​锕系元素和裂变产物在凝聚相和气相中的配位结构及其与分离效果之间关系的研究，基于光谱和质谱方法的锕系和镧系配位化学研究。

   

070301-无机化学

镧系锕系配位化学

2014-08--2019-06   中国科学院上海应用物理研究所   博士
2010-09--2014-06   兰州大学   学士

研究生

博士

   

2023-01~现在, 中国科学院上海应用物理研究所, 副高级高级工程师
2019-07~2022-12,中国科学院上海应用物理研究所, 工程师

   

[1] 王倩, 陈秀婷. Formation and Structure of Gas-Phase Lanthanide(III) Cyanobenzyne Complex. Journal of the American Society for Mass Spectrometry[J]. 2024, 35(4): 767-774, https://pubs.acs.org/doi/10.1021/jasms.4c00001?ref=PDF.
[2] Xiong, Zhixin, Yang, Meixian, Chen, Xiuting, Gong, Yu. Dual-Ligand Strategy for the Preparation of Gas-Phase Uranyl(VI) Benzyne Complexes from Uranyl(VI) Benzoates. INORGANIC CHEMISTRY[J]. 2023, 62(5): 2266-2272, http://dx.doi.org/10.1021/acs.inorgchem.2c04004.
[3] Yang, Meixian, Xiong, Zhixin, Li, Yangjuan, Chen, Xiuting, Zhou, Wei. Gas-phase formation of Grignard-type organolanthanide (III) ions RLnCl3-: The influences of lanthanide center and hydrocarbyl group. Rapid Communications in Mass Spectrometry[J]. 2023, 37(11): e9512-e9512, https://analyticalsciencejournals.onlinelibrary.wiley.com/doi/epdf/10.1002/rcm.9512.
[4] Chen, Xiuting, Xiong, Zhixin, Yang, Meixian, Gong, Yu. Gas-phase synthesis and structure of thorium benzyne complexes. CHEMICAL COMMUNICATIONS[J]. 2022, 58(50): 7018-7021, http://dx.doi.org/10.1039/d2cc02057b.
[5] Chen, Xiuting, Xiong, Zhixin, Yang, Meixian, Gong, Yu. Discrimination and quantitation of halobenzoic acid positional isomers upon Th(iv) coordination by mass spectrometry. CHEMICAL COMMUNICATIONS[J]. 2022, 58(16): 2658-2661, http://dx.doi.org/10.1039/d1cc06925j.
[6] Xiong, Zhixin, Yang, Meixian, Chen, Xiuting, Gong, Yu. Influence of Metal Coordination on the Gas-Phase Chemistry of the Positional Isomers of Fluorobenzoate Complexes. Journal of The American Society for Mass Spectrometry[J]. 2022, 33: 2181-2190, [7] Xiong, Zhixin, Yang, Meixian, Chen, Xiuting. Investigations of tetramethyl glutaramide ligand in the formation of stable gas-phase tetrapositive complexes with metal tetracations. INTERNATIONAL JOURNAL OF MASS SPECTROMETRY[J]. 2022, 475: http://dx.doi.org/10.1016/j.ijms.2022.116818.
[8] Chen, Xiuting, Xiong, Zhixin, Gong, Yu. HMNTA Complexes of Tetravalent Metal Ions: On the Roles of Carbonyl Oxygen and Amine Nitrogen in the Stabilization of Gas-Phase M(HMNTA)(2)(4+) Complexes. JOURNAL OF THE AMERICAN SOCIETY FOR MASS SPECTROMETRY[J]. 2021, 32(3): 700-706, http://dx.doi.org/10.1021/jasms.0c00420.
[9] Xiong, Zhixin, Chen, Xiuting, Gong, Yu. Mass spectrometric and theoretical study on the formation of uranyl hydride from uranyl carboxylate. PHYSICAL CHEMISTRY CHEMICAL PHYSICS[J]. 2021, 23(36): 20073-20079, http://dx.doi.org/10.1039/d1cp03092b.
[10] Li, Yangjuan, Chen, Xiuting, Gong, Yu. Photoluminescence of LaI3 switched on and off by association and dissociation of non-luminescent tetrahydrofuran. DALTON TRANSACTIONS[J]. 2021, 50(11): 3797-3800, http://dx.doi.org/10.1039/d1dt00162k.
[11] Wang, Chenyang, Chen, Xiuting, Gong, Yu. On the Structures of Thorium Fluoride and Oxyfluoride Anions in Molten FLiBe and FLiNaK. JOURNAL OF PHYSICAL CHEMISTRY B[J]. 2021, 125(6): 1640-1646, http://dx.doi.org/10.1021/acs.jpcb.0c10197.
[12] Xiong, Zhixin, Hu, Jingwen, Chen, Xiuting. Gas-phase structure, bonding, and fragmentation chemistry of the An (IV)-TMPDCAM complexes studied using mass spectrometry and theoretical calculation (An = Th and U). RAPID COMMUNICATIONS IN MASS SPECTROMETRY[J]. 2021, 35(19): http://dx.doi.org/10.1002/rcm.9168.
[13] Chen, Xiuting, Xiong, Zhixin, Andrews, Lester, Gong, Yu. End-On Cyanogen Complexes of Iridium, Palladium, and Platinum. INORGANIC CHEMISTRY[J]. 2020, 59(9): 6489-6495, https://www.webofscience.com/wos/woscc/full-record/WOS:000530668400073.
[14] Wei, Rui, Chen, Xiuting, Gong, Yu. Sulfur Dioxide Complexes of Main-Group Elements: from SO20 to SO2- and SO22- upon Coordination to Aluminum and Silicon Difluorides. INORGANIC CHEMISTRY[J]. 2020, 59(7): 4703-4710, https://www.webofscience.com/wos/woscc/full-record/WOS:000526414400056.
[15] Chen, Xiuting, Xiong, Zhixin, Gong, Yu. Complexation of Ln(3+) with Pyridine-2,6-dicarboxamide: Formation of the 1:2 Complexes in Solution and Gas Phase. INORGANIC CHEMISTRY[J]. 2020, 59(19): 14486-14492, http://dx.doi.org/10.1021/acs.inorgchem.0c02285.
[16] Wang, Chenyang, Chen, Xiuting, Wei, Rui, Gong, Yu. Raman Spectroscopic and Theoretical Study of Scandium Fluoride and Oxyfluoride Anions in Molten FLiNaK. JOURNAL OF PHYSICAL CHEMISTRY B[J]. 2020, 124(30): 6671-6678, https://www.webofscience.com/wos/woscc/full-record/WOS:000558655900020.
[17] Wei, Rui, Chen, Xiuting, Gong, Yu. Sulfur-substituted uranyl stabilized by fluoride ligands: matrix preparation of U(O)(S)F(2)viaoxidation of U(0) by SOF2. CHEMICAL COMMUNICATIONS[J]. 2020, 56(50): 6782-6785, https://www.webofscience.com/wos/woscc/full-record/WOS:000544928700005.
[18] Li, Yangjuan, Chen, Xiuting, Gong, Yu. Synthesis of a dinuclear europium(III) complex through deprotonation and oxygen-atom transfer of trimethylamine N-oxide. DALTON TRANSACTIONS[J]. 2019, 48(46): 17158-17162, [19] Wei, Rui, Chen, Xiuting, Gong, Yu. Side-On OMoF2(eta(2)-SO) and OWF2(eta(2)-SO) Complexes Featuring Peroxo-Like Sulfur Monoxide Ligand. INORGANIC CHEMISTRY[J]. 2019, 58(22): 15652-15658, http://dx.doi.org/10.1021/acs.inorgchem.9b02766.
[20] Fang, Zongtang, Vasiliu, Monica, Chen, Xiuting, Gong, Yu, Andrews, Lester, Dixon, David A. Formation of Cerium and Neodymium Isocyanides in the Reactions of Cyanogen with Ce and Nd Atoms in Argon Matrices. JOURNAL OF PHYSICAL CHEMISTRY A[J]. 2019, 123(38): 8208-8219, http://dx.doi.org/10.1021/acs.jpca.9b06026.
[21] Chen, XT, Gong, Y. Tetrapositive Hafnium-Diamide Complexes in the Gas Phase: Formation, Structure and Reaction. JOURNAL OF THE AMERICAN SOCIETY FOR MASS SPECTROMETRY[J]. 2019, 30(12): 2623-2631, https://www.webofscience.com/wos/woscc/full-record/WOS:000491832400001.
[22] Wei, Rui, Chen, Xiuting, Gong, Yu. End-On Oxygen-Bound Sulfur Monoxide Complex of Titanium Oxyfluoride. INORGANIC CHEMISTRY[J]. 2019, 58(17): 11801-11806, https://www.webofscience.com/wos/woscc/full-record/WOS:000484066500056.
[23] Chen, Xiuting, Li, Qingnuan, Gong, Yu. Coordination Structures of the Uranyl(VI)-Diamide Complexes: A Combined Mass Spectrometric, EXAFS Spectroscopic, and Theoretical Study. INORGANIC CHEMISTRY[J]. 2019, 58(9): 5695-5702, [24] Wei, Rui, Chen, Xiuting, Gong, Yu. Bidentate SO2 Complexes of Zirconium and Hafnium Difluorides with Highly Activated S-O Bonds. JOURNAL OF PHYSICAL CHEMISTRY A[J]. 2019, 123(44): 9567-9572, [25] Wei, Rui, Chen, Xiuting, Gong, Yu. Bidentate Sulfur Dioxide Complexes of Scandium, Yttrium, and Lanthanum Difluorides. INORGANIC CHEMISTRY[J]. 2019, 58(8): 5281-5288, [26] Chen, Xiuting, Li, Qingnuan, Gong, Yu. Formation and Characterization of Zr4+ Stabilized by Neutral Tridentate Ligands in the Gas Phase. JOURNAL OF THE AMERICAN SOCIETY FOR MASS SPECTROMETRY[J]. 2018, 29(12): 2327-2332, https://www.webofscience.com/wos/woscc/full-record/WOS:000450942400006.
[27] Chen, Xiuting, Li, Qingnuan, Andrews, Lester, Gong, Yu. Infrared Spectroscopic and Theoretical Studies of Group 3 Metal Isocyanide Molecules. JOURNAL OF PHYSICAL CHEMISTRY A[J]. 2018, 122(35): 7099-7106, https://www.webofscience.com/wos/woscc/full-record/WOS:000444354800017.
[28] Wei, Rui, Chen, Xiuting, Gong, Yu. Infrared Spectra of the SO2F2- Anion in Solid Argon and Neon. JOURNAL OF PHYSICAL CHEMISTRY A[J]. 2018, 122(38): 7723-7729, https://www.webofscience.com/wos/woscc/full-record/WOS:000446141200018.
[29] Wei, Rui, Chen, Xiuting, Gong, Yu. Infrared Spectra of the SO2F2- Anion in Solid Argon and Neon. JOURNAL OF PHYSICAL CHEMISTRY A[J]. 2018, 122(38): 7723-7729, https://www.webofscience.com/wos/woscc/full-record/WOS:000446141200018.
[30] Chen, Xiuting, Li, Qingnuan, Andrews, Lester, Gong, Yu. Infrared Spectroscopic and Theoretical Studies of Group 3 Metal Isocyanide Molecules. JOURNAL OF PHYSICAL CHEMISTRY A[J]. 2018, 122(35): 7099-7106, https://www.webofscience.com/wos/woscc/full-record/WOS:000444354800017.
[31] Chen, Xiuting, Li, Qingnuan, Gong, Yu. Coordination Structure and Fragmentation Chemistry of the Tripositive Lanthanide-Thio-Diglycolamide Complexes. JOURNAL OF PHYSICAL CHEMISTRY A[J]. 2017, 121(49): 9429-9434, https://www.webofscience.com/wos/woscc/full-record/WOS:000418394000004.
[32] Chen, Xiuting, Li, Qingnuan, Gong, Yu. Formation and Fragmentation Chemistry of Tripositive Ln(TMGA)(3)(3+) Complexes in the Gas Phase. JOURNAL OF THE AMERICAN SOCIETY FOR MASS SPECTROMETRY[J]. 2017, 28(8): 1696-1701, https://www.webofscience.com/wos/woscc/full-record/WOS:000405486200020.
[33] Guo, XiangGuang, Qin, Sen, Chen, Xiuting, Gong, Yu, Sun, Xiaoqi. Postsynthesis Modification of a Metallosalen-Containing Metal-Organic Framework for Selective Th(IV)/Ln(III) Separation. INORGANIC CHEMISTRY[J]. 2017, 56(20): 12357-12361, https://www.webofscience.com/wos/woscc/full-record/WOS:000413279300032.
[34] 陈秀婷, 李晴暖, 龚昱. 质谱在锕系配位化学研究中的应用. 核化学与放射化学[J]. 2017, 39(1): 1-12, http://lib.cqvip.com/Qikan/Article/Detail?id=671799077.
[35] Chen, Xiuting, Li, Qingnuan, Andrews, Lester, Gong, Yu. Matrix Infrared Spectra of Manganese and Iron Isocyanide Complexes. JOURNAL OF PHYSICAL CHEMISTRY A[J]. 2017, 121(46): 8835-8842, https://www.webofscience.com/wos/woscc/full-record/WOS:000416495300011.
[36] Chen, Xiuting, Li, Qingnuan, Gong, Yu, Andrews, Lester, Liebov, Benjamin K, Fang, Zongtang, Dixon, David A. Formation and Characterization of Homoleptic Thorium Isocyanide Complexes. INORGANIC CHEMISTRY[J]. 2017, 56(9): 5060-5068, http://dx.doi.org/10.1021/acs.inorgchem.7b00196.