基本信息
洪茂椿 男 博导 福建物质结构研究所
电子邮件:hmc@fjirsm.ac.cn
通信地址:中国科学院福建物质结构研究所
邮政编码:350002

研究领域

本课题组成立十多年以来,一直从事合成化学,材料化学和结构与性能关系的研究,合成出上百种新型的化合物,在过渡金属配合物的基元组装、谱学研究、结构分析等方面积累了丰富的经验。近年来在国际一流学术刊物,如 J. Am. Chem. Soc., Angew. Chem., Chem. Commun., Cryst. Growth Des., Inorg. Chem. 等杂志上发表了近三百篇论文。

  课题组成员主要以青年学者组成,学术思想活跃,刻苦耐劳,而且基础扎实。自一九九六年以来,课题组开始从事无机超分子聚合物的研究,在含硫氮配体银超分子聚合物的研究中取得了突出的成绩,已成功地合成和表征了上百个超分子聚合物。同时还成功地建立了自组装和模板引导合成法,得到了不同构型的超分子聚合物等。另外,课题组在非心对称配位聚合物的合成和非线性光学性能研究中进行了成功的尝试,初步建立了合成方法,已合成了一类非心对称并具有共轭作用的有机配体,进行了超分子聚合物组装合成的预研究,取得了非常满意的结果。近来将设计合成思想引入到纳米(尺度)分子化合物的制备中,设计合成一系列具有纳米笼、纳米球、纳米孔、纳米隧道、纳米棒、纳米线结构的化合物,研究其合成、结构及其与性能的关系规律,同时通过引入不同配体、不同的合成方法和条件来达到对纳米分子化合物的结构和性能进行修饰的目的,为实现这些纳米分子化合物的结构调控奠定坚实的基础,并在其应用性能特别是在光电性能的探索研究中取得一定的突破。

  课题组具有合成所需的合成条件、光学、磁性、电导等性能研究等研究设备及系统完整的结构分析和绘图等软件,可以独立完成晶体结构解析工作。可以使用大型公共仪器设备,如X-射线单晶衍射仪、时间分辨荧光光谱仪、高分辨率透射电镜、高分辨率电镜、电与磁性能测定仪、红外、拉曼、紫外、核磁共振。

招生方向

无机功能材料
纳米材料
配位聚合物
无机-有机杂化材料的制备、结构与性能的关系和应用研究
新材料与器件研究

导师简介

洪茂椿 男,博士,研究员,中国科学院院士,亚太材料科学院院士,第三世界科学院院士。《Crystal Growth & Design》,《结构化学》和《波谱学》杂志副主编,《Inorg. Chem. Commun.》,《Inorg. Chim. Acta》,《J. Mol. Struct.》,《中国科学B版》和《化学进展》等杂志编委。

现任中共福建省委委员,中国科学院福建物质结构研究所所长,党委书记,所学术委员会副主任,国家光电子材料工程技术研究中心主任,国家纳米评估中心副主任,国家纳米中心学术委员,国家自然科学基金委无机化学学科评审组组长,国家纳米重大研究计划专家组成员。1978年毕业于福州大学化学系,1981年获中国科学院福建物质结构研究所硕士学位。1985年-1987年在美国密执安大学化学系和伊利诺依大学化学系做访问学者,1992年-1993年在英国纽卡斯尔大学化学系做访问学者,1996-1998年曾两度在日本名古屋大学化学系做JSPS访问教授并获得博士学位。主要从事新材料与器件、无机功能材料、纳米材料、无机-有机杂化材料的制备、结构与性能的关系和应用研究。1998年开始主持国家自然科学基金重大项目课题,同年获国家自然科学杰出青年基金资助。目前正在开展国家自然科学基金重点“金属-有机纳米分子与功能材料”、国家科技攻关“光功能纳米陶瓷材料”和福建省重大专项“新材料与器件”等项目研究。1993年获得国务院政府特殊津贴,1994年获得物理学会首届王天眷波谱学奖,2001年获人事部和中科院先进工作者称号,2002年度被评为中科院优秀研究生导师和被福建省人民政府授予优秀专家,2003年获福建省先进工作者称号,2004年被福建省评为优秀科技工作者,2004年获福建省杰出科技人才奖,2005年当选第三世界科学院院士,2006年获全国杰出专业技术人才奖和福建省科技特别贡献奖。发表论文近三百篇,申请专利8项。

 

专利与奖励

2011年 获“十一五”国家科技计划执行突出贡献奖 (国家科技部)

2010年 获何梁何利基金科学与技术进步奖化学奖

2010年 获“全国优秀科技工作者 称号

2009年 获“朱李月华优秀教师奖”

2007年 获福建省科学技术一等奖

2006年 入选“福建经济年度杰出人物”

2006年 荣膺“全国杰出专业技术人才”荣誉称号

2006年 荣获“福建省科学技术大会特别奖”

2004年 被福建省评为优秀科技工作者,获福建省杰出科技人才奖。

2003年 获福建省先进工作者称号

2002年 评为中科院优秀研究生导师,福建省政府授予优秀专家

2001年 中国科学院自然科学奖一等奖,并获中科院先进工作者称号


出版专著

1. 洪茂椿, 陈莲, Metal-Organic Frameworks Based on Lanthanide Clusters” -Lanthanide Metal-Organic Frameworks; Struct. Bond. (2015) 163, 145-184。  

2. 洪茂椿, 陈莲, 《氧基簇合物化学》(2012) 50-68 科学出版社, 第二章“钒氧簇的非水介质合成”

3. 洪茂椿, 陈莲, Design and Construction of Coordination Polymers 出版于John Wiley &-Sons Inc. (USA), 2009。

4. 洪茂椿, 曹荣, 苏伟平, 吴新涛, Inorganic Chemistry in Focus II, P193-206, Wiley-Vch, 2005

5. 洪茂椿, 陈荣, 梁文平, 21世纪无机化学, 中国科学出版社, 2005

6. 洪茂椿, 曹荣, Inorganic structural Chemistry, 中国科学出版社, 2005


发表论文
   

近年代表论文

1. Jiandong Pang Caiping Liu, Yougui Huang, Mingyan Wu*, Feilong Jiang, Daqiang Yuan*, Falu Hu, Kongzhao Su, Guoliang Liu, Maochun Hong, “Visualizing the Dynamics of Temperature -and Solvent- Responsive Soft Crystals” -Angew. Chem. Int. Ed. (2016) 55, 7478-7482

2. Hui Xue, Qihui Chen* Feilong Jiang,Daqiang Yuan, Guangxun Lv, Linfeng Liang, Luyao Liu, Maochun Hong*“A regenerative metal-organic framework for reversible uptake of Cd(II): from effective adsorption to in situ detection” -Chem. Science (2016) DOI: 10.1039/C6SC00972G

3. Xingjun Li, Xueyuan Chen, Feilong Jiang, Lian Chen, Qihui Chen, Mingyan Wu, Daqiang Yuan, Maochun Hong*“Dynamic Respondence of a Flexible Indium-Organic Framework upon Gas Sorption” -Chem. Commun. (2016) 52, 2277-2280

4. Lian Chen, Qihui Chen, Mingyan Wu, Feilong Jiang, Maochun Hong* “Construction and Evolution of Nanosized Metallocages: Recent Advances” -Accoun. Chem. Res. (2015) 48, 201- 210

5. Jiandong Pang, Feilong Jiang, Mingyan Wu*, Caiping Liu, Kongzhao Su, Weigang Lu, Daqiang Yuan*, Maochun Hong, “A porous metal-organic framework with ultra-high acetylene uptake capacity under ambient condition” -Nature Commun. (2015) 6, 7575

6. Hui Xue, Feilong Jiang, Qihui Chen*, Haiying Wang, Jie Pan, Kongzhao Su, Jinjie Qian, Jiandong Pang, Guangxun Lv, Linfeng Liang, Maochun Hong* “Conformation driven in situ interlock: from discrete metallocycles to infinite polycatenane” -Chem. Commun. (2015) 51,13706-13709

7. Yan Yang, Feilong Jiang, Lian Chen*, Jiandong Pang, Mingyan Wu, Xiuyan Wan, Jie Pan, Kongzhao Su, Maochun Hong*“An unusual bifunctional Tb-MOF for highly sensing of Ba2+ions and remarkable selectivity of CO2/N2 and CO2/CH4” -J. Mater Chem. A (2015) 3, 13526-13532

8. Xiuyan Wan, Feilong Jiang, Caiping Liu, Kang Zhou, Lian Chen*,Yanli Gai, Yan Yang, Maochun Hong*“Rapid and Discriminative Detection of Nitro Aromatic Compounds with High Sensitivity by Two Zinc MOFs Synthesized through Temperature-Modulated Method” -J. Mater Chem. A (2015) 3, 22369-22376

9. Jiandong Pang, Feilong Jiang, Daqiang Yuan, Jun Zheng, Mingyan Wu*, Guoliang Liu, Kongzhao Su, Maochun Hong*“Encapsulating SO42- Anions into Hexagonal-Prismatic Cages via Cooperative C-H···O Hydrogen Bonds” -Chem. Science (2014) 5, 4163–4166 封面

10. Linjie Zhang, Zixue Su, Wenmu Li, Feilong Jiang, Youfu Zhou, Linlin Yang, Jinjie Qian, Maochun Hong* “Highly Graphitized Nitrogen-Doped Porous Carbon Nanopolyhedrons Derived from ZIF-8 Nanocolloids as Efficient Electrocatalysts for Oxygen Reduction Reactions” -Nano Scale, (2014) 6, 6590-6602

11. Jinjie Qian, Feilong Jiang, Kongzhao Su, Jie Pan, Zhenzhen Xue, Partha Pratim Bag, Maochun Hong* “Heterometallic cluster-based indium-organic framework” -Chem. Commun. (2014) 50, 15224-15227

Qihui Chen, Feilong Jiang, Daqiang Yuan, Guangxun Lyn, Lian Chen, Maochun Hong* “A controllable and dynamic assembly system based on discrete metallocages” -Chem. Science (2014) 5, 483-488 封面

12. Mingyan Wu, Feilong Jiang, Daqiang Yuan, Jiandong Pang, Jinjie Qian, Shaeel A. AL-Thabaiti, Maochun Hong* “Polymeric double-anion templated Er48 nano-tubes” -Chem. Commun. (2014) 50, 1113 -1115

13. Jinjie Qian, Feilong Jiang, Linjie Zhang, Kongzhao Su, Jie Pan, Qipeng Li, Daqiang Yuan, Mao-Chun Hong*“Unusual pore structure and sorption behaviour in a hexanodal zinc-organic framework material” -Chem. Commun. (2014) 50, 1678-1681 封面

14. Jiandong Pang, Feilong Jiang, Mingyan Wu*, Daqiang Yuan, Kang Zhou, Jinjie Qian, Kongzhao Su, Maochun Hong*“High H2 and CH4 adsorption capacity of a non-interpenetrated porous MOF based on a bent di-isophthalate ligand” -Chem. Commun. (2014) CC048381 封面

15. Mingyan Wu, Feilong Jiang, Xiangjian Kong, Daqiang Yuan, Lasheng Long, Maochun Hong* “Gd36 Nano-spheres with Large Magnetocaloric Effect” -Chem. Science (2013) 4, 3104-3109

16. Xiaochen Shan, Feilong Jiang, Daqiang Yuan, Huabin Zhang, Mingyan Wu, Lian Chen, Jing Wei, Shuquan Zhang, Jie Pan, Maochun Hong*“A Multi-metal-cluster MOF with Cu4I4 and Cu6S6 as Functional Groups Exhibiting Dual Emission of Thermochromism and NIR” -Chem. Science (2013) 4, 1484-1489

17. Xiao-Chen Shan, Fei-Long Jiang, Hua-bin Zhang, Xiang-Ying Qian, Lian Chen, Ming-Yan Wu, Shaeel A. AL-Thabaiti, Mao-Chun Hong*“A Solid AND Logic Stimuli-responsive Material with Bight Nondestuctive Performance Designed by Sensitive Cuprophilicity”-Chem. Commun. (2013) 49, 10227-10229 封面

18. Qihui Chen, Feilong Jiang, Daqiang Yuan, Lian Chen, Guangxun Lyn, Maochun Hong* “Anion-driven self-assembly of cages and their conversions: From discrete cages to polycatenane step by step” -Chem. Commun. (2013) 49, 719-721

19. Xiao-Chen Shan, Fei-Long Jiang, Lian Chen, Ming-Yan Wu, Jie Pan, Xiu-Yan Wan, Mao-Chun Hong*“Taking cuprophilicity as a multi-responsive chromphore switching colors responsive to temperature, mechanical force and solvent vapors” -J. Mater Chem. C (2013) 1, 4339-4349

20. Jin-Jie Qian, Fei-Long Jiang, Da-Qiang Yuan, Xing-Jun Li, Lin-Jie Zhang, Kong-Zhao Su, Mao-Chun Hong*“Increase in Pore Size and Gas Uptake Capacity in Indium-Organic Framework Materials” -J. Mater Chem. A (2013) 1, 9075-9082

21. Jinjie Qian, Feilong Jiang, Kongzhao Su, Jie Pan, Linjie Zhang, Xingjun Li, Daqiang Yuan, Maochun Hong* “Sorption behaviour in a unique 3,12-connected zinc-organic framework with 2.4 nm cages” -J. Mater Chem. A (2013) 1, 10631-10634

22. Wei Wei*, Wanlong Li, Zhongfeng Li, Weiping Su, Maochun Hong*“A Molecular “Storage Tank”: Stabilization and Controlled Release of Reactive Molecules by Interdigitated van der Waals Capsules” -Chem. Eur. J. (2013) 19, 469-473

23. Kecai Xiong, Feilong Jiang, Yanli Gai, Daqiang Yuan, Lian Chen Kongzhao Su, Maochun Hong*“Truncated octahedral coordination cage incorporating six tetranuclear-metal building blocks and twelve linear edges” -Chem. Science (2012) 3, 2321-2325

24. Kecai Xiong, Xingyi Wang, Feilong Jiang, Yanli Gai, Wentao Xu, Kongzhao Su, Xunjun Li, Daqiang Yuan, Maochun Hong* “Heterometallic thiacalix[4]arene-supported Na2NiII12LnIII2 clusters with vertex-fused tricubane cores (Ln = Dy and Tb)” -Chem. Commun. (2012) 48, 7456 -7458

25. Jin-Jie Qian, Fei-Long Jiang, Da-Qiang Yuan, Ming-Yan Wu, Shu-Quan Zhang, Lin-Jie Zhang, Mao-Chun Hong* “Highly selective carbon dioxide adsorption in a water-stable indium-organic framework material” -Chem. Commun. (2012) 48, 9696-9698 封面

26. Kang Zhou, Fei-Long Jiang, Lian Chen, Ming-Yan Wu, Shu-Quan Zhang, Jie Ma, Mao-Chun Hong* “Unprecedented three-level hierarchical entangled assembly of a coordination polymer” -Chem. Commun. (2012) 48, 12168-12170 封面

27. Zixue Su, Wuzong Zhou*, Feilong Jiang, Maochun Hong*“The role of localized dielectric breakdown in the growth of anodic TiO2 nanotubes” -J. Mater. Chem. (2012) 22, 535-544

28. Ke-Cai Xiong, Fei-Long Jiang, Yan-Li Gai, Da-Qiang Yuan, Dong Han, Jie Ma, Shu-Quan Zhang, Mao-Chun Hong* “Chlorine Induced Assembly of Cationic Coordination Cage with m5-Carbonato Bridged MnII24 Core” -Chem. Eur. J. (2012) 18, 5536-5540

29. Qihui Chen, Feilong Jiang, Lian Chen, Ming Yang, Maochun Hong*”Solvent and temperature controlled in situ ligand reactions mediated by cooper (II) and 3′-[(E)-{[(1S,2S)-2-aminocy clohexyl] imino}methyl] -4′-hydroxy-4-biphenylcarboxlic acid” -Chem. Eur. J. (2012) 18, 9117- 9124

30. Ning Li, Feilong Jiang, Lian Chen, Xingjun Li, Maochun Hong* “From discrete truncated octahedron nano-cages to 1D coordination polymer:Coordination-driven a single-crystal-to -single-crystal transformation via anion exchange” -Chem. Commun. (2011) 2327-2329

31. Dong Han, Fei-Long Jiang, Ming-Yan Wu, Lian Chen, Qi-Hui Chen, Mao-Chun Hong* “A Non-interpenetrated Porous Metal-Organic Framework with High Gas-Uptake Capacity: Steric Hindrance Effect of Axial N-donor Ligands” -Chem. Commun. (2011) 47, 9861-9863

32. Wei Wei, Mingyan Wu, Yougui Huang, Qiang Gao, Qingfu Zhang, Feilong Jiang, Maochun Hong*“Predesigned Disilver(I) Macrocycles with Additional Binding Sites: New Building Blocks for Coordination Polymers and Solvent-Controlled Conformational Transformation” -Chem. Eur. J. (2011) 17, 2189-2198

33. Yougui Huang, Feilong Jiang, Maochun Hong* “Magnetic Lanthanide–Transition–Metal Organic -Inorganic Hybrid Materials: from Discrete Clusters to Extended Frameworks” -Coord. Chem. Rev. (2009) 253, 2814-2834

34. Kecai Xiong, Mingyan Wu, Qingfu Zhang, Wei Wei, Ming Yang, Feilong Jiang*, Maochun Hong* “1D Infinite Silver(I) Chains Reside in the Big Cavities buit by the Novel p-Sulfonatocalix [4]are-Trisilver Blochs” -Chem. Commun. (2009) 1840-1842

35. Rui Feng, Feilong Jiang, Lian Chen, Chufeng Yan, Minyan Wu, Maochun Hong* “A luminescent homochiral 3D Cd(II) framework with a threefold interpenetrating uniform net 86” -Chem. Commun. (2009) 5296-5298

36. You-Gui Huang, Xiu-Teng Wang, Mao-Chun Hong*Song Gao* Ming-Yan Wu, Qiang Gao, Wei Wei and Fei-Long Jiang“Cobalt-Lanthanide Coordination Polymers Constructed with Metalloligands: A Ferromagnetic Coupled Quasi-1D Dy3+ Chain Showing Slow Relaxation”-Chem. Eur. J. (2008) 14, 10340-10347

37. Youfu Zhou, Maochun Hong* and Xintao Wu, Lanthanide-Transition Metal Coordination Polymers Based on Multiple N- and O-donor Ligands, -Chem. Comm. 2006, 135-143.

38. Lian Chen, Feilong Jiang, Zhengzhong Lin, Youfu Zhou, Chengyang Yue and Maochun Hong,* A Basket Tetradecavandate Cluster with Blue Luminescence, -J. Am. Chem. Soc., 2005, 127, 8588 -8589.

39. You-Fu Zhou, Fei-Long Jiang, Da-Qiang Yuan, Ben-Lai Wu, Rui-Hu Wang, Zheng-Zhong Lin, Mao-Chun Hong,* Copper Complex Cation Templated Gadolinium(III)-Isophthalate Frameworks, -Angew. Chem. Int. Ed., 2004, 43, 5665-5668.

40. Lei Han, Mao-Chun Hong,* Rui-Hu Wang,Ben-Lai Wu,Ying Xu,Ben-Yong Lou, Zheng-Zhong Lin, Red luminescent polymeric cuprous organosulfide generated by solvothermal redox reaction, -Chem. Commun. 2004, 2578-2579.

41. Lei Han, Maochun Hong,* Ruihu Wang, Junhua Luo, Zhengzhong Lin and Daqiang Yuan A novel nonlinear optically active tubular coordination network based on two distinct homo-chiral helices, -Chem. Commun., 2003, 2580-2581.

42. Ruihu Wang, Maochun Hong, Junhua Luo, Rong Cao, Jiabao Weng, A new type of three-dimensional framework constructed from dodecanuclear cadmium(II) macrocycles, -Chem. Commun., 2003, 1018-1019.

43. Yingjun Zhao, Maochun Hong,* Yucang Liang, Rong Cao, Wenjie Li, Jiabao Weng, Shaofang Lu, A Paramagnetic Lamellar Polymer with a high Semiconducty, -Chem. Commun. 2001, 1020-1021.

44. Weiping Su, Maochun Hong, Jiabao Weng, Rong Cao, Shaofang Lu, A Semiconducting Lamella Polymer [{Ag(C5H4NS)}n] with a Graphite-Like Array of Silver(I) Ions and Its Analogue with a Layered Structure, -Angew. Chem. Int. Ed., 2000, 39, 2911-2914.

45. Yucang Liang, Rong Cao, Weiping Su, Maochun Hong, and Wenjian Zhang, Syntheses, Structures and Magnetic Properties of Two Gadolinium(III)-Copper(II) Coordination Polymers by a Hydrothermal Reaction, -Angew. Chem. Int. Ed., 2000, 39, 3304-3307.

46. Maochun Hong, Yingjun Zhao, Weiping Su, Rong Cao, Makoto Fujita, Zhongyuan Zhou,Albert S. C. Chan, A Silver(I) Coordination Polymer Chain Containing Nanosized Tubes with Anionic and Solvent Molecule Guests, -Angew. Chem. Int. Ed., 2000, 39, 2468-2470.

47. Maochun Hong, Yingjun Zhao, Weiping Su, Rong Cao, Makoto Fujita, Zhongyuan Zhou,Albert S. C. Chan,A Nanometer-Sized Metallosupramolecular Cube with Oh Symmetry, -J. Am. Chem. Soc., 2000, 122, 4819-4820.


指导学生

已指导学生

林郑忠  博士研究生  070304-物理化学(含:化学物理)  

许莹  博士研究生  070304-物理化学(含:化学物理)  

罗军华  博士研究生  070304-物理化学(含:化学物理)  

许颜清  博士研究生  070301-无机化学  

韩磊  博士研究生  070304-物理化学(含:化学物理)  

陈莲  博士研究生  070301-无机化学  

王瑞虎  博士研究生  070304-物理化学(含:化学物理)  

范乐庆  博士研究生  070304-物理化学(含:化学物理)  

娄本勇  博士研究生  070304-物理化学(含:化学物理)  

吴本来   博士研究生  070304-物理化学(含:化学物理)  

陈白泉  博士研究生  070304-物理化学(含:化学物理)  

袁大强  博士研究生  070304-物理化学(含:化学物理)  

张静  博士研究生  070301-无机化学  

吴明燕  博士研究生  070301-无机化学  

赵颖隽  博士研究生  070304-物理化学(含:化学物理)  

弓亚琼  博士研究生  070301-无机化学  

周有福  博士研究生  070304-物理化学(含:化学物理)  

翁家宝  博士研究生  070304-物理化学(含:化学物理)  

司友涛  博士研究生  070304-物理化学(含:化学物理)  

黄有桂  博士研究生  070301-无机化学  

岳呈阳  博士研究生  070304-物理化学(含:化学物理)  

连芬燕  博士研究生  070301-无机化学  

高强  博士研究生  070304-物理化学(含:化学物理)  

王梅  博士研究生  070301-无机化学  

张庆富  博士研究生  070301-无机化学  

魏玮  博士研究生  070304-物理化学(含∶化学物理)  

熊克才  硕士研究生  070301-无机化学  

闫春凤  博士研究生  070301-无机化学  

李宁  博士研究生  070301-无机化学  

冯蕊  博士研究生  070301-无机化学  

杨明  博士研究生  070301-无机化学  

现指导学生

许文涛  博士研究生  070301-无机化学  

周康  硕士研究生  070301-无机化学  

张林杰  硕士研究生  070304-物理化学  

韩东  博士研究生  070301-无机化学  

熊克才  博士研究生  070304-物理化学  

张书泉  博士研究生  070301-无机化学  

钱金杰  硕士研究生  070303-有机化学  

苏孔钊  硕士研究生  070303-有机化学  

卜洋  博士研究生  070301-无机化学  

李幸俊  博士研究生  070301-无机化学  

吕广勋  硕士研究生  070301-无机化学  

庞建东  硕士研究生  070301-无机化学  

王坤  硕士研究生  070301-无机化学