Dr. Hongpeng You, Professor
State Key Lab. of Rare Earth Resource Utilization
Changchun Institute of Applied Chemistry
Telephone: 86-431-85262798
E-mail: hpyou@ciac.jl.cn
Research Areas
Research Interests
Ø Synthesis and properties of new optical information and function materials.
Ø Synthesis and luminescent properties of new highly efficient luminescent materials.
Ø Controllable synthesis, functional properties, and application of nanomaterials.
Ø Synthesis, properties, and application of highly efficient phosphors for white LED, LCD, PDP and so on.
Ø Assemble nanoarrays via AAO template.
Current Research and Achievement
Our research involves solid state chemistry, luminescent materials, and nanomaterials. Our overall research goal is the design, synthesis, and properties of new materials with particular emphasis on understanding the structure-function relationship and their applications. Our research is motivated by the need to improve our fundamental understanding of these materials as well as gain practical knowledge of immediate use in developing new optical information and function materials for laser, fluorescent lamps, PDP, LCD, white LED, and so on.
1. Explore new highly efficient luminescent materials
Our research is concentrated on the structures, luminescent properties, energy transfer of different activators, and the relationships among them. These investigations allow us to provide the theoretical fundaments for predicting, designing, and synthesizing new highly efficient luminescent materials for fluorescent lamps, white LEDs, backlight for LCD, PDP, and so on. These investigations also provide a chance for us to discover new highly efficient luminescent materials and explore their feasibility of applications. The study of optical properties covers the range from vacuum ultraviolet to near infrared. Synthesized compounds dealt with borate, aluminate, silicate, phosphate, aluminoborate, fluoride，sulphide, etc. We have obtained several highly efficient luminescent materials such as highly efficient red PDP Phosphor in the system Y2O3-P2O5-V2O5:Eu. We have obtained three patents of new highly efficient phosphors. We have also obtained the relationship between host-absorption position and host compound.
2. Develop new synthesis technologies for highly efficient phosphors in use
Our goal is to develop new preparation methods of highly efficient luminescent materials in use. We have synthesized highly efficient luminescent materials such as upconversion phosphors (NaYF4:Er,Yb, BaYF5:Yb,Er), long persistence phosphors ((Ba,Sr,Ca)Al2O4:Eu2+,Dy3+), tricolor phosphors (Y2O3:Eu, YVO4:Eu, (Ce,Tb)MgAl11O19, (La,Ce,Tb)PO4 Sr5(PO4)3Cl:Eu, BaMgAl10O17:Eu,), color PDP phosphors (BaMgAl10O17:Eu, (Ba,Sr,Mg)O·xAl2O3:Mn, Zn2SiO4:Mn, (Y,Gd)(P1-xVx)O4:Eu, (Y,Gd)BO3:Eu), and LED phosphors ((Y,Ln,Ce)3(Al,Ga)5O12). Some obtained phosphors have been used in tricolor fluorescent lamps and display. At the same time, we have applied five patents. Furthermore, we have developed a new measurement system for PDP phosphors and set up a product line of the phosphors in Baoto Huaguang Rare Earth New Materials Co., Ltd. The preparation technology was honored as one of the ten news of Rare Earth Science and Technology in 2004.
3. Control synthesis of functional micro/nanomaterials
Our attention focuses on the shape control, micro/nanostructure assembly, and functional properties of micro/nanomaterials. We have obtained different kinds of shapes of micro/nanomaterials by various methods such as sol-gel, hydrothermal, and microemulsion methods. We obtained some rare earth materials with different defined shapes and structures such as nanorods, nanotubes, hollow spheres, spheres, core-shell structure, and so on. Meanwhile, We have developed the mass production technology of rare earth oxide nanomaterials and set up a product line in Shanghai Yuelong New Materials Co., Ltd. We have obtained three patents about the preparation methods of nanomaterials.
4. Assemble nanoarrays via AAO template
Our aim is to prepare defined nanoarrays via templates especially AAO template and study their properties. We have obtained Y2O3:Eu nanotube array and Y2O3:Tb nanorod array by AAO template (see following Figure). These nanoarrays have a potential application in optical information storage.
5. Apply nanomaterials to practice.
The obtained rare earth nanomaterials have been used in the field of ultraviolet absorption material, catalyst, luminescent materials, rear projection TV, etc. The application of rare earth oxides in rear projection TV greatly improves the viewing angle of the screen (see following Figure). Therefore, this application was appraised as a breakthrough that possessed an original innovation and reached international leading level.
Education
1994.7: M.S., Changchun Institute of Applied Chemistry,
1988.7: B.S.,
Experience
Work Experience
2005.12 - : Professor, State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry,
2003.1-2005.12: COE researcher, Associate Professor of COE project, Department of Environmental and Materials Engineering, Nagoya Institute of Technology
1999.4-2002.12: Associate Professor, Changchun Institute of Applied Chemistry,
1997.11-1999.4: Research Assistant, Changchun Institute of Applied Chemistry,
Teaching Experience
Luminescent Properties and Applications of Rare Earth Ions
Honors & Distinctions
1. The First Class Award of
2. The Third Class Prize of Scientific Progress of
3. The Third Class Prize of Scientific Progress of
Publications
Recent Papers
1 Lihui Zhang, Guang Jia, Hongpeng You*, Kai Liu, Mei Yang, Yanhua Song, Yuhua Zheng, Yeju Huang, Ning Guo, Hongjie Zhang, Sacrificial Template Method for Fabrication of Submicrometer-Sized YPO4:Eu3+ Hierarchical Hollow Spheres, Inorg. Chem. 2010, DOI: 10.1021/ic9022739.
2 Kai Liu, Hongpeng You*, Yuhua Zheng, Guang Jia, Yanhua Song, Yeju Huang, Mei Yang, Junjiao Jia, Ning Guo, and Hongjie Zhang, Facile and rapid fabrication of metal–organic framework nanobelts and color-tunable photoluminescence properties, J. Mater. Chem. 2010, DOI: 10.1039/b927465k.
3 Guang Jia, Hongpeng You*, Kai Liu, Yuhua Zheng, Ning Guo, and Hongjie Zhang, Highly Uniform Gd2O3 Hollow Microspheres:Template-Directed Synthesis and Luminescence Properties, Langmuir, 2010, DOI: 10.1021/la903584j.
4 Yuhua Zheng, Hongpeng You*, Guang Jia, Kai Liu, Yanhua Song, Mei Yang, Yeju Huang, Hongjie Zhang*, Facile synthesis of Y4O(OH)9NO3:Eu3+/Y2O3:Eu3+ nanotubes and nanobundles from nanolamellar precursors, CrystEngComm, 2010, 12, 585-590.
5 Guang Jia, Hongpeng You*, Kai Liu, Yuhua Zheng, Ning Guo, Junjiao Jia, Hongjie Zhang, Highly Uniform YBO3 Hierarchical Architectures: Facile Synthesis and luminecence Properties, Chemistry - A European Journal 2010, 16, 2930-2937.
6 Kai Liu, Hongpeng You*, Guang Jia, Yuhua Zheng, Yeju Huang, Yanhua Song, Mei Yang, Lihui Zhang and Hongjie Zhang, Hierarchically Nanostructured Coordination Polymer: Facile and Rapid Fabrication and Tunable Morphologies, Cryst. Growth Des. 2010, 10 (2), 790–797.
7 Yanhua Song, Hongpeng You*, Mei Yang, Yuhua Zheng, Kai Liu, Guang Jia, Yeju Huang, Lihui Zhang and Hongjie Zhang, Facile Synthesis and Luminescence of Sr5(PO4)3Cl:Eu2+ Nanorod Bundles via a Hydrothermal Route, Inorg. Chem. 2010, 49 (4), 1674–1678.
8 Kai Liu, Hongpeng You*, Yuhua Zheng, Guang Jia, Yeju Huang, Mei Yang, Yanhua Song, Lihui Zhang and Hongjie Zhang, Room-Temperature Synthesis of Multi-Morphological Coordination Polymer and Tunable White-Light Emission, Cryst. Growth Des. 2010, 10(1), 16-19.
9 Yuhua Zheng, Hongpeng You*, Guang Jia, Kai Liu, Yanhua Song, Mei Yang, and Hongjie Zhang, Facile Hydrothermal Synthesis and Luminescent Properties of Large-Scale GdVO4:Eu3+ Nanowires, Cryst. Growth Des. 2009, 9, 5101-5109.
10 Mei Yang, Hongpeng You*, Yuhua Zheng, Kai Liu, Guang Jia, Yanhua Song, Yeju Huang, Lihui Zhang, and Hongjie Zhang, Hydrothermal Synthesis and Luminescent Properties of Novel Ordered Sphere CePO4 Hierarchical Architectures, Inorg. Chem. 2009, 48, 11559-11565.
11 Mei Yang, Hongpeng You*, Yanhua Song, Yeju Huang, Guang Jia, Kai Liu, Yuhua Zheng, Lihui Zhang and Hongjie Zhang, Synthesis and Luminescence Properties of Sheaflike TbPO4 Hierarchical Architectures with Different phase Structures, J. Phys. Chem. C 2009, 113, 20173-20177.
12 Guang Jia, Hongpeng You*, Lihui Zhang, Yuhua Zheng, Kai Liu, Yeju Huang and Hongjie Zhang, Facile synthesis of highly uniform octahedral LuVO4 microcrystals by a facile chemical conversion method, CrystEngComm, 2009, 11, 2745-2750.
13 Kai Liu, Hongpeng You*, Yuhua Zheng, Guang Jia, Lihui Zhang, Yeju Huang, Mei Yang, Yanhua Song and Hongjie Zhang, Facile shape-controlled synthesis of luminescent europium benzene-1,3,5-tricarboxylate architectures at room temperature, CrystEngComm 2009, 11,2622-2628.
14 Kai Liu, Guang Jia, Yuhua Zheng, Yanhua Song, Mei Yang, Yeju Huang, Lihui Zhang, Hongpeng You*, Room-temperature synthesis and luminescence properties of Eu3+/Tb3+-doped La(1,3,5–BTC)(H2O)6, Inorg. Chem. Commun. 2009, 12, 1246-1249.
15 Mei Yang, Hongpeng You*, Guang Jia, Yeju Huang, Yanhua Song, Yuhua Zheng, Kai Liu, Lihui Zhang, Selective synthesis of hexagonal and monoclinic LaPO4:Eu3+ nanorods by a hydrothermal method, J. Crystal Growth 2009, 311，4753-4758.
16 Guang Jia, Hongpeng You*, Yanhua Song, Junjiao Jia, Yuhua Zheng, Lihui Zhang, Kai Liu, and Hongjie Zhang, Facile chemical conversion synthesis and luminescence properties of uniform Ln3+ (Ln = Eu, Tb)-doped NaLuF4 nanowires and LuBO3 microdisks, Inorg. Chem. 2009, 48(21) 10193-10201.
17 Guang Jia, Yeju Huang, Yanhua Song, Mei Yang, Lihui Zhang, and Hongpeng You*, Controllable synthesis and luminescence properties of La(OH)3 and La(OH)3:Tb3+ nanocrystals with multiform morphologies, Eur. J. Inorg. Chem. 2009, 25, 3721–3726.
18 Yeju Huang, Hongpeng You*, Guang Jia, Yuhua Zheng, Yanhua Song, Mei Yang, Kai Liu, Lihui Zhang, Hydrothermal synthesis and luminescence of Eu-Doped Ba0.92Y
19 Guang Jia, Hongpeng You*, Mei Yang, Lihui Zhang, Hongjie Zhang, Uniform lanthanide orthoborates LnBO3 (Ln = Gd, Nd, Sm, Eu, Tb, and Dy) microplates: general synthesis and luminescence properties, J. Phys. Chem. C 2009, 113, 16638–16644.
20 Guang Jia, Yanhua Song, Mei Yang, Kai Liu, Yuhua Zheng, Hongpeng You*, Facile synthesis and luminescence properties of octahedral YVO4:Eu3+ microcrystals, J. Cryst. Growth 2009, 311, 4213–4218.
21 Kai Liu, Hongpeng You* , Guang Jia, Yuhua Zheng, Yanhua Song, Mei Yang, Yeju Huang and Hongjie Zhang, Coordination-induced formation of one-dimensiothermal transformation, Cryst. Growth Des. 2009, 9, 3519-3524.
22 Guang Jia, Kai Liu, Yuhua Zheng, Yanhua Song and Hongpeng You*, Facile synthesis and luminescence properties of highly uniform MF/YVO4:Ln3+ (Ln = Eu, Dy, and Sm) composite microspheres, Cryst. Growth Des. 2009, 9, 3702-3706.
23 Guang Jia, Kai Liu, Yuhua Zheng, Yanhua Song, Mei Yang, Hongpeng You*, Highly uniform Gd(OH)3 and Gd2O3:Eu3+ nanotubes: facile synthesis and luminescence properties, J. Phys. Chem. C 2009, 113, 6050–6055.
24 Guang Jia, Yanhua Song, Mei Yang, Yeju Huang, Lihui Zhang, Hongpeng You*, Uniform YVO4:Ln3+ (Ln = Eu, Dy and Sm) nanocrystals:solvothermal synthesis and luminescence properties, Opt. Mater. 2009, 31, 1032–1037.
25 Yanhua Song, Guang Jia, Mei Yang, Yeju Huang, Hongpeng You*, Hongjie Zhang, Sr3Al2O5Cl2:Ce3+,Eu2+: A potential tunable yellow-to-white-emitting phosphor for ultraviolet light emitting diodes, Appl. Phys. Lett. 2009, 94, 091902.
26 Guang Jia, Mei Yang, Yanhua Song, Hongpeng You*, Hongjie Zhang, General and facile method to prepare uniform Y2O3:Eu hollow microspheres, Cryst. Growth Des. 2009, 9 (1), 301–307.
27 Guang Jia, Yuhua Zheng, Kai Liu, Yanhua Song, Hongpeng You*, Hongjie Zhang, Facile surfactant- and template-Free synthesis and luminescent properties of one-dimensional Lu2O3:Eu3+ phosphors, J. Phys. Chem. C, 2009, 113, 153–158.
28 Mei Yang, Qipeng Liu, Fenghua Chen, Hongpeng You*, Dongfeng Li, Synthesis and fluorescent property of NH4Y1.9Eu
29 Hongpeng You*, Yanhuan Song, Guang Jia, Guangyan Hong, Energy transfer from Tb3+ to Mn2+ in LaMgAl11O19:Tb, Mn phosphors, Opt. Mater. 2008, 31, 342–345
30 Hongpeng You*, Jilin Zhang, Guangyan Hong, and Hongjie Zhang, Luminescent properties of Mn2+ in hexagonal aluminates under ultraviolet and vacuum ultraviolet excitation, J. Phys. Chem. C 2007, 111, 10657-10661.
31 Hongpeng You, Tomokatsu Hayakawa, and Masayuki Nogami, Optical properties and valence change of samarium ions in a sol–gel Al2O3–B2O3–SiO2 glass by femtosecond laser irradiation, J. Non-Cryst. Solids 2006, 352, 2778–2782.
32 Hongpeng You, Tomokatsu Hayakawa, and Masayuki Nogami, Spectral hole burning in Sol-Gel-Derived Eu3+-doped Al2O3-B2O3-SiO2 glass, Advanced Materials Research 2006, 11-12, 201-204.
33 Hongpeng You, Masayuki Nogami, Persistent spectral hole burning of Eu3+ ions in TiO2-SiO2 glass prepared by sol–gel method, J. Alloys Compd. 2006, 408-412, 796-799.
34 Hongpeng You, Masayuki Nogami, Optical properties and valence change of europium ions in a Sol-Gel Al2O3-B2O3-SiO2 glass by femtosecond laser pulses，J. Phys. Chem. B 2005, 109(29), 13980 -13984.
35 Hongpeng You, Masayuki Nogami, Optical Properties and Local Structure of Eu3+ Ions in Sol-Gel TiO2-SiO2 Glasses, J. Phys. Chem. B 2004, 108(32), 12003-12008.
36 Hongpeng You, Masayuki Nogami, Upconversion luminescence of Al2O3-SiO2:Ce3+ glass by femtosecond laser irradiation, Appl. Phys. Lett. 2004，85, 3432-3434。
37 Hongpeng You, Masayuki Nogami, Three-photon-excited fluorescence of Al2O3–SiO2 glass containing Eu3+ ions by femtosecond laser irradiation, Appl. Phys. Lett. 2004, 84, 2076-2078.
38 Hongpeng You, Masayuki Nogami, Local structure and persistent spectral hole burning of the Eu3+ ion in SnO2–SiO2 glass containing SnO2 nanocrystals, J. Appl. Phys. 2004, 95, 2781-2785.
39 Hongpeng You, Xueyan Wu, Guangyan Hong, Jinke Tang, Huiping Hu, A new type of high efficient luminescent material--the system Al2O3-B2O3 containing Ce3+ and Tb3+ ions, Chem. Mater. 2003, 15, 2000.
Recent Patents
1. Hongpeng You, Yanhuan Song, Guangyan Hong, A phosphor and its preparation for FED, Faming Zhuanli Shenqing Gongbu Shuomingshu, CN200910217921.22.
2. Hongpeng You, Guang Jia, Yanhua Song, Guangyan Hong, Preparartion of LuVO4:Eu red phosphor, Faming Zhuanli Shenqing Gongbu Shuomingshu, CN200810051586.9
3. Hongpeng You, Guang Jia, Yanhua Song, Guangyan Hong, Preparartion of Gd(OH)3 and Gd2O3 nanotubes, Faming Zhuanli Shenqing Gongbu Shuomingshu, CN200810051588.8
4. Hongpeng You, Yanhua Song, Song Liu, Guangyan Hong, A phosphor and its preparation for white LED from UV and near-UV light exitation, Faming Zhuanli Shenqing Gongbu Shuomingshu, CN2008100050736.4
5. Hongpeng You, Yanhua Song, Pengzhen Wu, Guangyan Hong, A phosphor and its preparation for FED, Faming Zhuanli Shenqing Gongbu Shuomingshu, CN2008100050913.9
6. Hongpeng You Wen Li, Guangyan Hong, Method for the preparation of green aluminate phosphor for vacuum ultraviolet excited light, Faming Zhuanli Shenqing Gongbu Shuomingshu, CN 200710055398.9.
7. Hongpeng You, Wen Li, Guangyan Hong, An infrared to visible upconversion phosphor and its preparation method, Faming Zhuanli Shenqing Gongbu Shuomingshu, CN200710055399.3,
8. Hongpeng You, Qipeng Liu, Guangyan Hong, An orange phosphor and its preparation for the White LED by blue light excitation, Faming Zhuanli Shenqing Gongbu Shuomingshu, CN 200710056252.6.
9. Hongpeng You, Qipeng Liu, Guangyan Hong, Preparation method of phosphor for the white LED by blue light excitation, Faming Zhuanli Shenqing Gongbu Shuomingshu, CN 200610173386.1,
10. Hongpeng You， Guangyan Hong，Xueyan Wu， Qiong Wu, Method for preparing vacuum UV ray excited blue aluminate phosphor. Faming Zhuanli Shenqing Gongkai Shuomingshu (2003)，CN1415695
11. Hongpeng You, Guangyan Hong, Xueyan Wu, Qiong Wu, Method for preparation of vacuum UV-excitable aluminate green phosphor. Faming Zhuanli Shenqing Gongkai Shuomingshu (2003), CN1405268
12. Hongpeng You, Xueyan Wu, Guangyan Hong, Hongtao Cui, Qiong Wu, Preparation of green barium magnesium aluminate fluorophors excited by vacuum ultraviolet, Faming Zhuanli Shenqing Gongkai Shuomingshu (2002), CN1366017.
13. Guangyan Hong, Hongpeng You, Yijie Zhang, Youmo Li, Shuifeng Xu, Qingxin Jia, Decai Yu, Preparation of rare earth Al2O3-B2O3 green luminescent material. Faming Zhuanli Shenqing Gongkai Shuomingshu (1998), CN1180095.
Research Projects
1. National Basic Research Program of
2. National Natural Science Foundation of
3. National Natural Science Foundation of
4. Science and
5. Projects supported by the industry: Investigation on the preparation technology and applications of highly efficient luminescent materials for white LED, PDP, LCD, and so on.
6.
Graduate Students
已指导学生
刘凯 硕士研究生 070301-无机化学
贾光 博士研究生 070301-无机化学
宋艳华 博士研究生 070301-无机化学
杨梅 博士研究生 070301-无机化学
张立会 博士研究生 070301-无机化学
黄叶菊 博士研究生 070301-无机化学
乔卉 硕士研究生 070301-无机化学
郑玉华 博士研究生 070301-无机化学
现指导学生
郭宁 博士研究生 070301-无机化学
邵百旗 硕士研究生 070301-无机化学
焦蒙蒙 硕士研究生 070301-无机化学
贾永超 博士研究生 070301-无机化学
赵琪 博士研究生 070301-无机化学
吕文珍 博士研究生 070301-无机化学