Industrial solid waste resource utilization and Basic research on application of soil improvement

2004.9.1--2007.6.30   Institute of Process Engineering, Chinese Academy of Sciences，doctor
2001.9.1--2004.6.30   Beijing University of Chemical Technology，master
1988.9.1--1992.6.30   Hebei University of Science and Technology，bachelor

   

2007.9.1--2009.8.30，Tsinghua University, Postdoctor

2009.9.1--2021.6.22，Institute of Process Engineering, Chinese Academy of Sciences，Associate Professor

2021.6.22--unti now，Institute of Process Engineering, Chinese Academy of Sciences，Professor

   

More than 80 papers have been published.

Selected publications:

1.        Shuhua Ma, Shili Zheng^*, Yifei Zhang, Yi Zhang. Phase Diagram for the Na₂O-Al₂O₃-H₂O System at 130℃. Journal of Chemical and Engineering Data, 2007, 52:77-79. 

2.        Shuhua Ma, Shili Zheng^*, Hongbin Xu, Yi Zhang. Spectra of sodium aluminate solutions. Transactions of Nonferrous Metals Society of China，2007,4:853-857. 

3.        Shuhua Ma^*, Zongguo Wen, Jining Chen, Shili Zheng. An environmentally friendly design for low-grade diasporic-bauxite processing. Minerals Engineering, 2009,22: 793-798. 

4.        Ran Zhang, Shuhua Ma, Quancheng Yang, Shili Zheng^*, Hao Du. Research on NaCaHSiO₄ decomposition in sodium hydroxide solution. Hydrometallurgy, 2011(108): 205-213. 

5.        Ran Zhang, Shili Zheng, Shuhua Ma^*. Recovery of alumina and alkali in Bayer red mud by the formation of andradite-grossular hydrogarnet in hydrothermal process. Journal of Hazardous Materials, 2011(189):827-835. 

6.        Ran Zhang, Shuhua Ma, Shili Zheng, Yi Zhang. Study on Hydro-Alkali Pre-Treatment for Red Mud and the Application of Post-Treated Residue on Construction Materials. ICSOBA international bauxite residue seminar, 2011.

7.        Weiquan Cai^*, Shuanggui Chen, Jiaguo Yu^*, Yuzhen Hu, Chengxiong Dang, Shuhua Ma. Template-free solvothermal synthesis of hierarchical boehmite hollow microspheres with strong affinity toward organic pollutants in water. Materials Chemistry and Physics, 2013, 138: 167-173. 

8.        Zhenhua Tang, Shuhua Ma, Jian Ding, Yuejiao Wang, Shili Zheng, Guanjie Zhai. Current status and prospect of fly ash utilization in China. 2013 World of Coal Ash (WOCA) Conference, April 22-25, Lexington, 2013. 

9.        Aijuan Ding, Yuejiao Wang, Shuhua Ma^*, Shili Zheng, Fen Guo. Phase diagram for Na₂SO₄-NaOH-H₂O system and Na₂SO₄ solubility in sodium aluminate solution with caustic ratios of 12 and 15 at 80℃. Journal of Chemical and Engineering Data. 2013, 58(4): 964-968.

10.    Shuhua Ma, Zongguo Wen, and Jining Chen. Scenario Analysis of Sulfur Dioxide Emissions Reduction Potential in China’s Iron and Steel Industry. Journal of Industrial Ecology. 2012,16(4): 506–517.

11.    Shuhua Ma^*, Zongguo Wen^*, Jining Chen, Zhichao Wen. Mode of circular economy in China's iron and steel industry: a case study in Wu'an city. Journal of Cleaner Production. 2014,64: 505-512.

12.    Quancheng Yang, Shuhua Ma^*, Shili Zheng, Ran Zhang. Recovery of alumina from circulating fluidized bed combustion Al-rich fly ash using mild hydrochemical process. Transactions of Nonferrous Metals Society of China. 2014,24(4):1187-1195.

13.    Jian Ding, Shuhua Ma, Shili Zheng, Yuejiao Wang, Yi Zhang. A Comparative Study on Properties of High-alumina Fly Ash Characterized with Different Combustion Way, The 6th International Conference on Hydrometallurgy, Beijing, 2014.

14.    Jian Ding, Zhenhua Tang, Shuhua Ma^*, Yuejiao Wang, Shili Zheng, Yi Zhang, Shirley Shen, Zongli Xie. A novel process for synthesis of tobermorite fiber from high-alumina fly ash. Cement and Concrete Composites，2016, 65:11-18.

15.    Jian Ding, Shuhua Ma^*, Shili Zheng, Yi Zhang, Zongli Xie, Shirley Shen, Zhongkai Liu. Study of extracting alumina from high-alumina PC fly ash by a hydro-chemical process. Hydrometallurgy, 2016，161:58-64 .

16.    Zehua Wang, Shuhua Ma^*, Zhenhua Tang, Xiaohui Wang, Shili Zheng. Effects of particle size and coating on decomposition of alumina-extracted residue from high-alumina fly ash. Journal of Hazardous Materials, 2016, 308：253-263.

17.    Zhichao Wen, Shuhua Ma^*, Shili Zheng, Yi Zhang, Yan Liang. Assessment of environmental risk for red mud storage facility in China: a case study in Shandong Province. Environmental science and pollution research international, 2016, 23(11): 11193.

18.    Shuhua Ma, Mindi Xu, Qiqige, Xiaohui Wang, Xiao Zhou. Challenges and Developments in the Utilization of Fly Ash in China. International Journal of Environmental Science and Development, 2017,Vol. 8, No. 11.

19.    Jian Ding, Shuhua Ma^*, Shirley Shen^*, Zongli Xie, Shili Zheng, Yi Zhang. Research and industrialization progress of recovering alumina from fly ash: A concise review. Waste Management ,2017,60:375-387.

20.    Zehua Wang, Shuhua Ma, Shili Zheng^*, Xiaohui Wang. Incorporation of Al and Na in hydrothermally synthesized tobermorite. Journal of the American Ceramic Society, 2017, 100（2）：792-799.

21.    Yang Luo, Shuhua Ma, Zhenqing Zhao, Zehua Wang, Shili Zheng^*, Xiaohui Wang. Preparation and characterization of whisker-reinforced ceramics from coal fly ash. Ceramics International, 2017,43（1）:1-11.

22.    Yang Luo, Shuhua Ma^*, Chunli Liu, Zhenqing Zhao, Shili Zheng, Xiaohui Wang. Effect of particle size and alkali activation on coal fly ash and their role in sintered ceramic tiles. Journal of the European Ceramic Society. 2017, 37(4): 1847–1856. 

23.    Yang Luo, Shili Zheng, Shuhua Ma^*, Chunli Liu, Xiaohui Wang. Ceramic tiles derived from coal fly ash: Preparation and mechanical characterization. Ceramics International. 2017，43（15）：11953-11966.

24.    Chunli Liu, Shuhua Ma^*, Shili Zheng, Yang Luo, Jian Ding,Xiaohui Wang, Yi Zhang. Combined treatment of red mud and coal fly ash by a hydro-chemical process. Hydrometallurgy. 2018，175：224-231.

25.    Chunli Liu, Shili Zheng, Shuhua Ma^*, Yang Luo, Jian Ding, Xiaohui Wang, Yi Zhang. A novel process to enrich alumina and prepare silica nanoparticles from high-alumina fly ash. Fuel Processing Technology. 2018，173:40-47.

26.    Yang Luo, Shili Zheng, Shuhua Ma^*, Chunli Liu, Xiaohui Wang. Preparation of sintered foamed ceramics derived entirely from coal fly ash. Construction and Building Materials. 2018，163:529-538.

27.    Yang Luo, Shuhua Ma, Shili Zheng^*，Chunli Liu, Dajie Han, Xiaohui Wang. Mullite-based ceramic tiles produced solely from high-alumina fly ash: Preparation and sintering mechanism. Journal of Alloys and Compounds. 2018，732(25):828-837.

28.    Yang Luo, Shili Zheng, Shuhua Ma^*, Chunli Liu, Jian Ding, Xiaohui Wang^*. Novel two-step process for synthesising beta-SiC whiskers from coal fly ash and water glass. Ceramics International.2018, 44(9):10585-10595.

29.    Xiaohui Wang*, Yujuan Jia, Shuhua Ma, Shili Zheng, Qing Sun. Effect of mechanical activation on the leaching kinetics of niobium-bearing mineralisation in KOH hydrothermal system. Hydrometallurgy, 2018,181:123-129.

30.    Zehua Wang, Shili Zheng, Shuhua Ma*, Jian Ding, Xiaohui Wang. Recovery of sodium from alumina-extracted fly ash using concentrated sodium carbonate solution. Journal of Mining and Metallurgy Section B: Metallurgy, 2018，54(2)： 225-232. 

31.    Zehua Wang, Shuhua Ma, Shili Zheng^*, Jian Ding, Xiaohui Wang. Flexural strength and thermal conductivity of fiber reinforced calcium silicate boards prepared from fly ash. Journal of Materials in Civil Engineering. 2019，31（8）：04019140.

32.    Chunli Liu, Shuhua Ma^*, Jian Ding, Yang Luo, Shili Zheng, Yi Zhang. Kinetics of Decomposition of mullite and corundum in coal fly ash under highly alkaline conditions. Transactions of nonferrous metals society of China. 2019，29(4)：868-875.

33.    Jian Ding, Shuhua Ma^*, Zongli Xie, Xiaohui Wang, Shili Zheng^*, Yi Zhang. Formation mechanism of an undesirable by-product in the mild hydro-chemical process for the extraction of alumina from fly ash and its mitigation. Hydrometallurgy. 2019，186：292-300. 

34.    Yang Luo, Yinghong Wu, Shuhua Ma, Shili Zheng^*, and Paul K. Chu^*. An eco-friendly and cleaner process for preparing architectural ceramics from coal fly ash: Pre-activation of coal fly ash by a mechanochemical method. Journal of cleaner production. 2019，214：419-428. 

35.    Chunbin Guo, Jingjing Zou*, Shuhua Ma*, Jianlin Yang, Kehan Wang. Alumina Extraction from Coal Fly Ash via Low-Temperature Potassium Bisulfate Calcination. Minerals. 2019, 9(10):585 .

36.    Lihong Cheng, Yang Luo, Shuhua Ma**, Weihong Guo*, Xiaohui Wang. Corrosion resistance of inorganic zinc-rich coating reinforced by Ni-coated coal fly ash. Journal of Alloys and Compounds. 2019, 786: 791-797.

37.    Lihong Cheng, Chunli Liu, Dajie Han, Shuhua Ma**, Weihong Guo*, Haifeng Cai, Xiaohui Wang. Effect of graphene on corrosion resistance of waterborne inorganic zinc-rich coatings. Journal of Alloys and Compounds. 2019, 774:255-264. 

38.        Yang Luo，Yinghong Wu，Chao Huang，Dezhi Xiao，Lizhai Zhang，Shuhua Ma，Jingkui Qu，Shili Zheng^*，Paul K. Chu^*. Graphite felt incorporated with MoS₂/rGO for electrochemical detoxification of high-arsenic fly ash. Chemical Engineering Journal. 2020，382：122763. 

39.        Fuli Liu, Shuhua Ma*, Kun Ren, Xiaohui Wang. Mineralogical phase separation and leaching characteristics of typical toxic elements in Chinese lignite fly ash. Science of the Total Environment, 2020,708:135095.

40.    Tianyuan Wang, Shuhua Ma*, Xiaohui Wang, Tao Hong, Yang Luo. A 100% high-aluminum fly ash-based high-density mullite ceramic with a triple microstructure: Preparation and mechanical characterization. Construction and Building Materials，2020,239:117761.

41.    Yanjun Ou, Shuhua Ma*, Xiao Zhou, Xiaohui Wang, Jianping Shi, Yi Zhang .The Effect of a Fly Ash-Based Soil Conditioner on Corn and Wheat Yield and Risk Analysis of Heavy Metal Contamination. Sustainability. 2020，12(18):7281.

42.    Luo Yang，Wu Yinghong， Ma Shuhua，Zheng Shili*，Zhang Yi，Chu Paul K. *. Utilization of coal fly ash in China: a mini-review on challenges and future directions. Environmental Science and Pollution Research. 2021，28（15）:18727-18740.

43.    Yanjun Ou，Shuhua Ma*，Xiao Zhou，etal. Multi-element Interactive Improvement Mechanism of Coal Fly Ash‑Based Soil Conditioner on Wheat. Applied Biochemistry and Biotechnology. 2022，194(4):1580-1605 . 

44. Joshua Olatunji Ayenia，Shuhua Ma*，Xiaohui Wang，Xuan Hou. Fabrication method，dielectric properties，and microwave absorption performance of high alumina fly ash-based ceramic composites. Ceramics International，2022，48(15): 21268-21282.

45.    Penglong Zhao，Shuhua Ma*，Xiaohui Wang，Wei Wu*，Yanjun Ou. Properties and mechanism of mullite whisker toughened ceramics. Ceramics International，2023, 49:10238-10248.

46.        Chenxu Liu，Shuhua Ma*，Xiaohui Wang，Yanjun Ou，Hao Du. Biodegradation of organic compounds in the coal gangue by Bacillus sp. into humic acid. Biodegradation，2023,34:125-138. 

47.        Xuan Hou, Shuhua Ma, Xiaohui Wang, Yanjun Ou, Ruiping Liu. Effects of alkali activation and hydrothermal processes on the transformation of fly ash into Al-substituted tobermorite fiber. Construction and Building Materials, 2023, 397, 132372. 

48.    Xuan Hou, Shuhua Ma*, Xiaohui Wang, Yanjun Ou, Ruiping Liu. Transformation of fly ash into a fluffy C-S-H material: Enhancing chemical properties and advancing the utilization of portland cement. Construction and Building Materials, 2024,416: 135198. 

More than 70 patents are field an 39 patents are authorized.

Selected patents:

         1. 羟基草酸铝及其制备方法、羟基草酸铝作为阻燃剂. ZL 200110000109.1

2.一种氢氧化钠熔盐法处理铝土矿生产氢氧化铝的方法. ZL 200610099393.1

3.一种拜耳法循环碱液中钠铝分离的方法. ZL 201010233127.X

4.一种铬盐清洁生产工艺中氧化铝的分离方法. ZL 201010233130.1

5.一种湿法从粉煤灰中提取氧化铝的方法. ZL 201010565571.1

6.一种氧化铝厂赤泥的深度脱碱方法. ZL 201110270687.7

7. 一种碱法处理高铁赤泥深度脱碱与铁富集的方法. ZL 201310108984.0

8. 一种用粉煤灰制备托贝莫来石的方法及其应用. ZL 201410187586.7

9.一种用酸法处理粉煤灰提铝后所得硅渣制备托贝莫来石的方法. ZL 201410707019.X

10.一种高纯氧化铝的制备方法. ZL 201410708308.1

11.一种硬硅钙石型保温材料的制备方法. ZL 201410198013.4

12. 一种轻质建筑保温砌块及其制备方法. ZL 201410706995.3

13.一种轻质硅酸钙板的制备方法. ZL 201410308051.0

14.一种种分母液的高浓度蒸发排盐方法. ZL ZL201610083294.8

15.一种从高铝粉煤灰中湿法提取氧化铝的方法. ZL 201510164903.8

16.一种高砷金矿两段焙烧-转化处理-氰化浸金的方法. ZL 201610493676.8

17.一种粉煤灰提铝渣的脱碱方法. ZL 201610350145.3

18. 一种粉煤灰基瓷质砖的制备方法. ZL 201510439043.4

19.一种乳浊釉及其制备方法. ZL 201510830510.6

20.一种陶质砖及其制备方法. ZL 201510833793.X

21.一种富枸溶性硅的土壤调理剂的制备方法. ZL 201510040893.7

22.一种以赤泥为主要原料制备轻质墙面砖的方法. ZL 201610031260.4

23. 一种提高赤泥浸出液过滤性能的方法. 专利号：ZL 201710049829.4

24.一种吸附材料及其制备方法和用途. ZL 201810540598.1

25.一种轻质墙面砖的制备方法. ZL 201610030843.5

26.一种土壤调理剂及其制备方法. ZL 201611217541.5

27. 粉煤灰中氧化铝的富集方法及固体白炭黑的制备方法. ZL 201710554296.5

28.一种碱活化钾长石制备可溶性钾和硅酸钙土壤调理剂的方法. ZL 2016112159573

29.一种β-碳化硅晶须的制备方法. ZL 201810102382.7

30.一种包覆镍的粉煤灰及其制备方法和用途. ZL 201811151688.8

31.一种金矿焙砂或焙烧氰化尾渣预处理浸金的方法. ZL 201910542055.8

32.一种矿物和/或固废中二氧化硅的脱除方法. ZL 201810730877.4

33.一种粉煤灰陶粒及其制备方法. ZL 201810943052.0

34.一种粉煤灰脱汞方法. ZL 201910950612.X

35.一种改性粉煤灰的制备方法、及其制备的改性粉煤灰和应用. ZL202011035383.8

36.一种脱除粉煤灰中重金属及含重金属尾液深度净化方法. ZL 202010600322.5

37.一种粉煤灰脱汞及脱汞液净化的方法. ZL 202010576051.4

38.一种镂空球状莫来石-刚玉催化剂载体及其制备方法和应用. ZL 202110064201.8

39.一种土壤调理剂及其制备方法与应用. ZL 202110114441.4

已指导学生

徐泺雲  硕士研究生  085600-材料与化工  

现指导学生

单秉泉  硕士研究生  085600-材料与化工