General

李志宝 男 汉族 博导 过程工程研究所
Email: zhibaoli@ipe.ac.cn
Telephone: 010-62551557
Address: 北京市海淀区中关村北二条1号
Postcode: 100190

Research Areas

 Specilalized in solid mineral and of Saline Lakes’ Brinesthe group makes efforts to apply the prnciples of precipitation-cryalline-separatation and advanced teniques to the explotation and utilization.The goal is to expolit the new process of energy-saving and ejection-decreasing to ensure the comprehensive utilization of solid and loqid and satisfy our country' strategy development.

Since the foundation,the group has been sponsored by the One Hundred Talents Program of Chinese Academy of Sciencesthe 973 Program (National High-Tech R&D Program),Qinghaikey scientific and technological projectJiangsu Jingshen Salt companyQinghai science&technology department.So far the group has built an inclusive labpurchased and installed the research equipment for material fabrication, property characterization,which provide significant convinence to research


Experience

   
Work Experimence
 Nov., 2006 – present, Institute of Process Eng., CAS, Beijing, Professor, Research and education  Aug., 2004 – 2006, McGill University, Montreal, Postdoctoral Fellow (Supervisor: Prof. Demopoulos), Research  May, 1999 – Jan., 2001, University of Ottawa, Ottawa, Research Associate, Research  July, 1987-Feb., 1994, Nanjing Univ. of Tech., Nanjing, Lecturer, Teaching and research

Honors & Distinctions

2011 The bset ten employees of IPE


Publications

   
Papers

[1]    Ziaul Haque Ansari, Zhibao Li. Solubilities and Modeling of Glycine in Mixed NaCl–MgCl2 Solutions in a Highly Concentrated Region. Journal of Chemical & Engineering Data, 2016, 61 (10):3488–3497

[2]    Yan Zhang, Edouard Asselin, Zhibao Li. Solubility measurement and chemical modeling of M MgSO4·7H2O in the Ti(SO4)2–H2SO4–H2O system. Journal of Chemical & Engineering Data, 2016, 61: 2363-2370.

[3]    Yan Zhang, Zhibao Li, Edouard Asselin. Determination and chemical modeling of the solubility of FeSO4·7H2O in the Ti(SO4)2−H2SO4−H2O system. Journal of Chemical Thermodynamics, 2016, 102: 219-227. 102.

[4]    Yan Zhang, Edouard Asselin, Zhibao Li. Laboratory and pilot scale studies of potassium extraction from K-feldspar decomposition with CaCl2 and CaCO3. Journal of Chemical Engineering of Japan, 2016, 49: 111-119. 102.

[5]    Yan Zeng, Zhibao Li, George P. Demopoulos Process for Glycine Production by Antisolvent Crystallization Using Its Phase Equilibria in the Ethylene Glycol–NH4Cl–Water System. Industrial & Engineering Chemistry Research, 2016, 55 (8):2426–2437.

[6]    Lanmu Zeng, Zhibao Li, Xiaolin Wang. Determination and Modeling of MgCl2 Solubility in Methanol, Ethanol, 2-Propanol, and Their Mixtures from 283 to 343 K. Journal of Chemical & Engineering Data, 2016, 61: 797-805.

[7]    Junfeng Wang, Zhibao Li, Ah-Hyung Alissa Park, Camille Petit. Thermodynamic and Kinetic Studies of the MgCl2-NH4Cl-NH3-H2O System for the Production of High Purity MgO from Calcined Low-Grade Magnesite. AIChE Journal 2015, 61(6): 19331946.

[8]    Lanmu Zeng, Zhibao Li. A new process for fuel ethanol dehydration based on modeling the phase equilibria of the anhydrous MgCl2 + ethanol + water system. AIChE Journal 2015, 61(2): 664-676.

[9]    Yan Zeng, Zhibao Li, Edouard Asselin. Modeling Phase Equilibria for the Glycine–NH4Cl–Methanol–Water System and Its Application for the Industrial Monochloroacetic Acid Process. Industrial & Engineering Chemistry Research 2015, 54 (13), 3488–3497.

[10]Yan Zhang, Zhibao Li. Vapor–Liquid Equilibria of the FeSO4–Fe2(SO4)3–H2SO4–H2O System at (30, 60, 90, and 101.3) kPa. Journal of Chemical & Engineering Data 2015, 60 (3): 947954.

[11]Yan Zeng, Zhibao Li, George P. Demopoulos. Phase equilibria for the glycine–methanol–NH4Cl–H2O System. Industrial & Engineering Chemistry Research 2014, 53 (43), 16864–16872.

[12]Geng Li, Yan Zhang, Edouard Asselin, Zhibao Li. Vapor−liquid equilibria for the ZnSO4−H2SO4−H2O and MgSO4−H2SO4−H2O systems at (30, 60, 90, and 101.3) kPa. Journal of Chemical & Engineering Data 2014, 2014, 59 (11): 3449−3460.

[13]Lanmu Zeng, Zhibao Li. Solubility of dicalcium silicate in the NaOH–NaAl(OH)4–Na2CO3solutions: Determination and prediction. Hydrometallurgy 2014, 147148: 127133.

[14]Geng Li, Edouard Asselin, Zhibao Li. Process simulation of sulfuric acid recovery by azeotropic distillation: Vapor–liquid equilibria and thermodynamic modeling. Industrial & Engineering Chemistry Research 2014, 53(29): 1179411804.

[15]Yan Zeng, Yan Zhang, Zhibao Li, George P. Demopoulos. Measurement and chemical modeling of the solubility of Na2SiO3·9H2O and Na2SiO3 in concentrated NaOH solution from 288 to 353 K. Industrial & Engineering Chemistry Research 2014, 53(23): 99499958.

[16]Wencheng Gao, Jiankang Wen, Zhibao Li. Dissolution kinetics of magnesium from calcined serpentine in NH4Cl solution. Industrial & Engineering Chemistry Research 2014, 53(19), 79477955.

[17]Yan Zeng, Zhibao Li, George P. Demopoulos. Determination and modeling of the solubility of Na2SiO3·9H2O in the NaCl–KCl–H2O system. Journal of Chemical & Engineering Data 2014, 59(4): 12641272.

[18]Wencheng Gao, Zhibao Li, Edouard Asselin. Solubility of AlCl3·6H2O in the Fe(II) + Mg + Ca + K + Cl + H2O system and its salting-out crystallization with FeCl2. Industrial & Engineering Chemistry Research 2013, 52: 14282–14290.

[19]Lanmu Zeng, Zhibao Li. Dissolution behavior of aluminum, silicon, and iron of diaspore concentrate in NaOH−NaAl(OH)4 solutions at elevated temperature. Industrial& Engineering Chemistry Research 2013, 52(51): 1842918439.

[20]Dehua Xu, Huiquan Li, Zhibao Li. Determination and modeling of isobaric vapor–liquid equilibria for the methylcarbamate + methyl-N-phenyl carbamate system at different pressures. Journal of Chemical & Engineering Data 2013, 58(11): 31103117.

[21]Wenting Cheng, Zhibao Li, Fangqin Cheng. Solubility of Li2CO3 in Na–K–Li–Cl brines from 20 to 90 °C. Journal of Chemical Thermodynamics 2013, 67: 74–8.

[22]Juanjuan Zhang, He Zhao, Hongbin Cao, Heping Li, Zhibao Li. Removal of Cd2+ from water by Friedel’s salt (FS:3CaO·A12O3·CaCl2·10H2O): Sorption characteristics and mechanisms. Journal of Environmental Sciences 2013, 25(9): 1719–1725.

[23]Wencheng Gao, Zhibao Li. A practical approach to produce Mg-Al spinel based on the modeling of phase equilibria for NH4ClMgCl2AlCl3H2O system. AIChE Journal 2013, 59: 18551867.

[24]Geng Li, Zhibao Li.  Measurement and modeling of vapor–liquid equilibria for the octane + sulfuric acid  + water + ethanol system. Journal of Chemical & Engineering Data 2013, 58(7): 20442050.

[25]Junfeng Wang, Zhibao Li. Measurement and modeling of vapor–liquid equilibria for systems containing alcohols, water, and imidazolium-based phosphate ionic liquids. Journal of Chemical & Engineering Data 2013, 58(6): 16411649.

[26]Geng Li, ZhibaoLi, Edouard Asselin. Determination and modeling of vapor–liquid equilibria for the sulfuricacid + water + butyl acetate + ethanol system. Industrial& Engineering Chemistry Research 2013, 52: 3481−3489.

[27]Feng Liu, Pengge Ning, Hongbin Cao, Zhibao Li, Yi Zhang. Solubilities of NH4VO3 in the NH3NH4+SO42ClH2O system and modeling by the BromleyZemaitis equation. Journal of Chemical & Engineering Data 2013, 58: 13211328.

[28]Ping Tian, Pengge Ning, Hongbin Cao, Zhibao Li. Determination and modeling of solubility for CaSO4·2H2ONH4+ClSO42NO3H2O system. Journal of Chemical & Engineering Data 2012, 57: 36643671.

[29]Daoguang  Wang, Zhibao Li. Gas-liquid reactive crystallization kinetics of hydromagnesite in the MgCl2CO2NH3H2O system: Its potential in CO2 sequestration. Industrial & Engineering Chemistry Research 2012, 51(50), 1629916310.

[30]Lanmu Zeng, Zhibao Li. Solubility and modeling of sodium aluminosilicate in NaOH–NaAl(OH)4 solutions and its application to desilication. Industrial & Engineering Chemistry Research 2012, 51(46): 1519315206.

[31]Geng Li, Zhibao Li. Determination and prediction of vapor–liquid equilibria for a system containing water + butyl acetate + cyclohexane + ethanol. Journal of Chemical & Engineering Data 2012, 57(9): 25432548.

[32]Junfeng Wang, Zhibao Li. Crystallization and agglomeration kinetics of hydromagnesite in the reactive system MgCl2Na2CO3NaOHH2O. Industrial & Engineering Chemistry Research 2012, 51(23): 78747883.

[33]Wencheng Gao, Zhibao Li. Determination and chemical modeling of phase equilibria for the glycineKClNaClH2O system and its application to produce crystals with anticaking characteristics. Industrial & Engineering Chemistry Research 2012, 51(24): 83158325.

[34]Daoguang Wang, Zhibao Li. Chemical modeling of nesquehonite solubility in Li + Na + K + NH4 + Mg + Cl + H2O system with a speciation-based approach. Chinese Journal of Chemical Engineering 2012, 20(2): 267276.

[35]Daoguang Wang, Zhibao Li. Kinetic analysis for crystal growth rate of NH4Cl in the NaClMgCl2H2O system with a thermodynamic approach. AIChE Journal 2012, 58(3): 914924.

[36]Daoguang Wang, Zhibao Li. Study of crystallization kinetics of ammonium carnallite and ammonium chloride in the NH4ClMgCl2H2O system. Industrial & Engineering Chemistry Research 2012, 51(5): 23972406.

[37]Shunping Sun, Junfeng Wang, Zhibao Li. Solubility and self-consistent modeling of aniline hydrochloride in HMgNaCaAlClH2O system at temperature range of 288348 K. Industrial & Engineering Chemistry Research 2012, 51(9): 37833790.

[38]Wencheng Gao, Zhibao Li. Solubility and KSP of Mg4Al2(OH)14·3H2O at the various ionic strengths. Hydrometallurgy 2012, 117118: 3646.

[39]Shunping Sun, Zhibao Li. Experimental measurement and modeling of aniline hydrochloride solubility in water, methanol, ethanol, propan-1-ol, and their mixed systems. Journal of Chemical & Engineering Data 2012, 57(1): 219–226.

[40]Daoguang Wang, Zhibao Li. Modeling solid-liquid equilibrium of NH4ClMgCl2H2O system and its application to recovery of NH4Cl in MgO production. AIChE Journal 2011, 57(6): 15951606.

[41]Jiayu Ma, Zhibao Li, Qinggui Xiao. A new process for Al2O3 production from low-grade diasporic bauxite based on reactive silica dissolution and stabilization in NaOHNaAl(OH)4 media. AIChE Journal 2011, 58(7): 21802191.

[42]Junfeng Wang, Shunping Sun, Zhibao Li. Modeling of solid–liquid equilibrium for the [HAE]Cl–MgCl2–H2O system. Industrial & Engineering Chemistry Research 2011, 50(13): 8314–8322.

[43]Yan Zhang, Zhibao Li. Effects of cooling rate, saturation temperature, and solvent on the metastable zone width of triethanolamine hydrochloride. Industrial & Engineering Chemistry Research 2011, 50(10): 6375–6381.

[44] Jiayu Ma, Kunming Zhai, Zhibao Li. Desilication of synthetic Bayer liquor with calcium sulfate dihydrate: Kinetics and modelling. Hydrometallurgy 2011, 107(12): 4855.

[45] Junfeng Wang, Zhibao Li, Chunxi Li, Zihao Wang. Density prediction of ionic liquids at different temperatures and pressures using a group contribution equation of state based on electrolyte perturbation theory. Industrial & Engineering Chemistry Research 2010, 49(9): 4420–4425.

[46] Junfeng Wang, Daoguang Wang, Zhibao Li, Fan Zhang. Vapor pressure measurement and correlation or prediction for water, 1-Propanol, 2-Propanol, and their binary mixtures with [MMIM][DMP] ionic liquid. Journal of Chemical & Engineering Data 2010, 55(11): 4872–4877.

[47] Wenting Cheng, Zhibao Li. Controlled supersaturation precipitation of hydromagnesite for the MgCl2Na2CO3 system at elevated temperatures: chemical modeling and experiment. Industrial & Engineering Chemistry Research 2010, 49: 19641974.

[48]Jiayu Ma, Zhibao Li. Chemical equilibrium modeling and experimental measurement of solubility for friedel’s salt in the NaOHClNO3H2O systems up to 200 oC. Industrial & Engineering Chemistry Research 2010, 49: 89498958.

[49]  Yan Zhang, Zhibao Li. Solubilities of triethanolamine hydrochloride ionic liquid in aqueous hydrochloric acid solutions with concentrations from (0 to 8.37) mol/kg. Journal of Chemical & Engineering Data 2010, 55: 44344439.

[50] Hongqing Wang, Daoguang Wang, Zhibao Li, George P. Demopoulos. Solubility and scale prevention of gypsum in transportation pipes of well brine with salinities up to 5 M at temperature range of 278 to 298 K. Desalination and Water Treatment 2010, 22: 7886.

[51] Wenting Cheng, Zhibao Li. Nucleation kinetics of nesquehonite (MgCO3·3H2O) in the MgCl2Na2CO3 system. Journal of Crystal Growth  2010, 312: 15631571.

[52] Tiechui Yuan, Junfeng Wang, Zhibao Li. Measurement and modelling of solubility for calcium sulfate dihydrate and calcium hydroxide in NaOH/KOH solutions. Fluid Phase Equilibria 2010, 297: 129137.

[53]Jiayu Ma, Zhibao Li, Yi Zhang, George P. Demopoulos. Desilication of sodium aluminate solution by Friedel’s salt (FS:3CaO·Al2O3·CaCl2·10H2O). Hydrometallurgy 2009, 99(34): 225230.

[54] Wenting Cheng, Zhibao Li. Precipitation of nesquehonite from homogeneous supersaturated solutions. Crystal Research and Technology 2009, 44(9): 937947.

[55] Wenting Cheng, Zhibao Li, George P. Demopoulos. Effects of Temperature on the Preparation of Magnesium Carbonate Hydrates by the Reaction of MgCl2 with Na2CO3 at 273363K. Chinese Journal of Chemical Engineering 2009, 17(4): 661666.

[56]Mei Dong, Zhibao Li, Jianguo Mi, George P. Demopoulos. Solubility and Stability of Nesquehonite (MgCO3·3H2O) in mixed NaCl + MgCl2, NH4Cl + MgCl2, LiCl, and LiCl + MgCl2 Solutions. Journal of Chemical & Engineering Data 2009, 5 (11): 30023007.

[57] Mei Dong, Wenting Cheng, Zhibao Li, George P. Demopoulos. Solubility and stability of nesquehonite (MgCO3×3H2O) in NaCl, KCl, MgCl2, and NH4Cl solutions. Journal of Chemical & Engineering Data 2008, 53: 25862593.

[58]Yong Wang, Zhibao Li, George P. Demopoulos. Controlled precipitation of nesquehonite by the reaction of MgCl2 with (NH4)2CO3 at 303K. Journal of Crystal Growth 2008, 310: 12201227.

[59] George P. Demopoulos, Zhibao Li et al. New technologies for HCl regeneration in chloride hydrometallurgy. ERZMETALL 2008, 61(2): 8998.

[60] Yan Liu, Zhibao Li, Jianguo Mi, Chongli Zhong. Modeling of aqueous electrolyte solutions based on primitive and first-order Mean Spherical Approximation. Industrial & Engineering Chemistry Research 2008, 47: 16951701.

[61]Zhibao Li, George P. Demopoulos.  Speciation-based chemical equilibrium model of CaSO4 solubility in the H + Na + Ca + Mg + Al + Fe(II) + Cl + SO4 + H2O system. Industrial & Engineering Chemistry Research 2007, 46: 63856392.

[62]Zhibao Li, George P. Demopoulos. Model-based construction of calcium sulfate phase-transition diagrams in the HClCaCl2H2O system between 0 and 100 oC. Industrial & Engineering Chemistry Research 2006,  45(13): 45174524.

[63] Zhibao Li, George P. Demopoulos.  Development of an improved chemical model for the estimation of CaSO4 solubilities in the HClCaCl2H2O system up to 100 oC. Industrial & Engineering Chemistry Research 2006, 45(9): 29142922. 

[64] Zhibao Li, George P. Demopoulos.  Effect of NaCl, MgCl2, FeCl2, FeCl3, and AlCl3 on Solubility of CaSO4 Phases in Aqueous HCl or HCl + CaCl2 Solutions at 298 to 353 K. Journal of Chemical & Engineering Data 2006, 51(2): 569576.

[65] Zhibao Li, George P. Demopoulos.  Solubility of CaSO4 phases in aqueous HCl + CaCl2 solutions from 283 K to 353 K. Journal of Chemical and Engineering Data 2005, 50(6): 19711982.

[66] Zhibao Li, Lu, Benjamin C.-Y. Prediction of interfacial tension between an organic solvent and aqueous solutions of mixed-electrolytes. Fluid Phase Equilibria 2002, 200: 239250.

[67] Zhibao Li, Lu, Benjamin C.-Y. On the prediction of surface tension for multicomponent mixtures. Canadian Journal of Chemical Engineering 2001, 79: 402411.

[68] Zhibao Li, Lu, Benjamin C.-Y. A molecular model for representing surface tension for polar liquids. Chemical Engineering Science 2001, 56: 69776987.

[69] Zhibao Li, Lu, Benjamin C.-Y. Surface tension of aqueous electrolyte solutions at high concentrations-representation and prediction. Chemical Engineering Science 2001, 56: 28792888.

[70] Zhibao Li, Lu, Benjamin C.-Y. Excess molar enthalpies of he ternary mixture: 2,2,4-trimethylpentane +cyclohexane + n-octane. Thermochimica Acta 2000, 343: 4348.

[71] Zhibao Li, Yigui Li, Jiufang Lu. Surface tension model for concentrated electrolyte aqueous solutions by Pitzer equation. Industrial & Engineering Chemistry Research 1999, 38: 11331139.

[72] Zhibao Li, Shiquan Shen, Meiren Shi. Prediction of the surface tension of binary and multicomponent liquid mixtures by the UNIFAC group contribution method. Thermochimica Acta 1990, 169: 231238.

[73] Zhibao Li, Jiufang Lu, Yigui Li. A statistical thermodynamic model of vapor-liquid interfacial tension for liquid mixtures at high pressure. Chinese Journal of Chemical Engineering 1998, 6: 257263.

[74]Chunxi, Li, Zhibao Li, Yigui Li. A thermodynamic model for calculating the surface tension of pure liquids and liquid mixtures. Tsinghua Science and Technology 1998, 3: 1029−1034.

[75] Yongqi Hu, Zhibao Li, Jiufang Lu, Yigui Li, Yong Jin. A new model for surface tension of binary and ternary liquid mixtures based on Peng-Robinson equation of state. Chinese Journal of Chemical Engineering 1997, 5: 193199.

 

Patents
[1] 李志宝,曾澜沐. 一种利用二水氯化镁性质制备无水乙醇的方法. 中国专利, 公开号:CN103483149A
[2] 李志宝,张妍,李赓. 一种蛇纹石和/或橄榄石的碱法处理方法. 中国专利,申请号:201410036293.9, 2013
[3] 李志宝,曾艳. 一种利用碳酸氢钠控制过饱和度生产沉淀二氧化硅的方法. 中国专利,申请号: 201310382894.0, 2013.
[4] 李志宝,李赓. 一种稀硫酸浓缩除杂的工艺方法. 中国专利,申请号:201210106955.6, 公布号:CN102633238A, 2012.
[5] 李志宝,张妍. 一种利用蛇纹石制备氧化镁、镍、钴和白炭黑的方法. 中国专利,申请号:201210179818.5, 2012.
[6] 李志宝,张妍. 一种采用Friedel盐或Kuzel盐除去水溶液中有害阴离子的方法. 中国专利,申请号:201210231178.8, 2012.
[7] 李志宝,高文成. 一种以粉煤灰为原料氯化亚铁诱导结晶制备六水氯化铝的方法. 中国专利,申请号:201210237836.4, 2012.
[8] 李志宝,高文成,王均凤. 一种综合利用钾长石生产钾肥和氧化铝的方法. 中国专利,申请号:201010590230.X, 公开号:CN 102531710 A, 2010.
[9] 李志宝,王均凤. 一种通过碳铵循环法经三水碳酸镁生产高纯氧化镁的方法. 中国专利,申请号:201010562109.6, 2010.
[10] 李志宝,王道广. 一种通过制备六水合氯化铵镁复盐回收氯化铵的方法. 中国专利,申请号:201010108996.X, 2010.
[11] 李志宝,孙顺平. 一种建筑材料及利用钛白废硫酸制备半水硫酸钙的方法. 中国专利,申请号:201110085646.0, 2011.
[12] 李志宝,马家玉,王英军. 一种用水滑石除去水溶液中金属离子的方法. 中国专利,申请号:201010239598.1, 2010.
[13] 李志宝,王均凤. 一种制备电解镁用无水氯化镁的方法. 中国专利,申请号:201010108988.5,2010.
[14] 李志宝,王勇. 一种使用连续结晶法制备三水碳酸镁的方法. 中国专利,申请号:201010119370.9, 2010.
[15] 李志宝,马家玉. 一种含硅的铝酸钠溶液深度脱硅的方法. 中国专利,申请号:200910084484.1, 2009. 公开号:CN 101891227 A.
[16] 李志宝,肖清贵. 从低品位一水硬铝石型铝土矿中脱除二氧化硅. 中国专利,申请号:200910081559.1, 2009.
[17] 李志宝,祁宏波,邵平平. 一种利用苦卤与碳酸盐制备氧化镁的方法. 中国专利,申请号:200910076545.X,2009.
[18] 李志宝,张妍. 一种利用氯化盐浸取钼精矿提纯二硫化钼的方法. 中国专利,申请号:200910087262.5,2009.
[19] 李志宝,王道广,程文婷. 以碳酸镁水合物为中间体生产氧化镁并联产氯化铵的方法. 中国专利,申请号:200910091752.2, 2009.
[20] 李志宝,程文婷. 一种以三水碳酸镁为中间体制备氧化镁的方法. 中国专利,申请号:200810114987.4, 2008.
[21] 李志宝,肖清贵. 在硫酸介质中分解氯化铵制备盐酸和硫酸铵的方法. 中国专利,申请号:200810056435.2,2008.
[22] 李志宝,王勇. 一种使用碳酸铵从含氯化镁卤水中制备三水碳酸镁的方法. 中国专利,申请号:200710064243.1, 2007.


Research Interests

1Novel Extraction Flowsheet of Mg/Li from Qinghai Saline Lakes
2
Thermodynamics and Kinetics of Nucleation and Growth of Crystal
3
Chemical Modeling of Complex systems of Saline Lakes
4
Design and optimization of Special Reaction-crystallization Equipments
5
Advances in Crystal Growth Inhibition Technologies

Students

Past Graduates:

程文婷     (PhD)

马家玉     (PhD)

孙顺平     (Masters')

王道广     (PhD)

高文成     (PhD)

李赓         (Masters')

曾艳         (Masters')

曾澜沐      (Masters')

Zia Ansari  (PhD)

张妍          (PhD)

Current:

王乔欣      (PhD Exp.)

张晓娟      (PhD Exp.)

曾祥钊      (Masters' Exp.)