-Directed Highly Enantioselective Approach to Axially Chiral α-Allenols
Juntao Ye, Wu Fan, and Shengming Ma*
Chem. Eur. J201319, 716 – 720

34. Unexpected Regioselectivity Switch: Organophosphine-Triggered Reactions of Cyclopropene-1,1-dicarboxylates with Aldehydes

Shengjun Ni, Jie Chen, and Shengming Ma*  

Org. Lett., 2013, 15, 3290-3293
                                                
 
35. Gorlos-phos: addressing the stereoselectivity in palladium-catalyzed exo-mode cyclization of allenes with a nucleophilic functionality
Juntao Ye, Suhua Li, and Shengming Ma*                                                  

Org. Biomol. Chem.201311, 5370–5373
 
36. Highly Selective FeCl3-Catalyzed Cyclization of β-Sulfonamidoallenes or    β-Allenols and Aldehydes
 Jiajia Cheng, Xinjun Tang, and Shengming Ma*                          

ACS Catal20133, 663−666                    

 
37. Carbometalation−Carboxylation of 2,3-Allenols with Carbon Dioxide: A Dramatic Effect of Halide Anion
Suhua Li, Bukeyan Miao, Weiming Yuan, and Shengming Ma*                                   
 Org. Lett.201315, 977-979


38. Enantioselective Decarboxylative Amination: Synthesis of Axially Chiral Allenyl Amines
Baoqiang Wan and Shengming Ma*                                                          
Angew. Chem. Int. Ed., 201352, 441-445 


39. Tandem Michael Addition/Cyclization Reaction of 2,3-Allenoates with Organozincs: Facile Synthesis of Isocoumarins
Bo Chen and Shengming Ma*                                                             
Org. Lett.201315, 3884-3887


40. Coupling and Cyclization of o-Iodoanilines and Propargylic Bromides via Allenes: An Efficient Entry to Indomethacin
Can Zhu and Shengming Ma*                                                              
Org. Lett., 201315, 2782-2785


41. Studies on ZnBr2-mediated Synthesis of Axially Chiral Aryl-substituted Allenes from Terminal Alkynes, Aromatic Aldehydes and (S)-α, α-diphenylprolinol
Juntao Ye, Ruizhi Lü, Wu Fan, & Shengming Ma*                                           
Tetrahedron 201369, 8959-8963.


42. Allene Relay: Palladium-Catalyzed Bicyclization of Allene-Propargylic Carbonates with Geminal Bis(nucleophile)s
Juntao Ye and Shengming Ma*                                                                     
 Angew. Chem. Int. Ed.201352, 10809-10813.


43. CuBr for KA2 Reaction: En Route to Propargylic Amines Bearing a Quaternary  Carbon Center
 Xinjun Tang, Jinqiang Kuang and Shengming Ma*                                            
 Chem. Commun., 2013, 49, 8976-8978.


44. Cadmium Iodide-mediated Allenylation of Terminal Alkynes with Ketones
Nat. Commun. 4: 2450 4:2450 doi: 10.1038/ncomms 3450 (2013).
Xinjun Tang, Can Zhu, Tao Cao, Jingqiang Kuang, Weilong Lin, Shengjun Ni, Jiasheng Zhang & Shengming Ma*     
                                                                  
45. Palladium-Catalyzed Reaction of Propargylic Carbonates with Benzyne
   Synlett 2013, 24, 2310-2314
Shengjun Ni, Wei Shu & Shengming Ma*    
 
46. Highly Regioselective Three-component Palladium-catalyzed
Synthesis of 5-vinyloxazolidin-2-ones from 2,3-allenyl amines,
Organic Iodides, and Carbon Dioxide
Tetrahedron 2013, 69, 10450-10456
   Suhua Li, Juntao Ye, Weiming Yuan & Shengming Ma* 
 
47. Preparation of 1-Benzyl-2-methyl-3-(ethoxycarbonyl)-4-(2-phenylethyl)
-1H-pyrrole from 4-Phenyl-1,2-butadiene
   Org. Synth., 2013, 90, 327-337                                  
Shengjun Ni, Zhu Can, Jie Chen & Shengming Ma*
 
48. A General Approach to Terminal Allenols
Synthesis 2013, 45, 592–595
Jinqiang Kuang, Xi Xie, Shengming Ma*                                              
 
49. Ring-Opening Reactions of Cyclopropenedicarboxylates with Organolithiums and Organozincs
Eur. J. Org. Chem., 2013, 3033–3040   
Yu Liu, Qiong Yu, and Shengming Ma*                                             
 
50. Aerobic Oxidation of Indole Carbinols Using Fe(NO3)3·9H2O/TEMPO/NaCl as Catalysts
Org. Biomol. Chem., 2013, 11, 4186–4193
Jinxian Liu and Shengming Ma*                                                           
 
51. CuI-Catalyzed Synthesis of Functionalized Terminal Allenes from 1-Alkynes
Eur. J. Org. Chem., 2013, 3041–3048
Hongwen Luo and Shengming Ma*                                                      
 
52. Palladium-catalyzed Asymmetric Coupling Cyclization of Terminal γ-allenols with Aryl Iodides
Chem. Commun., 2013, 49, 5693-5695
Xi Xie and Shengming Ma*                                                                   
 
53. A Room-Temperature Catalytic Asymmetric Synthesis of Allenes with ECNU-Phos
J. Am. Chem. Soc., 2013, 135, 11517−11520
Yuli Wang, Wanli Zhang, and Shengming Ma*                                          
 
54. Aerobic Oxidation of Propargyl Alcohol: A Convenient Method for the Synthesis of Propiolaldehyde
Synthesis 2013, 45, 1624–1626
Jinxian Liu, Shengming Ma*                                                              
 
55. Bimetallic Enantioselective Approach to Axially Chiral Allenes
Org. Lett. 2013, 15, 2254-2257
Ruizhi Lü, Juntao Ye, Tao Cao, Bo Chen, Wu Fan, Weilong Lin, Jinxian Liu, Hongwen Luo, Bukeyan Miao, Shengjun Ni, Xinjun Tang, Nan Wang, Yuli Wang, Xi Xie, Qiong Yu, Weiming Yuan, Wanli Zhang, Can Zhu, and Shengming Ma*                                     
 
56. Optically Active 2,3-Allenoates via Palladium-Catalyzed Carbonylation of Enantioenriched Propargylic Mesylates
Adv. Synth. Catal., 2013, 355, 741 – 750
Yuli Wang and Shengming Ma*                                                          
 
57. Amide-Controlled Highly Selective Catalytic Borylcupration of Allenes
 Chem. Eur. J., 2013, 19, 7193 – 7202
 Weiming Yuan, Xue Zhang,*Yihua Yu, and Shengming Ma* 
 
58. Iron-Catalyzed Aerobic Oxidation of Allylic Alcohols: The Issue of C═C Bond
Isomerization
Org. Lett., 2013, 15, 5150-5153
Jinxian Liu and Shengming Ma*      
 
59. An Easily Removable Stereo-dictating Group for Enantioselective Synthesis of Propargylic Amines
Chem. Commun., 2013, 49, 10175-10177
Wu Fan and Shengming Ma*    
 
60. Room Temperature Fe(NO3)3.9H2O/TEMPO/NaCl-Catalyzed Aerobic Oxidation of Homopropargylic Alcohols
Tetrahedron 2013, 69, 10161-10167
Jinxian Liu, Shengming Ma*                             
 
61. Copper-Catalyzed Cyclic Oxytrifluoromethylation of 2,3-Allenoic Acids to
Trifluoromethylated Butenolides
Chem. Eur. J., 2013, 19, 13304 – 13308
Qiong Yu and Shengming Ma*          
 
62. Pd-Catalyzed Suzuki Coupling Reaction of Chloroalkylidene-β-lactones with LB-Phos as the Ligand
Org. Biomol. Chem., 2013, 11, 98-109
Pengbin Li, Bo Lü, Chunling Fu, and Shengming Ma*
                                      
63. An Efficient Au-catalyzed Synthesis of Isomukonidine, Clausine L, Mukonidine, Glycosinine, Mukonal, and Clausine V from Propadienyl Methyl Ether
Org. Biomol. Chem., 2013, 11, 1666-1671
Youai Qiu, Dengke Ma, Chunling Fu* and Shengming Ma*     
 
64. Iron-Catalyzed Diastereoselective Synthesis of α-(Methoxycarbonyl)allylsilanes
Eur. J. Org. Chem., 2013, 148–154
Guobi Chai, Rong Zeng, Chunling Fu, and Shengming Ma* 
                                    
65. Cleavage of Oxygen–sulfur Double Bonds and Carbon–sulfur Bonds: Unusual Highly Selective Electrophilic Addition of Allenylic Sulfoxides
Chem. Sci., 2013, 4, 1016–1022
Minyan Wang, Chunling Fu and Shengming Ma*                            
 
66. Zheda-Phos for General α-Monoarylation of Acetone with Aryl Chlorides
Adv. Synth. Catal., 2013, 355, 1255 – 1259
Pengbin Li, Bo Lü, Chunling Fu, and Shengming Ma*  
                                    
67. Arene C-H Bond Functionalization Coupling with Cyclization of Allenes
Adv. Synth. Catal., 2013, 355, 1963 – 1970
Rong Zeng, Juntao Ye, Chunling Fu, and Shengming Ma*                      
 
68. C–F Bond Formation with Fluoride Anions – Highly Selective Iodofluorination
of Simple Allenes
Chem. Commun., 2013, 49, 5651-5653
Can Xue, Xinpeng Jiang, Chunling Fu* and Shengming Ma*                    
 
69. General Approach to Benzo[b]thiophenes, Benzo[b]furans, and Dibenzofurans Via Gold-Catalyzed Cyclization of 1-heteroarylalka-2,3-dienyl Acetates
Tetrahedron 2013, 69, 6305-6312
Youai Qiu, Dengke Ma, Chunling Fu, Shengming Ma*             
    
70. Palladium(0)-Catalyzed Regioselective Synthesis of Macrocycles from Allenes with a Nucleophilic Functionality and Organic Iodides
Adv. Synth. Catal., 2013, 355, 3295 – 3303
Xin Huang, Xinpeng Jiang, Chunling Fu, and Shengming Ma*        
 
71. Room-Temperature Synthesis of Trisubstituted Allenylsilanes via Regioselective C−H Functionalization
J. Am. Chem. Soc., 2013, 135, 18284-18287
Rong Zeng, Shangze Wu, Chunling Fu, and Shengming Ma*         
 
72. Efficient Carbazole Synthesis via Pd/Cu-Cocatalyzed Cross-Coupling/Isomerization of 2-Allyl-3-iodoindoles and Terminal Alkynes
Can Zhu and Shengming Ma*
Org. Lett., 2014, 16, 1542-1545                          
 
73. Copper-Mediated Pyrazole Synthesis from 2,3-Allenoates or 2-Alkynoates, Amines and Nitriles
Bo Chen, Can Zhu, Yang Tang and Shengming Ma*
Chem. Commun., 2014, 50, 7677-7679  
 
74. Enantioselective Double Manipulation on Tetrahydro- isoquinolines with Terminal Alkynes and Aldehydes under Copper(I) Catalysis
Weilong Lin, Tao Cao, Wu Fan, Yulin Han, Jinqiang Kuang, Hongwen Luo,    Bukeyan Miao, Xinjun Tang, Qiong Yu, Weiming Yuan, Jiasheng Zhang, Can Zhu, and Shengming Ma*
Angew. Chem. Int. Ed., 2014, 53, 277-281   
                                                               
75. Highly Efficient and General Enantioselective Synthesis of Naturally Occurring Isoquinoline Alkaloids
 Weilong Lin and Shengming Ma*
 Org. Chem. Front., 2014, 1, 338-346                                                             
 
76. Copper-Mediated Efficient Three-Component Synthesis of 1,2,4-Triazoles from Amines and Nitriles
Jinqiang Kuang, Bo Chen and Shengming Ma*
Org. Chem. Front., 2014, 1, 186-189                                     
 
77. Palladium-Catalyzed Cyclization Reactions of Allenes in the Presence of Unsaturated Carbon-Carbon Bonds
Juntao Ye and Shengming Ma*
Acc. Chem. Res., 2014, 47, 989-1000                                                                          
 
78. Sc(OTf)3-Catalyzed Bicyclization of o-Alkynylanilines with Aldehydes: Ring-Fused 1,2-Dihydroquinolines
Can Zhu and Shengming Ma*
Angew. Chem. Int. Ed., 2014, 53, 13532-13535                                                                                              
 
79. Conquering Three-Carbon Axial Chirality of Allenes
Juntao Ye and Shengming Ma*
Org. Chem. Front., 2014, 1, 11210-1224                                                                                            
 
80. Preparation of (R)-4-Cyclohexyl-2,3-butadien-1-ol
Juntao Ye and Shengming Ma*
Org. Synth. 2014, 91, 233-247                                                         
 
81. Studies on Palladium-Catalyzed Synthesis of Dihydrocycloocta[b]indoles and Their Thermal Reactivities with Maleimide or Maleic Anhydride
Can Zhu and Shengming Ma*
Adv. Synth. Catal., 2014, 356, 3897-3911                                                                                              
 
82. Unexpected E-stereoselective Reductive A3-coupling Reaction of Terminal Alkynes with Aldehydes and Amines
Wu Fan, Weiming Yuan and Shengming Ma*
Nat. Commun. 5: 3884 doi: 10.1038/ncomms4884 (2014)                                                                 
 
83. Efficient Synthesis of 1,2-Bis(alkoxycarbonyl)- pyrazol-3-ones from 2,3-Allenoic Acids,Azodicarboxylates and PPh3
Ruizhi Lu, Xin Cheng, Xingliang Zheng and Shengming Ma*
Chem. Commun., 2014, 50, 1537-1539    
 
84. Direct Carboxylation of Allylic Halides with Carbon Dioxide in the Presence of Indium
Bukeyan Miao and Shengming Ma*
Chem. Commun., 2014, 50, 3285-3287                                                                                         
 
85. Identifying a Non-chiral Ligand for the Efficient Chirality Transfer in Carbonylation ofPropargylic Mesylates
Yuli Wang, Wanli Zhang and Shengming Ma*
Org. Chem. Front., 2014, 1, 807-811                                  
                                                   
86. Studies on Electrophilic Cyclization of N-(Buta-2,3-dienyl)amides with N-Bromosuccinimide and its Applications
Nan Wang, Bo Chen, and Shengming Ma*
Adv. Synth. Catal., 2014, 356, 485-492                                                                                            
 
87. A Practical Synthesis of Chiral Oxazolines through a Highly Diastereoselective Coupling–Cyclization Reaction of N-(Buta-2,3-dienyl)amides and Aryl Iodides
Nan Wang, Bo Chen, and Shengming Ma*
Asian J. Org. Chem., 2014, 3, 723-730  
 
88. Copper(I)-Catalyzed Three-Component Reaction of Terminal Propargyl Alcohols, Aldehydes, and Amines: Synthesis of 3-Amino-2-pyrones and 2,5-Dihydrofurans
Wu Fan and Shengming Ma*
Angew. Chem. Int. Ed., 2014, 53, 13532-13535                                                                                            
 
89. Benzofuran Derivatives from Alkynyl-Substituted Benzynes and Aryl Halides
Weiming Yuan and Shengming Ma*
Org. Lett., 2014, 16, 193-195                                      
 
90. Palladium-Catalyzed Asymmetric Amination of Allenyl Phosphates: Enantioselective Synthesis of Allenes with an Additional Unsaturated Unit
Qiankun Li, Chunling Fu, and Shengming Ma*
Angew. Chem. Int. Ed., 2014, 53, 6511-6514                                                                                  
 
91. Metal Alkoxide Promoted Regio- and Stereoselective C=O and C=C Metathesis of Allenoates with Aldehydes
 Minyan Wang, Zhao Fang, Chunling Fu, and Shengming Ma*
 Angew. Chem. Int. Ed., 2014, 53, 3214-3217 
 
92. Sodium Iodide/tert-Butyl(dimethyl)silyl Chloride-Induced Isomerization of 2,3-Allenols to 2(E)-Enals
Rong Zeng, Zhichao Ma, Chunling Fu,* and Shengming Ma*
Adv. Synth. Catal., 2014, 356, 1343-1358                                                                                       
 
93. Asymmetric Semipinacol Rearrangement of 2,3-Allenols with N-bromo -1,8-naphthalimide
Binjie Guo, Chunling Fu* and Shengming Ma*
Chem. Commun., 2014, 50, 4445-4447                                                                                                   
 
94. Gorlos-Phos for Palladium-Catalyzed Borylation of Aryl Chlorides
Pengbin Li, Chunling Fu, and Shengming Ma*
Org. Biomol. Chem., 2014, 12, 3604–3610                                                                                      
 
95. Regiocontrolled 1,2-Migration in Cyclization of 1-(indol-2-yl)-3-alkyn-1-ols: (Ph3P)Au+ vs. PtCl4
Youai Qiu, Dengke Ma, Wangqing Kong, Chunling Fu, and Shengming Ma*
Org. Chem. Front., 2014, 1, 62–67   
                                   
96. Highly Selective 4-Alkynoic Acids Synthesis via Iron-mediated Complete Inversion of Stereogenic Carbon Centers
Xiaobing Zhang, Youai Qiu, Chunling Fu, and Shengming Ma*
 Org. Chem. Front., 2014, 1, 247–252 
                                      
97. Gram Scale Synthesis of 7-methoxy-O-methylmukonal, Clausine-O, Clausine-K,
Clausine-H, 7-methoxymukonal, and Methyl 2-hydroxy-7-methoxy-9H-carbazole-
3-carboxylate
Dengke Ma, Jianxin Dai, Youai Qiu, Chunling Fu,* and Shengming Ma*
Org. Chem. Front., 2014, 1, 782–791 
 
98. N‑Heterocyclic Carbene-Promoted Annulation Reaction of Allenals with Chalcones: Synthesis of Polysubstituted Pyranyl Aldehydes
Dengke Ma, Youai Qiu, Jianxin Dai, Chunling Fu, and Shengming Ma*
Org. Lett., 2014, 16, 4742−4745   
                                     
99. Studies on [PtCl2]- or [AuCl]-Catalyzed Cyclization of 1-(Indol-2-yl)-2,3-Allenols: The Effects of Water/Steric Hindrance and 1,2-Migration Selectivity
Youai Qiu, Chunling Fu, Xue Zhang,* and Shengming Ma*
Chem. Eur. J., 2014, 20, 10314-10322                                                           
 
100. Electrophilic Cyclizations of Diaryl-2,3-allenyl Ethers with N‑Bromosuccinimide: En Route to 2‑Bromonaphthalenes
Minyan Wang, Jing Li, Chunling Fu,* and Shengming Ma*
Org. Lett., 2014, 16, 4976-4979      
                                    
101. Copper(I) Iodide Mediated Synthesis of Carbohydrate-Based Terminal Allenes by ATA Reaction
Xin Huang,nChunling Fu, Shengming Ma*
Sythesis 2014, 46, 2917-2926                                           
 
102. A General Diversified Synthesis of Carbazoles and the First Synthesis of Karapinchamine A
Youai Qiu, Jing Zhou, Chunling Fu, and Shengming Ma*
Chem. Eur. J., 2014, 20, 14589-14593      
 
103. Highly Regio- and Stereoselective Nitrooxoamination of Mono-substituted Allenes
Can Xue, Chunling Fu* and Shengming Ma*
Chem. Commun., 2014, 50, 15333-15336                                      
 
104. Harmony of CdI2 with CuBr for the One-Pot Synthesis of Optically Active α-allenols
Jiasheng Zhang, Juntao Ye and Shengming Ma*                         
Org. Biomol. Chem., 2015, 13, 4080–4089   
 
105. CuBr2-Catalyzed Enantioselective Routes to Highly Functionalized and Naturally Occurring Allenes
Xinjun Tang, Xin Huang, Tao Cao, Yulin Han, Xingguo Jiang, Weilong Lin,
Yang Tang, Jiasheng Zhang, Qiong Yu, Chunling Fu and Shengming Ma*                                                                      
  Org. Chem. Front., 2015, 2, 688–691  
 
106. Cadmium Iodide Mediated Allenylation of Terminal Alkynes for the Synthesis of Methyl-Substituted Allenes
Xinjun Tang, Yulin Han, and Shengming Ma*
Org. Lett., 2015, 17, 1176−1179                                                                        
 
107. Zinc Diiodide-Promoted Synthesis of Trisubstituted Allenes from Propargylic Amines
 Jinqiang kuang, Xinjun Tang and Shengming Ma*
 Org. Chem. Front., 2015, 2, 470–475      
 
108. Zinc-Mediated Allylation of Carbon Dioxide—the LiOAc Effect
Bukeyan Miao and Shengming Ma*
Org. Chem. Front., 2015, 2, 65–68                                           
 
109. Copper(I)-Catalyzed A3-Coupling Based Reaction of Alkynes, Aldehydes, and   Amines: An Efficient Approach to 2,5-Polysubstituted Dihydrofurans and 2,5-Disubstituted Furans
Wu Fan and Shengming Ma*
Eur. J. Org. Chem., 2015, 3531–3539  
                                                                       
110. An Enantioselective Synthesis of (R)-5,6-Octadecadienoic Acid
Qiong Yu and Shengming Ma*                                  
Eur. J. Org. Chem., 2015, 1596–1601                                                     
 
111. The Renaissance of an Old Problem: Highly Regioselective Carboxylation of 2-Alkynyl Bromides with Carbon Dioxide
Bukeyan Miao, Gen Li, and Shengming Ma*
Chem. Eur. J., 2015, 21, 17224–17228                                                                                   
 
112. General CuBr2-Catalyzed Highly Enantioselective Approach for Optically Active Allenols from Terminal Alkynols
Xin Huang,Tao Cao, Yulin Han, Xingguo Jiang, Weilong Lin, Jiasheng Zhang and
Shengming Ma*
Chem. Commun., 2015, 51, 6956–6959 
 
113. Palladium(0)-Catalyzed Synthesis of Cyclic Glucosides
Xin Huang, Chunling Fu and Shengming Ma*
Org. Biomol. Chem., 2015, 13, 248–251                                                         
 
114. Rhodium-Catalyzed C–H Functionalization-Based Approach to Eight-Membered Lactams
 Shangze Wu, Rong Zeng, Chunling Fu, Yihua Yu, Xue Zhang* and Shengming Ma*
 Chem. Sci., 2015, 6, 2275–2285   
 
115. A C–H Bond Activation-Based Catalytic Approach to Tetrasubstituted Chiral
   Allenes
 Shangze Wu, Xin Huang, Wangteng Wu, Pengbin Li, Chunling Fu and
 Shengming Ma*                            
Nat. Commun.6: 7946 doi: 10.1038/ncomms 8946 (2015).
                                                                  
116. A Concise Construction of Carbohydrate-Tethered Axially Chiral Allenes via
   Copper Catalysis
   Xin Huang, Can Xue, Chunling Fu and Shengming Ma*
   Org. Chem. Front., 2015, 2, 1040–1044 
 
117. Palladium-Catalyzed Triple Cyclization of 2,7-Alkadiynylic Carbonates
   with Allenes Bearing a Carbon Nucleophile
   Xin Huang,Wangteng Wu, Chunling Fu, Yihua Yu, and Shengming Ma*
   Chem. Eur. J., 2015, 21, 15540–15543
 
118. Asymmetric Construction of Six-Membered Rings by Cyclization of Allenes with
   Dinuclear Gold Catalysis                            
Youai Qiu, Jing Zhou, Junzhao Li, Chunling Fu, Yinlong Guo, Haoyang Wang,*
and Shengming Ma*                   
Chem. Eur. J., 2015, 21, 15939–15943 
 
119. Gram Scale Total Synthesis of 2-Hydroxy-3-methylcarbazole, Pyrano[3,2-α]carbazole
    and Prenylcarbazole Alkaloids
Jianxin Dai, Dengke Ma, Chunling Fu* and Shengming Ma*
Eur. J. Org. Chem., 2015, 5655–5662                                                                          
 
120. TfOH-Catalyzed Domino Cycloisomerization/Hydrolytic Defluorination of 2,3-Allenyl Perfluoroalkyl Ketones
Can Xue, Xin Huang, Shangze Wu, Jing Zhou, Jianxin Dai, Chunling Fu and
Shengming Ma*
Chem. Commun., 2015, 51, 17112–17115                                                                   
 
121. Identifying a Highly Active Copper Catalyst for KA2 Reaction of Aromatic Ketones
YujuanCai, Xinjun Tang, Shengming Ma*
Chem. Eur. J. 2016,22, 22662269
 
122. A Practical Solution to StereodefinedTetrasubstituted Olefins
Jianxin Dai, Minyan Wang, Guobi Chai, Chunling Fu, Shengming Ma*
J. Am. Chem. Soc. 2016, 138, 25322535
 
123. Highly Stereo- and RegioselectiveHydrocarboxylation of Diynes withCarbon Dioxide
Tao Cao, Shengming Ma*
Org. Lett.2016, 18, 15101513
 
124. Nickel-catalyzed alkyl-zincation and carboxylationof diynes
Tao Caoa and Shengming Ma*
Org. Chem. Front.2016, 3, 1711–1715.
 
125. Copper-Catalyzed Borylcupration of Allenylsilanes
Weiming Yuan, Liu Song, Shengming Ma*
Angew. Chem. Int. Ed. 2016, 55, 3140 3143
 
126. Iron(III) Chloride-Catalyzed Tandem Aza-Prins/Friedel–CraftsCyclization of 2-Arylethyl-2,3-butadienyl Tosylamides and Aldehydes-An Efficient Synthesis of Benzo[f]isoquinolines
WeilongLin, JiajiaCheng, Shengming Ma*
Adv. Synth. Catal.2016, 358, 1989-1999.
 
127. Controlled TfOH- or AuCl-catalyzed cycloisomerization and tandem hydrolytic 
defluorination of 1,2-allenyl perfluoroalkyl ketones
Can Xue, Xin Huang, Chunling Fu, Shengming Ma*
Org. Chem. Front.2016, 3, 588-597
 
128. Cyclic Anti-Azacarboxylation of 2Alkynylanilines with Carbon Dioxide
Bukeyan Miao, Suhua Li,Gen Li, Shengming Ma*
Org. Lett.2016, 18, 2556−2559
 
129. Iron Catalysis for Room-Temperature Aerobic Oxidation of Alcohols to Carboxylic Acids
Xingguo Jiang, Jiasheng Zhang, Shengming Ma*
J. Am. Chem. Soc. 2016, 138, 83448347,
 
130. Synthesis of Tricyclic Isoquinoline Derivatives via PalladiumCatalyzed Tandem Reactions of 2,7-Alkadiynylic Carbonates with2,3-Allenyl Sulfamides
Xin Huang, Wangteng Wu, Shihua Song, Chunling Fu, Shengming Ma*
Adv. Synth. Catal.2016, 358, 2791 – 2805
 
131. New Approaches to the Synthesis of Metal Carbenes
MinqiangJia, Shengming Ma*
Angew. Chem. Int. Ed. 2016, 55, 9134 –9166
 
132. Palladium-catalysed formation of vicinal all-carbonquaternary centres via propargylation
Xin Huang, Shangze Wu, Wangteng Wu, Pengbin Li, Chunling Fu, Shengming Ma*
NATURE COMMUNICATIONS | 7:12382 | DOI: 10.1038/ncomms12382
 
133. Suzuki coupling for preparation of allenes – ligandeffects and chirality transfer
Hongwen Luo,YihuaYub and Shengming Ma*
Org. Chem. Front.2016, 3, 1705-1710.