1. 原位紫外拉曼光谱研究甲醇制烯烃（Methanol -to-olefins, MTO）反应机理

结合复杂气相产物快速分析的瞬态反应研究系统，组建operando 244 nm紫外拉曼光谱，原位跟踪分子筛上甲醇制烯烃反应中活性中间物种和积碳生成与演变，结合同位素切换甄别活性中间体，完善MTO反应机理。

2. 原位谱学研究分子筛表面甲氧基催化作用

利用原位红外光谱、原位近常压XPS能谱和上海光源D-line 06B研究甲醇转化过程中表面甲氧基在甲醇转化、甲醇耦合烃类及甲醇耦合芳烃转化过程中的重要作用，提出甲醇转化及甲醇耦合转化过程中反应机理和目的产物高选择性调控策略。

3. 分子筛酸催化反应中扩散性质动态演变

组建分子扩散反应研究系统，研究MTO反应过程中催化剂扩散行为随反应进程的演变过程，探究扩散性质变化对催化剂活性和选择性的影响，发展基于扩散性质动态演变的催化反应调控机制。

4. 金属分子筛体系催化烷烃和CO₂耦合反应探索

利用上海光源D-line 05U EDXAS分支的同步辐射X射线近边吸收谱，原位研究金属中心在烷烃C-H键活化、CO₂参与的C-H键活化和CO₂活化过程中的价态变化，结合稳态同位素瞬变分析和理论计算，建立金属分子筛体系的催化反应循环，为烷烃和CO₂转化新过程探索和催化剂研发提供理论指导。

   

081705-工业催化

反应机理，原位谱学，反应动力学

2007-09--2015-07   中国科学院大学   博士

研究生

博士

   

2019-07~现在, 中国科学院大连化学物理研究所, 副研究员
2018-01~2019-06,中国科学院大连化学物理研究所, 助理研究员
2015-06~2017-12,中国科学院大连化学物理研究所, 博士后

   

（ 1 ） 一种表层富集碱性分子的分子筛材料、其制备方法及应用, 发明专利, 2020, 第 5 作者, 专利号: CN111115657A

（ 2 ） 一种金属改性SAPO-34分子筛的制备方法, 发明专利, 2020, 第 4 作者, 专利号: CN110902693A

（ 3 ） 一种金属改性SAPO-34分子筛的制备方法及其应用, 发明专利, 2019, 第 4 作者, 专利号: CN110548538A

（ 4 ） 一种媒介体辅助的电化学分解硫化氢的方法, 专利授权, 2019, 第 4 作者, 专利号: CN107815698B

（ 5 ） 一种表面富集金属的分子筛材料、其制备方法及应用, 发明专利, 2019, 第 1 作者, 专利号: CN109794284A

（ 6 ） 一种光电化学分解水的GaN:ZnO光阳极的制备方法, 发明专利, 2018, 第 3 作者, 专利号: CN106319557B

（ 7 ） 一种α‑Fe 2 O 3 的光阳极及其制备方法, 发明专利, 2017, 第 2 作者, 专利号: CN104617355B

（ 8 ） 一种光电催化-化学环反应耦合分解硫化氢的方法, 发明专利, 2016, 第 2 作者, 专利号: CN105648464A

（ 9 ） 光、电催化-化学环反应耦合分解硫化氢制氢和硫的方法, 发明专利, 2016, 第 2 作者, 专利号: CN105603450A

（ 10 ） 一种光、电催化-化学环反应耦合分解硫化氢的方法, 发明专利, 2015, 第 2 作者, 专利号: CN105018958A

（ 11 ） 一种利用甘油制备乙醇醛的方法, 发明专利, 2013, 第 5 作者, 专利号: CN103159601A

   

[1] Zhang Xiaosi, Yang, Miao, Li Wang, Han, Jingfeng, Caiyi Lou, Xu, Shutao, Yanyu Zhang, 吴仁安, Peng Tian, Zhongmin Liu. Recognizing the Minimum Structural Units Driving the Crystallization of SAPO‐34 from a Top‐Down Process. Chem EUR J[J]. 2023, 29(17): e202203886, 
[2] 王林英, 朱大丽, 王娟, 崔文浩, 韩晶峰, 李冰, 樊栋, 田鹏, 刘中民. Embryonic zeolite-assisted synthesis of SSZ-13 with superior efficiency and their excellent catalytic performance. JOURNAL OF MATERIALS CHEMISTRY A[J]. 2021, 9(27): 15238-15245, http://dx.doi.org/10.1039/d1ta01452h.
[3] Zhong, Jiawei, Han, Jingfeng, Wei, Yingxu, Liu, Zhongmin. Catalysts and shape selective catalysis in the methanol-to-olefin (MTO) reaction. JOURNAL OF CATALYSIS. 2021, 396: 23-31, http://dx.doi.org/10.1016/j.jcat.2021.01.027.
[4] Shao, Chenyi, Malik, Anum Shahid, Han, Jingfeng, Li, Deng, Dupuis, Michel, Zong, Xu, Li, Can. Oxygen vacancy engineering with flame heating approach towards enhanced photoelectrochemical water oxidation on WO3 photoanode. NANO ENERGY[J]. 2020, 77: http://dx.doi.org/10.1016/j.nanoen.2020.105190.
[5] Jiao, Yilai, Forster, Luke, Xu, Shaojun, Chen, Huanhao, Han, Jingfeng, Liu, Xuqing, Zhou, Yangtao, Liu, Jinmin, Zhang, Jinsong, Yu, Jihong, DAgostino, Carmine, Fan, Xiaolei. Creation of Al-Enriched Mesoporous ZSM-5 Nanoboxes with High Catalytic Activity: Converting Tetrahedral Extra-Framework Al into Framework Sites by Post Treatment. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2020, 59(44): 19478-19486, https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7687177/.
[6] 黄保坤, 朱琳, 韩晶峰, 欧阳顺利. 拉曼积分球设计及其在气体检测中的应用. 光散射学报[J]. 2020, 32(2): 154-158, http://lib.cqvip.com/Qikan/Article/Detail?id=7102778599.
[7] Han, Jingfeng, Liu, Zhiqiang, Li, Hua, Zhong, Jiawei, Zhang, Wenna, Huang, Jindou, Zheng, Anmin, Wei, Yingxu, Liu, Zhongmin. Simultaneous Evaluation of Reaction and Diffusion over Molecular Sieves for Shape-Selective Catalysis. ACS CATALYSIS[J]. 2020, 10(15): 8727-8735, http://dx.doi.org/10.1021/acscatal.0c02054.
[8] 钟家伟, 韩晶峰, 魏迎旭, 徐舒涛, 孙毯毯, 曾姝, 郭新闻, 宋春山, 刘中民. 修饰SAPO-18分子筛的笼结构以调变甲醇制烯烃反应的产物选择性. 催化学报[J]. 2019, 40(4): 477-485, http://lib.cqvip.com/Qikan/Article/Detail?id=7001384951.
[9] Liu, Na, Li, Chunlin, Xie, Hua, Liu, Yingjia, Liu, Jiannan, Gao, Jing, Han, Jingfeng, Chen, Jian, Wei, Yingxu, Lin, Bingcheng, Liu, Zhongmin. Doping Graphene into Monodispersed Fe3O4 Microspheres with Droplet Microfluidics for Enhanced Electrochemical Performance in Lithium-Ion Batteries. BATTERIES & SUPERCAPS[J]. 2019, 2(1): 49-54, https://www.webofscience.com/wos/woscc/full-record/WOS:000493566700004.
[10] Yan, Nana, Wang, Lei, Liu, Xiaona, Wu, Pengfei, Sun, Tantan, Xu, Shutao, Han, Jingfeng, Guo, Peng, Tian, Peng, Liu, Zhongmin. A novel approach for facilitating the targeted synthesis of silicoaluminophosphates. JOURNAL OF MATERIALS CHEMISTRY A[J]. 2018, 6(47): 24186-24193, http://www.corc.org.cn/handle/1471x/2372954.
[11] Shao, Chenyi, Han, Jingfeng, Liu, Guiji, Wang, Zhiliang, Zhao, Yongle, Zong, Xu, Li, Can. Fabrication of a Robust Tantalum Nitride Photoanode from a Flame-Heating-Derived Compact Oxide Film. CHEMPHOTOCHEM[J]. 2018, 2(3): 249-256, http://dx.doi.org/10.1002/cptc.201700178.
[12] Li, Zheng, Zhang, Fuxiang, Han, Jingfeng, Zhu, Jian, Li, Mingrun, Zhang, Bingqing, Fan, Wenjun, Lu, Junling, Li, Can. Using Pd as a Cocatalyst on GaN-ZnO Solid Solution for Visible-Light-Driven Overall Water Splitting. CATALYSIS LETTERS[J]. 2018, 148(3): 933-939, http://cas-ir.dicp.ac.cn/handle/321008/168936.
[13] Zhong Jiawei, Han Jingfeng, Wei Yingxu, Xu Shutao, Sun Tantan, Guo Xinwen, Song Chunshan, Liu Zhongmin. 通过SAPO-34分子筛笼中引入金属物种提升甲醇制烯烃反应中乙烯选择性. 催化学报[J]. 2018, 39(11): 1821-1831, http://lib.cqvip.com/Qikan/Article/Detail?id=7000787612.
[14] 钟家伟, 韩晶峰, 魏迎旭, 徐舒涛, 孙毯毯, 郭新闻, 宋春山, 刘中民. 通过SAPO-34分子筛笼中引入金属物种提升甲醇制烯烃反应中乙烯选择性. 催化学报[J]. 2018, 39(11): 1821-1831, http://lib.cqvip.com/Qikan/Article/Detail?id=7000787612.
[15] Wang, Zhiliang, Zong, Xu, Gao, Yuying, Han, Jingfeng, Xu, Zhiqiang, Li, Zheng, Ding, Chunmei, Wang, Shengyang, Li, Can. Promoting Charge Separation and Injection by Optimizing the Interfaces of GaN:ZnO Photoanode for Efficient Solar Water Oxidation. ACS APPLIED MATERIALS & INTERFACES[J]. 2017, 9(36): 30696-30702, http://cas-ir.dicp.ac.cn/handle/321008/150155.
[16] Xu, Shutao, Zhi, Yuchun, Han, Jingfeng, Zhang, Wenna, Wu, Xinqiang, Sun, Tantan, Wei, Yingxu, Liu, Zhongmin, Song, C. Advances in Catalysis for Methanol-to-Olefins Conversion. ADVANCES IN CATALYSIS, VOL 61. 2017, 61: 37-122, https://www.webofscience.com/wos/woscc/full-record/WOS:000432515600003.
[17] Yao, Tingting, Chen, Ruotian, Li, Junjie, Han, Jingfeng, Qin, Wei, Wang, Hong, Shi, Jingying, Fan, Fengtao, Li, Can. Manipulating the Interfacial Energetics of n-type Silicon Photoanode for Efficient Water Oxidation. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY[J]. 2016, 138(41): 13664-13672, http://cas-ir.dicp.ac.cn/handle/321008/169982.
[18] Ma, Weiguang, Han, Jingfeng, Yu, Wei, Yang, Dong, Wang, Hong, Zong, Xu, Li, Can. Integrating Perovskite Photovoltaics and Noble-Metal-Free Catalysts toward Efficient Solar Energy Conversion and H2S Splitting. ACS CATALYSIS[J]. 2016, 6(9): 6198-6206, http://cas-ir.dicp.ac.cn/handle/321008/168300.
[19] Wang, Zhiliang, Han, Jingfeng, Li, Zheng, Li, Mingrun, Wang, Hong, Zong, Xu, Li, Can. Moisture-Assisted Preparation of Compact GaN:ZnO Photoanode Toward Efficient Photoelectrochemical Water Oxidation. ADVANCED ENERGY MATERIALS[J]. 2016, 6(20): https://www.doi.org/10.1002/aenm.201600864.
[20] Han, Jingfeng, Zong, Xu, Zhou, Xin, Li, Can. Cu2O/CuO photocathode with improved stability for photoelectrochemical water reduction. RSC ADVANCES[J]. 2015, 5(14): 10790-10794, http://cas-ir.dicp.ac.cn/handle/321008/147875.
[21] Zhao, Dan, Han, JingFeng, Cui, JunYan, Zong, Xu, Li, Can. A new Pb(IV)-based photocathode material Sr2PbO4 with good light harvesting ability. JOURNAL OF MATERIALS CHEMISTRY A[J]. 2015, 3(22): 12051-12058, http://cas-ir.dicp.ac.cn/handle/321008/146301.
[22] Yan, Pengli, Wang, Xiang, Zheng, Xiaojia, Li, Rengui, Han, Jingfeng, Shi, Jingying, Li, Ailong, Gan, Yang, Li, Can. Photovoltaic device based on TiO2 rutile/anatase phase junctions fabricated in coaxial nanorod arrays. NANO ENERGY[J]. 2015, 15: 406-412, http://dx.doi.org/10.1016/j.nanoen.2015.05.005.
[23] Zong, Xu, Han, Jingfeng, Seger, Brian, Chen, Hongjun, Lu, Gaoqing Max, Li, Can, Wang, Lianzhou. An Integrated Photoelectrochemical-Chemical Loop for Solar-Driven Overall Splitting of Hydrogen Sulfide**. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2014, 53(17): 4399-4403, http://cas-ir.dicp.ac.cn/handle/321008/145681.
[24] Huang, Lei, Li, Rengui, Chong, Ruifeng, Liu, Gang, Han, Jingfeng, Li, Can. Cl- making overall water splitting possible on TiO2-based photocatalysts. CATALYSIS SCIENCE & TECHNOLOGY[J]. 2014, 4(9): 2913-2918, http://cas-ir.dicp.ac.cn/handle/321008/145899.
[25] Liu, Guiji, Shi, Jingying, Zhang, Fuxiang, Chen, Zheng, Han, Jingfeng, Ding, Chunmei, Chen, Shanshan, Wang, Zhiliang, Han, Hongxian, Li, Can. A Tantalum Nitride Photoanode Modified with a Hole-Storage Layer for Highly Stable Solar Water Splitting. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION[J]. 2014, 53(28): 7295-7299, http://cas-ir.dicp.ac.cn/handle/321008/145745.
[26] Han, Jingfeng, Zong, Xu, Wang, Zhiliang, Li, Can. A hematite photoanode with gradient structure shows an unprecedentedly low onset potential for photoelectrochemical water oxidation. PHYSICAL CHEMISTRY CHEMICAL PHYSICS[J]. 2014, 16(43): 23544-23548, http://159.226.238.44/handle/321008/143195.
[27] 黄垒, 李仁贵, 种瑞峰, 刘刚, 韩晶峰, 李灿. Cl−making overall water splitting possible on TiO2-based photocatalysts. CATALYSIS SCIENCE & TECHNOLOGY[J]. 2014, 4(1): 2913, http://cas-ir.dicp.ac.cn/handle/321008/144221.
[28] 韩晶峰, 宗旭, 王志亮, 李灿. Hematite photoanode with gradient structure shows an unprecedentedly low onset potential for photoelectrochemical water oxidation. PHYSICAL CHEMISTRY CHEMICAL PHYSICS[J]. 2014, 16(1): 23544, http://cas-ir.dicp.ac.cn/handle/321008/144349.
[29] Huang, Lei, Wang, Xiuli, Yang, Jinhui, Liu, Gang, Han, Jingfeng, Li, Can. Dual Cocatalysts Loaded Type I CdS/ZnS Core/Shell Nanocrystals as Effective and Stable Photocatalysts for H-2 Evolution. JOURNAL OF PHYSICAL CHEMISTRY C[J]. 2013, 117(22): 11584-11591, http://159.226.238.44/handle/321008/137958.
[30] Liu, Gang, Han, Jingfeng, Zhou, Xin, Huang, Lei, Zhang, Fuxiang, Wang, Xiuli, Ding, Chunmei, Zheng, Xiaojia, Han, Hongxian, Li, Can. Enhancement of visible-light-driven O-2 evolution from water oxidation on WO3 treated with hydrogen. JOURNAL OF CATALYSIS[J]. 2013, 307: 148-152, http://159.226.238.44/handle/321008/119491.
[31] Huang, Lei, Yang, Jinhui, Wang, Xiuli, Han, Jingfeng, Han, Hongxian, Li, Can. Effects of surface modification on photocatalytic activity of CdS nanocrystals studied by photoluminescence spectroscopy. PHYSICAL CHEMISTRY CHEMICAL PHYSICS[J]. 2013, 15(2): 553-560, http://www.irgrid.ac.cn/handle/1471x/720998.
[32] Li, Haiju, Liu, Fengyu, Han, Jingfeng, Cai, Mingzhu, Sun, Shiguo, Fan, Jiangli, Song, Fengling, Peng, Xiaojun. Interaction of Cy3 dye with CCG and its application for BSA detection. JOURNAL OF MATERIALS CHEMISTRY B[J]. 2013, 1(5): 693-697, http://159.226.238.44/handle/321008/137651.
[33] Wang, Donge, Li, Rengui, Zhu, Jian, Shi, Jingying, Han, Jingfeng, Zong, Xu, Li, Can. Photocatalytic Water Oxidation on BiVO4 with the Electrocatalyst as an Oxidation Cocatalyst: Essential Relations between Electrocatalyst and Photocatalyst. JOURNAL OF PHYSICAL CHEMISTRY C[J]. 2012, 116(8): 5082-5089, http://159.226.238.44/handle/321008/138015.
[34] Meng, Yang, Liu, Fengyu, Han, Jingfeng, Sun, Shiguo, Fan, Jiangli, Song, Fengling, Peng, Xiaojun. Interaction study on DNA, single-wall carbon nanotubes and acridine orange. MATERIALS SCIENCE AND ENGINEERING B-ADVANCED FUNCTIONAL SOLID-STATE MATERIALS[J]. 2012, 177(11): 887-891, http://dx.doi.org/10.1016/j.mseb.2012.03.055.
[35] 王冬娥, 李仁贵, 朱剑, 施晶莹, 韩晶峰, 李灿. Photocatalytic Water Oxidation on BiVO4 Sheets with Different Exposures of Crystal Facet and the Electrocatalyst as an Oxidation Co-catalyst under Visible Light Irradiation. 15TH INTERNATIONAL CONGRESS ON CATALYSIS. 2012, 0, http://159.226.238.44/handle/321008/117110.
[36] Zong, Xu, Han, Jingfeng, Ma, Guijun, Yan, Hongjian, Wu, Guopeng, Li, Can. Photocatalytic H-2 Evolution on CdS Loaded with WS2 as Cocatalyst under Visible Light Irradiation. JOURNAL OF PHYSICAL CHEMISTRY C[J]. 2011, 115(24): 12202-12208, http://159.226.238.44/handle/321008/142532.
[37] 王冬娥, 韩晶峰, 朱剑, 李灿. Photochemical deposition of cobalt-based cocatalyst on BiVO4 for oxygen production from water splitting. sixth tokyo conference on advanced catalytic science and technology & fifth asia pacific congress on catalysis. 2010, 191/2, http://159.226.238.44/handle/321008/114100.

   

（ 1 ） 分子筛表面甲氧基在甲醇转化及甲醇耦合转化过程中的作用, 负责人, 国家任务, 2022-01--2025-12

已指导学生

任翔翔  硕士研究生  081705-工业催化