基本信息
宋宪根 男 博导 中国科学院大连化学物理研究所
电子邮件: xiangensong@dicp.ac.cn
通信地址: 辽宁省大连市中山路457号能源楼1号601
邮政编码:
研究领域
合成气转化,多相羰基合成,酯化,酸及酯加氢等。
招生信息
工业催化 博士研究生 、硕士研究生
招生方向
合成气转化多相羰基化酯化及加氢
教育背景
2007-09--2013-01 中国科学院大连化学物理研究所 工业催化专业 博士学位2003-09--2007-06 东北大学理学院应用化学系 理学学士学位
工作经历
工作简历
2022-07~现在, 中国科学院大连化学物理研究所合成气转化与精细化学品催化研究中心, 研究员2018-09~现在, 中国科学院大连化学物理研究所合成气转化与精细化学品催化研究中心, 合成气选择转化制化学品研究组组长2016-07~2022-07,中国科学院大连化学物理研究所C1化学与精细化工催化研究组, 副研究员2013-01~2016-06,中国科学院大连化学物理研究所C1化学与精细化工催化研究组, 助理研究员
专利与奖励
专利成果
( 1 ) 一种用于甲醇无卤素气相羰基化制备醋酸及醋酸酯的催化剂制备方法与应用, 发明专利, 2022, 第 3 作者, 专利号: CN113941329A( 2 ) 一种单原子催化剂低温催化氧化乙烷制备乙酸的方法, 发明专利, 2021, 第 3 作者, 专利号: CN112898149A( 3 ) 一种CO加氢制C 2 含氧化合物的方法, 发明专利, 2021, 第 3 作者, 专利号: CN112892532A( 4 ) 一种用于低温催化氧化甲烷制备乙酸的原子级单分散的过渡金属催化剂的制备方法与应用, 发明专利, 2021, 第 3 作者, 专利号: CN112892588A( 5 ) 一种铑基催化剂、其制备方法及在甲醇气相羰基化反应中的应用, 发明专利, 2021, 第 3 作者, 专利号: CN111195529B( 6 ) 一种原子级单分散铱基催化剂、其制备方法及在甲醇气相羰基化制备乙酸甲酯中的应用, 发明专利, 2021, 第 3 作者, 专利号: CN111195532B( 7 ) 一种原子级单分散的铱基催化剂其制备方法与应用, 专利授权, 2021, 第 3 作者, 专利号: CN111195530B( 8 ) 一种原子级单分散铑基催化剂、其制备方法及在甲醇气相羰基化制备乙酸甲酯中的应用, 专利授权, 2021, 第 3 作者, 专利号: CN111195516B( 9 ) 一种单原子分散贵金属催化剂、其制备方法及应用, 专利授权, 2021, 第 3 作者, 专利号: CN111195515B( 10 ) 一种单原子分散的铑基催化剂、其制备方法及在甲烷低温氧化反应中的应用, 专利授权, 2021, 第 3 作者, 专利号: CN111195514B( 11 ) 一种负载型铑基催化剂、其制备方法及在合成气制C 2 含氧化物中的应用, 发明专利, 2019, 第 1 作者, 专利号: CN110354852A( 12 ) 一种活性炭负载的硫化铁基催化剂及其制备与应用, 发明专利, 2019, 第 3 作者, 专利号: CN109759085A( 13 ) 一种活性炭负载的含硫铱基催化剂及其制备与应用, 发明专利, 2019, 第 3 作者, 专利号: CN109759055A( 14 ) 活性炭负载的含硫化铁镍的铱基催化剂及其制备与应用, 发明专利, 2019, 第 3 作者, 专利号: CN109759090A( 15 ) 含有助剂的活性炭负载的硫化铁基催化剂及其制备与应用, 发明专利, 2019, 第 3 作者, 专利号: CN109759086A( 16 ) 用于甲醇气相羰基化制乙酸甲酯的催化剂及其制备与应用, 发明专利, 2019, 第 3 作者, 专利号: CN109759084A( 17 ) 含磺酸基和膦配体多级孔聚合物固载铑催化剂及制备和应用, 专利授权, 2019, 第 4 作者, 专利号: CN109453814A( 18 ) 有机含膦聚合物载体负载的铑基催化剂及其制备和应用, 发明专利, 2019, 第 3 作者, 专利号: CN109453815A( 19 ) 有机含氮聚合物载体负载Rh基催化剂及其制备和应用, 发明专利, 2019, 第 4 作者, 专利号: CN109453812A( 20 ) 一种超高分散负载型单原子贵金属催化剂及其制备方法, 专利授权, 2019, 第 1 作者, 专利号: CN109126774A( 21 ) 活性炭载体负载的硫促进的铱基催化剂及其制备和应用, 专利授权, 2018, 第 3 作者, 专利号: CN108067222A( 22 ) 一种香芹醇分子氧多相催化氧化制备香芹酮的方法, 发明专利, 2018, 第 3 作者, 专利号: CN108069840A( 23 ) 一种用于甲醇气相羰基化制乙酸甲酯的活性炭负载铱基催化剂及其应用, 发明专利, 2018, 第 4 作者, 专利号: CN108069857A( 24 ) 一种用于香芹醇分子氧催化氧化制香芹酮的催化剂及其制备方法, 专利授权, 2018, 第 3 作者, 专利号: CN108067223A( 25 ) 一种活性炭负载的铱基催化剂及其制备与应用, 发明专利, 2018, 第 4 作者, 专利号: CN108067226A( 26 ) 一种酸处理炭载体负载的铱基催化剂及其制备方法和应用, 发明专利, 2017, 第 3 作者, 专利号: CN107486191A( 27 ) 一种碳基材料负载的铱基催化剂及其制备方法和应用, 发明专利, 2017, 第 1 作者, 专利号: CN106807367A( 28 ) 一种活性炭负载的铱基催化剂及其制备方法和应用, 发明专利, 2017, 第 1 作者, 专利号: CN106807368A( 29 ) 一种活性炭负载的铑基催化剂及其制备方法和应用, 发明专利, 2016, 第 1 作者, 专利号: CN106140156A( 30 ) 一种用于甲醇羰基化的含碘聚合物负载的铑基催化剂, 发明专利, 2016, 第 1 作者, 专利号: CN105618136A( 31 ) 一种用于合成气转化的磷化物催化剂和制备方法及其应用, 发明专利, 2014, 第 2 作者, 专利号: CN103521249A( 32 ) 由氢、一氧化碳和乙烯制备3-戊酮和丙醛的钴磷化物催化剂, 发明专利, 2013, 第 2 作者, 专利号: CN103084192A( 33 ) 由氢气、一氧化碳和乙烯制备3-戊酮和丙醛的方法, 发明专利, 2013, 第 2 作者, 专利号: CN103086853A
出版信息
发表论文
[1] Nature Communications. 2024, 通讯作者 [2] Small. 2024, 通讯作者 [3] Chem Catalysis. 2024, 通讯作者 [4] Chinese Journal of Catalysis. 2024, 通讯作者 [5] Angew. Chem. Int. Ed.. 2023, 通讯作者 [6] Angew. Chem. Int. Ed.. 2023, 第 3 作者[7] Adv. Funct. Mater.. 2023, 通讯作者 [8] Applied Catalysis B: Environmental. 2023, 通讯作者 [9] Molecular Catalysis. 2023, 通讯作者 [10] ACS Catalysis. 2022, 通讯作者 [11] Journal of Catalysis. 2022, 通讯作者 [12] 任周, 刘洋, 吕元, 宋宪根, 郑长勇, 姜政, 丁云杰. 通过“双离子键”固载于季鏻盐聚合物的[Rh(CO)I3]2–物种在多相乙醇羰基化中的应用(英文). CHINESE JOURNAL OF CATALYSIS[J]. 2021, 第 4 作者606-617, https://kns.cnki.net/KCMS/detail/detail.aspx?dbcode=CJFQ&dbname=CJFDLAST2021&filename=CHUA202104008&v=MDU4MTdiek9KaVhlYjdHNEhORE1xNDlGYklSOGVYMUx1eFlTN0RoMVQzcVRyV00xRnJDVVI3dWZZZWRuRkNyZ1U=.[13] Li, Bin, Song, Xiangen, Feng, Siquan, Yuan, Qiao, Jiang, Miao, Yan, Li, Ding, Yunjie. Direct conversion of methane to oxygenates on porous organic polymers supported Rh mononuclear complex catalyst under mild conditions. APPLIED CATALYSIS B-ENVIRONMENTAL[J]. 2021, 第 2 作者 通讯作者 293: http://dx.doi.org/10.1016/j.apcatb.2021.120208.[14] Chen, Weimiao, Song, Xiangen, Ning, Lili, Ding, Yunjie. CO Hydrogenation to C-2 Oxygenates over SiO2 Supported Rh-Based Catalyst: The Effect of pH Value of Impregnation Solution. CATALYSIS LETTERS[J]. 2021, 第 2 作者151(9): 2775-2783, http://dx.doi.org/10.1007/s10562-021-03533-8.[15] Ren, Zhou, Liu, Yang, Lyu, Yuan, Song, Xiangen, Zheng, Changyong, Jiang, Zheng, Ding, Yunjie. Quaternary phosphonium polymer-supported dual-ionically bound Rh(CO)I-3(2-) catalyst for heterogeneous ethanol carbonylation. CHINESE JOURNAL OF CATALYSIS[J]. 2021, 第 4 作者42(4): 606-617, http://dx.doi.org/10.1016/S1872-2067(20)63676-2.[16] Yuan, Qiao, Song, Xiangen, Feng, Siquan, Jiang, Miao, Yan, Li, Li, Jingwei, Ding, Yunjie. An efficient and ultrastable single-Rh-site catalyst on a porous organic polymer for heterogeneous hydrocarboxylation of olefins. CHEMICAL COMMUNICATIONS[J]. 2021, 第 2 作者 通讯作者 57(4): 472-475, https://www.webofscience.com/wos/woscc/full-record/WOS:000608997100006.[17] Feng, Siquan, Lin, Xiangsong, Song, Xiangen, Mei, Bingbao, Mu, Jiali, Li, Jingwei, Liu, Yang, Jiang, Zheng, Ding, Yunjie. Constructing Efficient Single Rh Sites on Activated Carbon via Surface Carbonyl Groups for Methanol Carbonylation. ACS CATALYSIS[J]. 2021, 第 3 作者 通讯作者 11(2): 682-690, http://dx.doi.org/10.1021/acscatal.0c03933.[18] Yu, Zhipeng, Xu, Junyuan, Feng, Siquan, Song, Xiangen, Bondarchuk, Oleksandr, Faria, Joaquim L, Ding, Yunjie, Liu, Lifeng. Rhodium single-atom catalysts with enhanced electrocatalytic hydrogen evolution performance dagger. NEW JOURNAL OF CHEMISTRY[J]. 2021, 第 4 作者45(13): 5770-5774, https://www.webofscience.com/wos/woscc/full-record/WOS:000632138600001.[19] 任周, 刘洋, 吕元, 宋宪根, 郑长勇, 姜政, 丁云杰. 通过“双离子键”固载于季鏻盐聚合物的Rh(CO)I_(3)^(2–)物种在多相乙醇羰基化中的应用. 催化学报[J]. 2021, 第 4 作者42(4): 606-617,中插27, http://lib.cqvip.com/Qikan/Article/Detail?id=7103978627.[20] Li, Xingju, Feng, Siquan, Hemberger, Patrick, Bodi, Andras, Song, Xiangen, Yuan, Qiao, Mu, Jiali, Li, Bin, Jiang, Zheng, Ding, Yunjie. Iodide-Coordinated Single-Site Pd Catalysts for Alkyne Dialkoxycarbonylation. ACS CATALYSIS[J]. 2021, 第 5 作者 通讯作者 11(15): 9242-9251, http://dx.doi.org/10.1021/acscatal.1c01579.[21] Feng, Siquan, Lin, Xiangsong, Song, Xiangen, Liu, Yang, Jiang, Zheng, Hemberger, Patrick, Bodi, Andras, Ding, Yunjie. The role of H-2 on the stability of the single-metal-site Ir-1/AC catalyst for heterogeneous methanol carbonylation. JOURNAL OF CATALYSIS[J]. 2020, 第 3 作者 通讯作者 381: 193-203, http://dx.doi.org/10.1016/j.jcat.2019.10.032.[22] 陈维苗, 宋宪根, 丁云杰. 合成气直接制C2含氧化合物Rh基催化剂中金属-助剂(载体)界面的构建. 无机化学学报[J]. 2020, 第 2 作者36(11): 2005-2013, http://lib.cqvip.com/Qikan/Article/Detail?id=7103145624.[23] Feng, Siquan, Hemberger, Patrick, Bodi, Andras, Song, Xiangen, Yu, Tongpo, Jiang, Zheng, Liu, Yang, Ding, Yunjie. Preparation and regeneration of supported single-Ir-site catalysts by nanoparticle dispersion via CO and nascent I radicals. JOURNAL OF CATALYSIS[J]. 2020, 第 4 作者 通讯作者 382: 347-357, http://dx.doi.org/10.1016/j.jcat.2019.12.040.[24] Ren, Zhou, Lyu, Yuan, Song, Xiangen, Ding, Yunjie. Review of heterogeneous methanol carbonylation to acetyl species. APPLIED CATALYSIS A-GENERAL[J]. 2020, 第 3 作者595: http://dx.doi.org/10.1016/j.apcata.2020.117488.[25] Chen WeiMiao, Song XianGen, Ding YunJie. Construction of Metal-Promoter (Support) Interfaces within Rh based Catalyst for Direct Synthesis of C-2 Oxygenates from Syngas. CHINESE JOURNAL OF INORGANIC CHEMISTRY[J]. 2020, 第 2 作者36(11): 2005-2013, https://www.webofscience.com/wos/woscc/full-record/WOS:000589373500001.[26] Chen, Weimiao, Song, Xiangen, Ning, Lili, Ding, Yunjie. Ammonium salts modified silica supported Rh-Mn-Li catalyst for CO hydrogenation to C(2)oxygenates. REACTION KINETICS MECHANISMS AND CATALYSIS[J]. 2020, 第 2 作者131(2): 677-690, https://www.webofscience.com/wos/woscc/full-record/WOS:000577272300001.[27] Chen, Weimiao, Song, Xiangen, Ning, Lili, Ding, Yunjie. Ammonia Hydrothermally Treated SiO2 Supported Rh-Based Catalyst for CO Hydrogenation to C-2 Oxygenates: Remarkable Effect of Support Pore Size. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH[J]. 2020, 第 2 作者59(42): 18798-18807, http://dx.doi.org/10.1021/acs.iecr.0c03676.[28] Ren, Zhou, Lyu, Yuan, Song, Xiangen, Liu, Yang, Jiang, Zheng, Lin, Ronghe, Ding, Yunjie. Dual-Ionically Bound Single-Site Rhodium on Porous Ionic Polymer Rivals Commercial Methanol Carbonylation Catalysts. ADVANCED MATERIALS[J]. 2019, 第 3 作者31(50): https://www.webofscience.com/wos/woscc/full-record/WOS:000494863000001.[29] Ren, Zhou, Liu, Yang, Lyu, Yuan, Song, Xiangen, Zheng, Changyong, Feng, Siquan, Jiang, Zheng, Ding, Yunjie. Single-atom Rh based bipyridine framework porous organic polymer: A high active and superb stable catalyst for heterogeneous methanol carbonylation. JOURNAL OF CATALYSIS[J]. 2019, 第 4 作者369: 249-256, http://www.corc.org.cn/handle/1471x/2372667.[30] Siquan Feng, Xiangen Song, Yang Liu, Xiangsong Lin, Li Yan, Siyue Liu, Wenrui Dong, Xueming Yang, Zheng Jiang, Yunjie Ding. In situ formation of mononuclear complexes by reaction-induced atomic dispersion of supported noble metal nanoparticles. NATURE COMMUNICATIONS[J]. 2019, 第 2 作者 通讯作者 10(1): 1-9, https://doaj.org/article/07cab734fa41491983886b38a3cc8cb9.[31] Feng, Siquan, Song, Xiangen, Ren, Zhou, Ding, Yunjie. La-Stabilized, Single-Atom Ir/AC Catalyst for Heterogeneous Methanol Carbonylation to Methyl Acetate. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH[J]. 2019, 第 2 作者 通讯作者 58(12): 4755-4763, http://cas-ir.dicp.ac.cn/handle/321008/165562.[32] Feng, Siquan, Lin, Xiangsong, Song, Xiangen, Liu, Yang, Jiang, Zheng, Ding, Yunjie. Insight into the stability of binuclear Ir-La catalysts for efficient heterogeneous methanol carbonylation. JOURNAL OF CATALYSIS[J]. 2019, 第 3 作者 通讯作者 377: 400-408, http://dx.doi.org/10.1016/j.jcat.2019.06.050.[33] 郑长勇, 冯四全, 宋宪根, 丁云杰. 活性炭负载Au-Cu二元催化剂用于多相甲醇羰基化反应. 石油化工[J]. 2019, 第 3 作者48(12): 1191-1198, http://lib.cqvip.com/Qikan/Article/Detail?id=7100568700.[34] Ren Zhou, Lyu Yuan, Feng Siquan, Song Xiangen, Ding Yunjie. 基于酸促进的单原子活性位点Ir-La-S/AC催化剂在甲醇羰基化中的应用. 催化学报[J]. 2018, 第 4 作者39(6): 1060-1069, http://lib.cqvip.com/Qikan/Article/Detail?id=675137773.[35] Ren, Zhou, Lyu, Yuan, Feng, Siquan, Song, Xiangen, Ding, Yunjie. Acid-promoted Ir-La-S/AC-catalyzed methanol carbonylation on single atomic active sites. CHINESE JOURNAL OF CATALYSIS[J]. 2018, 第 4 作者39(6): 1060-1069, https://www.webofscience.com/wos/woscc/full-record/WOS:000434870800007.[36] 任周, 吕元, 冯四全, 宋宪根, 丁云杰. 基于酸促进的单原子活性位点Ir-La-S/AC催化剂在甲醇羰基化中的应用. 催化学报[J]. 2018, 第 4 作者39(6): 1060-1069, http://lib.cqvip.com/Qikan/Article/Detail?id=675137773.[37] Ren, Zhou, Lyu, Yuan, Feng, Siquan, Song, Xiangen, Ding, Yunjie. A highly efficient single site Rh-POL-PPh3 catalyst for heterogeneous methanol carbonylation. MOLECULAR CATALYSIS[J]. 2017, 第 4 作者442: 83-88, http://dx.doi.org/10.1016/j.mcat.2017.09.007.[38] Shi, Lihua, Song, Xiangen, Liu, Guodong, Guo, Hongchen. Effect of Catalyst Preparation on Hydroisomerization of n-Heptane over Pt/Silicalite-1. CATALYSIS LETTERS[J]. 2017, 第 2 作者147(10): 2549-2557, http://cas-ir.dicp.ac.cn/handle/321008/150101.[39] Wang, Tao, Wang, Wenlong, Lyu, Yuan, Chen, Xingkun, Li, Cunyao, Zhang, Yan, Song, Xiangen, Ding, Yunjie. Highly recyclable polymer supported ionic liquids as efficient heterogeneous catalysts for batch and flow conversion of CO2 to cyclic carbonates. RSC ADVANCES[J]. 2017, 第 7 作者7(5): 2836-2841, http://cas-ir.dicp.ac.cn/handle/321008/151900.[40] Wang, Tao, Wang, Wenlong, Lyu, Yuan, Chen, Xingkun, Li, Cunyao, Zhang, Yan, Song, Xiangen, Ding, Yunjie. Highly recyclable polymer supported ionic liquids as efficient heterogeneous catalysts for batch and flow conversion of CO2 to cyclic carbonates ( vol 7,pg 2836, 2017). RSC ADVANCES. 2017, 第 7 作者7(30): 18400-18400, https://www.webofscience.com/wos/woscc/full-record/WOS:000399005500028.[41] Chen, Xingkun, Zhu, Hejun, Song, Xiangen, Du, Hong, Wang, Tao, Zhao, Ziang, Ding, Yunjie. Ru-PPh3@porous organic polymer: efficient and stable catalyst for the trickle bed regioselective hydrogenation of cinnamaldehyde. REACTION KINETICS MECHANISMS AND CATALYSIS[J]. 2017, 第 3 作者120(2): 637-649, http://cas-ir.dicp.ac.cn/handle/321008/150337.[42] Li, Cunyao, Yan, Li, Lu, Lanlu, Xiong, Kai, Wang, Wenlong, Jiang, Miao, Liu, Jia, Song, Xiangen, Zhan, Zhuangping, Jiang, Zheng, Ding, Yunjie. Single atom dispersed Rh-biphephos&PPh3@porous organic copolymers: highly efficient catalysts for continuous fixed-bed hydroformylation of propene. GREEN CHEMISTRY[J]. 2016, 第 8 作者18(10): 2995-3005, http://ir.sinap.ac.cn/handle/331007/25832.[43] Li, Cunyao, Xiong, Kai, Yan, Li, Jiang, Miao, Song, Xiangen, Wang, Tao, Chen, Xingkun, Zhan, Zhuangping, Ding, Yunjie. Designing highly efficient Rh/CPOL-bp&PPh3 heterogenous catalysts for hydroformylation of internal and terminal olefins. CATALYSIS SCIENCE & TECHNOLOGY[J]. 2016, 第 5 作者6(7): 2143-2149, http://cas-ir.dicp.ac.cn/handle/321008/170714.[44] 薛飞, 何纪敏, 陈维苗, 宋宪根, 程显波, 丁云杰. 载体焙烧温度对Rh-Mn-Li/SBA-15催化CO加氢性能的影响. 物理化学学报[J]. 2016, 第 4 作者32(11): 2769-2775, http://lib.cqvip.com/Qikan/Article/Detail?id=670465004.[45] 姜淼, 严丽, 孙雪萍, 林荣和, 宋宪根, 姜政, 丁云杰. Effect of different synthetic routes on the performance of propylene hydroformylation over 3V-PPh3 polymer supported Rh calalysts. REACTION KINETICS MECHANISMS AND CATALYSIS[J]. 2016, 第 5 作者116: 223, http://cas-ir.dicp.ac.cn/handle/321008/148036.[46] Xue, Fei, Chen, Weimiao, Song, Xiangen, Cheng, Xianbo, Ding, Yunjie. Promotional effects of Cr and Fe on Rh/SiO2 catalyst for the preparation of ethanol from CO hydrogenation. RSC ADVANCES[J]. 2016, 第 3 作者6(42): 35348-35353, http://cas-ir.dicp.ac.cn/handle/321008/170784.[47] Chen, Weimiao, Ding, Yunjie, Xue, Fei, Song, Xiangen, Ning, Lili. Highly efficient beta-SiC-supported 0.5% Rh-based catalyst for CO hydrogenation to C-2 oxygenates. CATALYSIS COMMUNICATIONS[J]. 2016, 第 4 作者85: 44-47, http://cas-ir.dicp.ac.cn/handle/321008/170070.[48] Xue Fei, He JiMin, Chen WeiMiao, Song XianGen, Cheng XianBo, Ding YunJie. Effect of the Calcination Temperature of the Support on the Performance of Rh-Mn-Li/SBA-15 Catalysts for CO Hydrogenation. ACTA PHYSICO-CHIMICA SINICA[J]. 2016, 第 4 作者32(11): 2769-2775, http://cas-ir.dicp.ac.cn/handle/321008/150355.[49] Wang, Tao, Lyu, Yuan, Chen, Xingkun, Li, Cunyao, Jiang, Miao, Song, Xiangen, Ding, Yunjie. Ru coordinated with BINAP in knitting aryl network polymers for heterogeneous asymmetric hydrogenation of methyl acetoacetate. RSC ADVANCES[J]. 2016, 第 6 作者6(34): 28447-28450, http://cas-ir.dicp.ac.cn/handle/321008/171144.[50] 裴彦鹏, 丁云杰, 臧娟, 宋宪根, 董文达, 朱何俊, 王涛, 陈维苗. 费托合成: SiO2和Al2O3负载的Co2C催化剂的表征和评价. 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科研活动
科研项目
( 1 ) 负载型铁族金属磷化物催化剂CO加氢合成乙醇等其他高级含氧化物的应用及反应机理研究, 负责人, 国家任务, 2014-01--2016-12( 2 ) 绿色能源化工技术在山东应用推广子课题-甲醇/合成气多相羰基化及其加氢制乙醇暨醇-水分离膜技术, 负责人, 中国科学院计划, 2017-01--2019-12( 3 ) 煤经合成气直接制高值化学品子课题煤经合成气直接制乙醇, 参与, 国家任务, 2017-07--2021-06( 4 ) 中科院基础科研领域优秀青年团队, 负责人, 国家任务, 2021-06--2023-06( 5 ) 甲醇-钢厂煤气制乙酸乙酯技术示范, 负责人, 中国科学院计划, 2022-02--2027-02