General

Zhen LI 

Doctoral Advisor

Lanzhou Institute of Chemical Physics, CAS 

 
Email: zhenli@licp.cas.cn
Telephone: 869314968155 
Mobile phone: 8613919253473 
Address: No.18 Tianshui Middle Road 
Postcode: 730000

Research Areas

Clean catalysis & task-specific ionic liquids catalysts

Education

Ph.D. State Key Laboratory of Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences (2002.7~2005.11)

M.Sc., Physical Chemistry, State Key Laboratory of Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences (1999.9~2001.11)

B.Sc., Applied Chemistry, SiChuan University (1993.9~1997.7)


Experience

Researcher, State Key Laboratory of Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, China (2012.11 ~)

Associate Researcher, State Key Laboratory of Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, China (2005.3 ~2012.10)

Assistant Researcher, State Key Laboratory of Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, China (2001.8 ~ 2005.3)

Assistant Engineer, State Key Laboratory of Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou, China (1997.7 ~ 2001.8)


Work Experience
2012.3~2012.9 Visiting scholar, University of New Brunswick, Canada 


Publications

   
Papers
(1) High-cetane additives for diesel based on polyoxymethylene dimethyl ethers: Density behavior and prediction, Journal of Molecular Liquids, 2017, 第 4 作者
(2) Corrosion Behavior of Metallic Materials in Acidic-Functionalized Ionic Liquids, ACS Sustainable Chem. Eng., 2016, 通讯作者
(3) Silica-Gel-Supported Dual Acidic Ionic Liquids as Efficient Catalysts for the Synthesis of Polyoxymethylene Dimethyl Ethers, Ind. Eng. Chem. Res., 2016, 通讯作者
(4) Acidic-Functionalized Ionic Liquid as Corrosion Inhibitor for 304 Stainless Steel in Aqueous Sulfuric Acid, ACS Sustainable Chemistry & Engineering, 2016, 通讯作者
(5) Functional Ionic Liquids as Efficient and Recyclable Catalysts for the Methylation of Formaldehyde with Aromatics, Catal Lett, 2016, 通讯作者
(6) Solvent-Free Selective Condensations Based on the Formation of the Olefinic (C=C) Bond Catalyzed by Organocatalyst, Catalysts, 2016, 通讯作者
(7) Mechanistic study for the formation of polyoxymethylene dimethyl ethers promoted by sulfonic acid-functionalized ionic liquids, Journal of Molecular Catalysis A: Chemical, 2015, 第 3 作者
(8) Synthesis and Physicochemical Properties of Two SO3H-Functionalized Ionic Liquids with Hydrogen Sulfate Anion, J. Chem. Eng. Data , 2014, 第 3 作者
(9) Metal-Free and Recyclable Route to Synthesize Polysubstituted Olefins via CC Bond Construction from Direct Dehydrative Coupling of Alcohols or Alkenes with Alcohols Catalyzed by Sulfonic Acid-Functionalized Ionic Liquids, Adv. Synth. Catal., 2014, 第 3 作者
(10) Mechanism and origins of enantioselectivity for [BMIM]Cl ionicliquids and ZnCl2co-catalyzed coupling reaction of CO2 with epoxides, Journal of Molecular Catalysis A: Chemical, 2014, 第 3 作者
(11) 甲缩醛合成反应及其动力学研究进展, Advances in synthesis methods and kinetics of methylal, 化工进展, 2014, 第 2 作者
(12) Novel Functional Ionic Liquids as Metal-Free, Efficient and Recyclable Catalysts for the Carbonylation of Formaldehyde, Catalysis Letters, 2014, 第 4 作者
(13) Kinetics and quantum chemical study for cyclotrimerization ofpropanal catalyzed by Br?nsted acidic ionic liquidsWu, Journal of Molecular Catalysis A: Chemical, 2013, 第 2 作者
(14) Sulfonic Acid-Functionalized Ionic Liquids as Metal-Free, Efficient and Reusable Catalysts for Direct Amination of Alcohols, Adv. Synth. Catal., 2012, 第 3 作者
(15) 离子液体的非常规制备技术研究进展, 化工进展, 2012, 第 1 作者
(16) NOVEL ACIDIC IONIC LIQUIDS AS EFFICIENT AND RECYCLABLE CATALYSTS FOR THE CYCLOTRIMERIZATION OF ALDEHYDES, Synthetic Communications, 2012, 通讯作者
(17) 离子液体工业应用研究进展, 化工进展, 2012, 第 1 作者
(18) Bronsted Acidic Ionic Liquids as Efficient and Recyclable Catalysts for the Carbonylation of Formaldehyde, Catalysis Letters, 2012, 通讯作者
(19) 功能化离子液体的催化作用及其应用, Catalysis and applications of task-specific ionic liquids, 中国科学:化学, 2012, 第 1 作者
(20) Acidic-functionalized ionic liquid as an efficient, green and reusable catalyst for hetero-Michael addition of nitrogen, sulfur and oxygen nucleophiles to α,β-unsaturated ketones , Organic and Biomolecular Chemistry , 2012, 第 3 作者
(21) 烷基磺酸酯基功能化离子液体的合成、性质及其在酯化反应中的应用, Alkyl Sulfonate Functionalized Ionic Liquids: Synthesis, Properties, and Their Application in Esterification, CHINESE JOURNAL OF CATALYSIS, 2011, 第 2 作者
(22) Novel guanidinium zwitterion and derived ionic liquids: physicochemical properties and DFT theoretical studies, Structural Chemistry, 2011, 第 3 作者
(23) 离子液体微乳液体系的应用研究, Application studies of ionic liquid based microemulsions, 化学进展, 2011, 通讯作者
(24) 新型磺酸功能化离子液体理化性质的研究, 分子催化, 2011, 通讯作者
(25) Polyoxometalates Based Supported Ionic Liquid Catalysis for Alcohol Oxidation with Hydrogen Peroxide, 分子催化, 2011, 第 3 作者
(26) Pyrrolidine-based Dicationic Acidic Ionic Liquids: Efficient and Recyclable Catalysts for Esterifications, Chin. J. Chem., 2010, 第 3 作者
(27) 基于甲醇清洁转化的碳一化工新催化技术, 化工进展, 2010, 第 1 作者
(28) 基于清洁氧源的金属卟啉配合物仿生催化氧化研究进展, 分子催化, 2010, 第 3 作者
(29) Synthesis, properties and catalysis of novel methyl- or ethyl-sulfate-anion- based acidic ionic liquids, Catalysis Communications, 2009, 第 2 作者
(30) Catalytic amounts of Bronsted acidic ionic liquids promoted esterification: Study of acidity-activity relationship, Catalysis Communications, 2009, 通讯作者
(31) Co-doped Attapulgite Catalyzed Solvent-free Oxidation of Cyclohexane Using Molecular Oxygen, Catalysis Letters, 2009, 第 2 作者
(32) [alpha-PW12O40](3-) immobilized on ionic liquid-modified polymer as a heterogeneous catalyst for alcohol oxidation with hydrogen peroxide, SYNTHETIC COMMUNICATIONS, 2008, 第 2 作者
(33) A magnetically recyclable heterogeneous catalyst: Cobalt nano-oxide supported on hydroxyapatite-encapsulated gamma-Fe2O3 nanocrystallites for highly efficient olefin oxidation with H2O2, Catalysis Communications, 2008, 第 2 作者
(34) 金属卟啉配合物的催化氧化应用研究进展, 有机化学, 2007, 第 1 作者
(35) Highly effective catalysts of natural polymer supported Salophen Mn(III) complexes for aerobic oxidation of cyclohexene, J. Mol. Catal. A :Chem., 2006, 第 3 作者
(36) Insight into the Mechanism of Oxidative Kinetic Resolution of Racemic Secondary Alcohols by Using Manganese(III)(Salen) Complexes as Catalysts, Chem. Eur. J., 2005, 第 1 作者
(37) Highly efficient catalysts of chitosan-Schiff base Co(II) and Pd(II) complexes for aerobic oxidation of cyclohexane in the absence of reductants and solvents, J. Mol. Catal. A :Chem., 2005, 第 2 作者


Patents
( 1 ) Method for preparing polymethoxymethylal, 发明, 2009, 第 5 作者, 专利号: US 7,560,599 B2
( 2 ) 含磺酸酯基侧链室温离子液体及其制备方法和应用, 发明, 2010, 第 2 作者, 专利号: ZL200710305965.1
( 3 ) Process for synthesizing trioxymethylene using ionic liquid, 发明, 2009, 第 5 作者, 专利号: US 7,598,402 B2
( 4 ) 一种烷氧基醚类化合物的制备方法, 发明, 2011, 第 2 作者, 专利号: CN 201110106186.5
( 5 ) A Method for Synthesizing Polyoxymethylene Dimethyl Ether Catalyzed by an Ionic Liquid, 发明, 2011, 第 4 作者, 专利号: US13154359
( 6 ) 一种乙醇酸甲酯的制备方法, 发明, 2011, 第 4 作者, 专利号: CN 201110085387.1
( 7 ) 甲醛与甲醇缩醛化反应制备聚甲氧基二甲醚的工艺过程, 发明, 2010, 第 4 作者, 专利号: CN201010176630.6
( 8 ) A Method for Synthesizing Polyoxymethylene Dimethyl Ether Catalyzed by an Ionic Liquid, 发明, 2011, 第 4 作者, 专利号: GB 1108697.2
( 9 ) A Method for Preparing Polyoxymethylene Dimethyl Ethers by Acetalation Reaction of Formaldehyde with Methanol, 发明, 2011, 第 4 作者, 专利号: US13134677
( 10 ) A Method for Preparing Polyoxymethylene Dimethyl Ethers by Acetalation Reaction of Formaldehyde with Methano, 发明, 2011, 第 4 作者, 专利号: GB 1110391.8
( 11 ) 一种富马酸二甲酯的制备方法, 发明, 2011, 第 1 作者, 专利号: CN 201110106188.4
( 12 ) 一种丙酮缩甘油的制备方法, 发明, 2011, 第 2 作者, 专利号: CN 201110106189.9
( 13 ) 功能化离子液体催化合成胺类化合物的方法, 发明, 2011, 第 4 作者, 专利号: CN 201110327102.0
( 14 ) 一种β-氨基羰基化合物、β-巯基酮、β-烷氧基酮的合成方法, 发明, 2011, 第 4 作者, 专利号: CN 201110327181.5
( 15 ) 离子液体催化合成聚甲氧基二甲醚的工艺过程, 发明, 2010, 第 4 作者, 专利号: CN201010176791.5
( 16 ) Method of synthesizing trioxymethylene from formaldehyde by the catalytic action of an ionic liquid, 发明, 2007, 第 5 作者, 专利号: US 7,244,854 B2
( 17 ) 离子液体催化合成聚甲氧基二甲醚的方法, 发明, 2011, 第 4 作者, 专利号: PCT/CN 2011/072377
( 18 ) 甲醛与甲醇缩醛化反应制备聚甲氧基二甲醚的方法, 发明, 2011, 第 4 作者, 专利号: PCT/CN2011/072420
( 19 ) 烯烃类化合物的合成方法, 发明, 2012, 第 4 作者, 专利号: CN201210146355.2
( 20 ) 一种聚乙二醇功能化多金属氧酸盐离子液体及其制备方法, 发明, 2012, 第 2 作者, 专利号: CN201210340229.0
( 21 ) 一种甘油与甲醛反应合成甘油缩甲醛的方法, 发明, 2013, 第 2 作者, 专利号: ZL 200810183393.9
( 22 ) 一种酸性离子液体催化合成低碳多醚类化合物的方法, 发明, 2013, 第 2 作者, 专利号: CN 201310659995.8
( 23 ) 一种烷氧基醚类化合物的制备方法, 发明, 2014, 第 2 作者, 专利号: CN201110106186.5
( 24 ) 离子液体催化合成聚甲氧基二甲醚的工艺过程, 发明, 2014, 第 4 作者, 专利号: US8816131B2
( 25 ) 一种聚乙二醇功能化多金属氧酸盐离子液体及其制备方法, 发明, 2016, 第 2 作者, 专利号: ZL201210340229.0
( 26 ) Method for preparing polyoxymethylene dimethyl ethers by acetalation reaction of formaldehyde with methanol, 发明, 2015, 第 4 作者, 专利号: US8987521B2
( 27 ) 一种离子液体催化2-甲基呋喃羟烷基化-烷基化反应的方法发明专利申请说明书, 发明, 2016, 第 1 作者, 专利号: ZL201310274053.8


Students

已指导学生

李沛陪  硕士研究生  070304-物理化学  

周剑伟  硕士研究生  070304-物理化学  

孟雅莉  硕士研究生  070304-物理化学  

吴丽  硕士研究生  070304-物理化学  

魏焕梅  硕士研究生  070304-物理化学  

刘文巧  硕士研究生  070304-物理化学  

现指导学生

王国芹  博士研究生  070304-物理化学